Submit to Molecules Review for Molecules Propose a Special Issue

Journal Menu

Journal Browser

► Journal Browser

Research on Polyoxometalate Materials

Print Special Issue Flyer
Special Issue Editors
Special Issue Information
Keywords
Published Papers

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Applied Chemistry".

Deadline for manuscript submissions: closed (20 November 2022) | Viewed by 19501

Printed Edition Available!
A printed edition of this Special Issue is available here.

Special issue Research on Polyoxometalate Materials book cover image

Share This Special Issue

Special Issue Editor

Dr. Xiaobing Cui

E-Mail Website
Guest Editor

College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130021, Jilin, China
Interests: polyoxometalate; crystal structure; coordination compounds based on polyoxometalates; catalysis of polyoxometalates; electrode material based on polyoxometalates

Special Issue Information

Dear Colleagues,

Polyoxometalates (POMs) are a large and rapidly growing class of early transition metal oxide clusters. POMs are formed via acid-involved condensation reactions from monomeric oxometalate units, thus holding a special position (intermediate state) between monomeric oxometalate units and infinite metal oxide frameworks. Though the first compound of what we term a polyoxometalate was reported about two centuries ago by Berzelius (1826), POMs continue to show remarkable advances and unexpected surprises in both their fundamentals and applications. POMs exhibit a large diversity of structures including saturated structures such as the famous Keggin, Well–Dawson, Anderson, etc., and unsaturated structures such as the vacant Keggin, vacant Well–Dawson, etc. Especially, the unsaturated POMs can act as robust and pure inorganic ligands to coordinate with almost all the transition metals, and then be integrated into the frameworks of POM clusters. The chemical compositions of POMs are mainly Mo, W, V, Nb and Ta. The heteroatom of POMs are more variable, including P, As, B, Al, Si, Ge, S, and so on. It is well known that there is a general correlation between the complexity of the structure of a compound and the functionality that it displays. The wide range of chemical composition variability and a large amount of unusual structural types of POMs can thus exhibit a large number of different properties such as rich solution equilibria, significant chemical and thermal stability, strong acidity, and the ability to act as proton–electron sinks due to their fast and reversible proton-coupled redox processes. Virtually all of the molecular properties of these POMs can be altered by fine-tuning the structure and chemical composition of the POMs at the atomic level. Based on their intrinsic multifunctional nature, POMs have significant applications in catalysis, medicine, and materials science, etc. POMs can not only be used widely in different disciplines, but can also be combined with polymers, oxides, ionic liquids or carbonaceous supports to construct new and advanced composite (hybrid) materials, which have important, extensive applications in catalysis, electrode materials, electrocatalysis, photocatalysis and so on. This Special Issue focuses on the fundamentals of POMs and POM-based materials, including synthetic methods, reactivity, spectroscopic or spectrometric studies, structures, mechanistic insights and DFT calculations, and potential applications, such as redox- and acid-base catalysis, photo- and electrochemistry, magnetism, electronics, optics, bio-medicine, energy conversion and storage, sorption and separation, environmental remediation and medicine. Full papers, communications, and reviews on these topics are welcome.

Dr. Xiaobing Cui
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Molecules is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

polyoxometalate
crystal materials of polyoxometalates
coordination compounds based on polyoxometalates
catalysis of polyoxometalates
electrode material based on polyoxometalates
DFT calculations of polyoxometalates
composites based on polyoxometalates

Published Papers (12 papers)

Download All Papers

Order results

Result details

Show export options Show export options

Select all

Export citation of selected articles as:

Editorial

Jump to: Research, Review

3 pages, 192 KiB

Open AccessEditorial

Special Issue: Research on Polyoxometalate Materials

by Xiao-Bing Cui

Molecules 2023, 28(12), 4662; https://doi.org/10.3390/molecules28124662 - 09 Jun 2023

Cited by 1 | Viewed by 1082

Abstract

The science of polyoxometalates (POMs) has come a long way since molybdenum blue was first described in 1778 [...] Full article

(This article belongs to the Special Issue Research on Polyoxometalate Materials)

Research

Jump to: Editorial, Review

15 pages, 4414 KiB

Open AccessArticle

Proton Affinity in the Chemistry of Beta-Octamolybdate: HPLC-ICP-AES, NMR and Structural Studies

by Victoria V. Volchek, Nikolay B. Kompankov, Maxim N. Sokolov and Pavel A. Abramov

Molecules 2022, 27(23), 8368; https://doi.org/10.3390/molecules27238368 - 30 Nov 2022

Cited by 1 | Viewed by 1124

Abstract

The affinity of [β-Mo₈O₂₆]⁴⁻ toward different proton sources has been studied in various conditions. The proposed sites for proton coordination were highlighted with single crystal X-ray diffraction (SCXRD) analysis of (Bu₄N)₃[β-{Ag(py-NH₂)Mo₈O₂₆]}] (1) and from analysis of reported structures. Structural rearrangement of [β-Mo₈O₂₆]⁴⁻ as a direct response to protonation was studied in solution with ⁹⁵Mo NMR and HPLC-ICP-AES techniques. A new type of proton transfer reaction between (Bu₄N)₄[β-Mo₈O₂₆] and (Bu₄N)₄H₂[V₁₀O₂₈] in DMSO results in both polyoxometalates transformation into [V₂Mo₄O₁₉]⁴⁻, which was confirmed by the ⁹⁵Mo, ⁵¹V NMR and HPLC-ICP-AES techniques. The same type of reaction with [H₄SiW₁₂O₄₀] in DMSO leads to metal redistribution with formation of [W₂Mo₄O₁₉]²⁻. Full article

(This article belongs to the Special Issue Research on Polyoxometalate Materials)

► Show Figures

Figure 1

21 pages, 49737 KiB

Open AccessArticle

Grafting of Anionic Decahydro-Closo-Decaborate Clusters on Keggin and Dawson-Type Polyoxometalates: Syntheses, Studies in Solution, DFT Calculations and Electrochemical Properties

by Manal Diab, Ana Mateo, Joumada El Cheikh, Zeinab El Hajj, Mohamed Haouas, Alireza Ranjbari, Vincent Guérineau, David Touboul, Nathalie Leclerc, Emmanuel Cadot, Daoud Naoufal, Carles Bo and Sébastien Floquet

Molecules 2022, 27(22), 7663; https://doi.org/10.3390/molecules27227663 - 08 Nov 2022

Cited by 5 | Viewed by 1457

Abstract

Herein we report the synthesis of a new class of compounds associating Keggin and Dawson-type Polyoxometalates (POMs) with a derivative of the anionic decahydro-closo-decaborate cluster [B₁₀H₁₀]²⁻ through aminopropylsilyl ligand (APTES) acting as both a linker and a spacer between the two negatively charged species. Three new adducts were isolated and fully characterized by various NMR techniques and MALDI-TOF mass spectrometry, notably revealing the isolation of an unprecedented monofunctionalized SiW₁₀ derivative stabilized through intramolecular H-H dihydrogen contacts. DFT as well as electrochemical studies allowed studying the electronic effect of grafting the decaborate cluster on the POM moiety and its consequences on the hydrogen evolution reaction (HER) properties. Full article

(This article belongs to the Special Issue Research on Polyoxometalate Materials)

► Show Figures

Figure 1

13 pages, 1777 KiB

Open AccessArticle

Organic/Inorganic Species Synergistically Supported Unprecedented Vanadomolybdates

by Tian Chang, Di Qu, Bao Li and Lixin Wu

Molecules 2022, 27(21), 7447; https://doi.org/10.3390/molecules27217447 - 02 Nov 2022

Cited by 6 | Viewed by 1126

Abstract

Vanadomolybdates (VMos), comprised of Mo and V in high valences with O bridges, are one of the most important types of polyoxometalates (POMs), which have high activity due to their strong capabilities of gaining/losing electrons. Compared with other POMs, the preparation of VMos is difficult due to their relatively low structural stability, especially those with unclassical architectures. To overcome this shortcoming, in this study, triol ligands were applied to synthesize VMos through a beaker reaction in the presence of V₂O₅, Na₂MoO₄, and organic species in the aqueous solution. The single-crystal X-ray diffraction results indicate that two VMo clusters, Na₄{V₅Mo₂O₁₉[CH₃C(CH₂O)₃]}∙13H₂O and Na₄{V₅Mo₂O₁₉[CH₃CH₂C(CH₂O)₃]}∙13H₂O, with a similar architecture, were synthesized, which were both stabilized by triol ligand and {MoO₆} polyhedron. Both clusters are composed of five V ions and one Mo ion in a classical Lindqvist arrangement with an additional Mo ion, showing an unprecedented hepta-nuclear VMo structure. The counter Na⁺ cations assemble into one-dimensional channels, which facilitates the transport of protons and was further confirmed by proton conductivity experiments. The present results provide a new strategy to prepare and stabilize VMos, which is applicable for developing other compounds, especially those with untraditional architectures. Full article

(This article belongs to the Special Issue Research on Polyoxometalate Materials)

► Show Figures

Figure 1

16 pages, 4861 KiB

Open AccessArticle

First Organic–Inorganic Hybrid Compounds Formed by Ge-V-O Clusters and Transition Metal Complexes of Aromatic Organic Ligands

by Hai-Yang Guo, Hui Qi, Xiao Zhang and Xiao-Bing Cui

Molecules 2022, 27(14), 4424; https://doi.org/10.3390/molecules27144424 - 11 Jul 2022

Cited by 3 | Viewed by 1556

Abstract

Three compounds based on Ge-V-O clusters were hydrothermally synthesized and characterized by IR, UV-Vis, XRD, ESR, elemental analysis and X-ray crystal structural analysis. Both [Cd(phen)(en)]₂[Cd₂(phen)₂V₁₂O₄₀Ge₈(OH)₈(H₂O)]∙12.5H₂O (1) and [Cd(DETA)]₂[Cd(DETA)₂]_0.5[Cd₂(phen)₂V₁₂O₄₁Ge₈(OH)₇(0.5H₂O)]∙7.5H₂O (2) (1,10-phen = 1,10-phenanthroline, en = ethylenediamine, DETA = diethylenetriamine) are the first Ge-V-O cluster compounds containing aromatic organic ligands. Compound 1 is the first dimer of Ge-V-O clusters, which is linked by a double bridge of two [Cd(phen)(en)]²⁺. Compound 2 exhibits an unprecedented 1-D chain structure formed by Ge-V-O clusters and [Cd₂(DETA)₂]⁴⁺ transition metal complexes (TMCs). [Cd(en)₃]{[Cd(η₂-en)₂]₃[Cd(η₂-en)(η₂-μ₂-en)(η₂-en)Cd][Ge₆V₁₅O₄₈(H₂O)]}∙5.5H₂O (3) is a novel 3-D structure which is constructed from [Ge₆V₁₅O₄₈(H₂O)]¹²⁻ and four different types of TMCs. We also synthesized [Zn₂(enMe)₃][Zn(enMe)]₂[Zn(enMe)₂(H₂O)]₂[Ge₆V₁₅O₄₈(H₂O)]∙3H₂O (4) and [Cd(en)₂]₂{H₈[Cd(en)]₂Ge₈V₁₂O₄₈(H₂O)}∙6H₂O (5) (enMe = 1,2-propanediamine), which have been reported previously. In addition, the catalytic properties of these five compounds for styrene epoxidation have been assessed. Full article

(This article belongs to the Special Issue Research on Polyoxometalate Materials)

► Show Figures

Graphical abstract

12 pages, 2327 KiB

Open AccessArticle

Designed Syntheses of Three {Ni₆PW₉}-Based Polyoxometalates, from Isolated Cluster to Cluster-Organic Helical Chain

by Chong-An Chen, Yan Liu and Guo-Yu Yang

Molecules 2022, 27(13), 4295; https://doi.org/10.3390/molecules27134295 - 04 Jul 2022

Cited by 2 | Viewed by 1601

Abstract

Three new hexa-Ni-substituted Keggin-type polyoxometalates (POMs), [Ni₆(OH)₃- (DACH)₃(H₂O)₆(PW₉O₃₄)]·31H₂O (1), [Ni(DACH)₂][Ni₆(OH)₃(DACH)₃(HMIP)₂(H₂O)₂(PW₉ [...] Read more.

Three new hexa-Ni-substituted Keggin-type polyoxometalates (POMs), [Ni₆(OH)₃- (DACH)₃(H₂O)₆(PW₉O₃₄)]·31H₂O (1), [Ni(DACH)₂][Ni₆(OH)₃(DACH)₃(HMIP)₂(H₂O)₂(PW₉O₃₄)]·56 H₂O (2), and [Ni(DACH)₂][Ni₆(OH)₃(DACH)₂(AP)(H₂O)₅(PW₉O₃₄)]·2H₂O (3) (DACH = 1,2-Diami- nocyclohexane, MIP = 5-Methylisophthalate, AP = Adipate) were successfully made in the presence of DACH under hydrothermal conditions. 1 is an isolated hexa-Ni-substituted Keggin unit decorated by DACH. In order to further construct POM cluster-organic frameworks (POMCOFs) on the basis of 1, by analyzing the steric hindrances and orientations of the POM units, the rigid HMIP and flexible AP ligands were successively incorporated, and another anionic monomeric POM 2 and the new 1D POM cluster organic chain (POMCOC) 3 were obtained. HMIP ligand still acts as a decorating group on the Ni₆ core of 2 but results in the different spatial arrangement of the {Ni₆PW₉} units. AP ligands in 3 successfully bridge adjacent isolated POM cluster units to 1D POMCOC with left-hand helices. The AP in 3 is the longest aliphatic carboxylic acid ligand in POMs, and the 1D POM cluster-AP helical chain represents the first 1D POMCOC with a helical feature. Full article

(This article belongs to the Special Issue Research on Polyoxometalate Materials)

► Show Figures

Graphical abstract

12 pages, 3068 KiB

Open AccessArticle

Vanadium-Substituted Dawson-Type Polyoxometalate–TiO₂ Nanowire Composite Film as Advanced Cathode Material for Bifunctional Electrochromic Energy-Storage Devices

by Yu Fu, Yanyan Yang, Dongxue Chu, Zefeng Liu, Lili Zhou, Xiaoyang Yu and Xiaoshu Qu

Molecules 2022, 27(13), 4291; https://doi.org/10.3390/molecules27134291 - 04 Jul 2022

Cited by 4 | Viewed by 1587

Abstract

Polyoxometalates (POMs) demonstrate potential for application in the development of integrated smart energy devices based on bifunctional electrochromic (EC) optical modulation and electrochemical energy storage. Herein, a nanocomposite thin film composed of a vanadium-substituted Dawson-type POM, i.e., K₇[P₂W₁₇VO₆₂]·18H₂O, and TiO₂ nanowires were constructed via the combination of hydrothermal and layer-by-layer self-assembly methods. Through scanning electron microscopy and energy-dispersive spectroscopy characterisations, it was found that the TiO₂ nanowire substrate acts as a skeleton to adsorb POM nanoparticles, thereby avoiding the aggregation or stacking of POM particles. The unique three-dimensional core−shell structures of these nanocomposites with high specific surface areas increases the number of active sites during the reaction process and shortens the ion diffusion pathway, thereby improving the electrochemical activities and electrical conductivities. Compared with pure POM thin films, the composite films showed improved EC properties with a significant optical contrast (38.32% at 580 nm), a short response time (1.65 and 1.64 s for colouring and bleaching, respectively), an excellent colouration efficiency (116.5 cm² C⁻¹), and satisfactory energy-storage properties (volumetric capacitance = 297.1 F cm⁻³ at 0.2 mA cm⁻²). Finally, a solid-state electrochromic energy-storage (EES) device was fabricated using the composite film as the cathode. After charging, the constructed device was able to light up a single light-emitting diode for 20 s. These results highlight the promising features of POM-based EES devices and demonstrate their potential for use in a wide range of applications, such as smart windows, military camouflage, sensors, and intelligent systems. Full article

(This article belongs to the Special Issue Research on Polyoxometalate Materials)

► Show Figures

Graphical abstract

9 pages, 1879 KiB

Open AccessCommunication

Detecting the Subtle Photo-Responsive Conformational Bistability of Monomeric Azobenzene Functionalized Keggin Polyoxometalates by Using Ion-Mobility Mass Spectrometry

by Bo Qi, Luran Jiang, Sai An, Wei Chen and Yu-Fei Song

Molecules 2022, 27(12), 3927; https://doi.org/10.3390/molecules27123927 - 19 Jun 2022

Cited by 1 | Viewed by 1197

Abstract

Accurately characterizing the conformational variation of novel molecular assemblies is important but often ignored due to limited characterization methods. Herein, we reported the use of ion-mobility mass spectrometry (IMS/MS) to investigate the conformational changes of four azobenzene covalently functionalized Keggin hybrids (azo-Keggins, compounds 1–4). The as-prepared azo-Keggins showed the general molecular formula of [C₁₆H₃₆N]₄[SiW₁₁O₄₀(Si(CH₂)₃NH–CO(CH₂)_nO–C₆H₄N=NC₆H₄–R)₂] (R = H, n = 0 (1); R = NO₂, n = 0 (2); R = H, n = 5 (3); R = H, n = 10 (4)). The resultant azo-Keggins maintained stable monomeric states in the gas phase with intact molecular structures. Furthermore, the subtle photo-responsive trans-cis conformational variations of azo-Keggins were clearly revealed by the molecular shape-related collision cross-section value difference ranging from 2.44 Å² to 6.91 Å². The longer the alkyl chains linkers were, the larger the conformational variation was. Moreover, for compounds 1 and 2, higher stability in trans-conformation can be observed, while for compounds 3 and 4, bistability can be achieved for both of them. Full article

(This article belongs to the Special Issue Research on Polyoxometalate Materials)

► Show Figures

Figure 1

14 pages, 3415 KiB

Open AccessFeature PaperArticle

Cations Modulated Assembly of Triol-Ligand Modified Cu-Centered Anderson-Evans Polyanions

by Yiran Wang, Fengxue Duan, Xiaoting Liu and Bao Li

Molecules 2022, 27(9), 2933; https://doi.org/10.3390/molecules27092933 - 04 May 2022

Cited by 8 | Viewed by 1373

Abstract

Counter-cations are essential components of polyoxometalates (POMs), which have a distinct influence on the solubility, stabilization, self-assembly, and functionality of POMs. To investigate the roles of cations in the packing of POMs, as a systematic investigation, herein, a series of triol-ligand covalently modified Cu-centered Anderson-Evans POMs with different counter ions were prepared in an aqueous solution and characterized by various techniques including single-crystal X-ray diffraction. Using the strategy of controlling Mo sources, in the presence of triol ligand, NH₄⁺, Cu²⁺ and Na⁺ were introduced successfully into POMs. When (NH₄)₆Mo₇O₂₄ was selected, the counter cations of the produced POMs were ammonium ions, which resulted in the existence of clusters in the discrete state. Additionally, with the modulation of the pH of the solutions, the modified sites of triol ligands on the cluster can be controlled to form δ- or χ-isomers. By applying MoO₃ in the same reaction, Cu²⁺ ions served as linkers to connect triol-ligand modified polyanions into chains. When Na₄Mo₈O₂₆ was employed as the Mo source to react with triol ligands in the presence of CuCl₂, two 2-D networks were obtained with {Na₄(H₂O)₁₄} or {{Na₂(H₂O)₄} sub-clusters as linkers, where the building blocks were δ/δ- and χ/χ-isomers, respectively. The present investigation reveals that the charges, sizes and coordination manners of the counter cations have an obvious influence on the assembled structure of polyanions. Full article

(This article belongs to the Special Issue Research on Polyoxometalate Materials)

► Show Figures

Figure 1

13 pages, 39391 KiB

Open AccessArticle

Controllable Assembly of Vanadium-Containing Polyoxoniobate-Based Materials and Their Electrocatalytic Activity for Selective Benzyl Alcohol Oxidation

by Xiaoxia Li, Ni Zhen, Chengpeng Liu, Di Zhang, Jing Dong, Yingnan Chi and Changwen Hu

Molecules 2022, 27(9), 2862; https://doi.org/10.3390/molecules27092862 - 30 Apr 2022

Cited by 6 | Viewed by 1650

Abstract

During the controllable synthesis of two vanadium-containing Keggin-type polyoxoniobates (PONbs), [Ni(en)₂]₅[PNb₁₂O₄₀(VO)₅](OH)₅·18H₂O (1) and [Ni(en)₃]₅[PNb₁₂O₄₀(VO)₂]∙17H₂O (2, en = ethylenediamine) are realized by changing the vanadium source and hydrothermal temperature. Compounds 1 and 2 have been thoroughly characterized by single-crystal X-ray diffraction analysis, FT-IR spectra, X-ray photoelectron spectrum (XPS), powder X-ray diffraction (PXRD), etc. Compound 1 contains a penta-capped Keggin-type polyoxoniobate {PNb₁₂O₄₀(VO)₅}, which is connected by adjacent [Ni(en)₂]²⁺ units into a three-dimensional (3D) organic-inorganic framework, representing the first nickel complexes connected vanadoniobate-based 3D material. Compound 2 is a discrete di-capped Keggin-type polyoxoniobate {PNb₁₂O₄₀(VO)₂} with [Ni(en)₃]²⁺ units as counter cations. Compounds 1 and 2 have poor solubility in common solvents and can keep stable in the pH range of 4 to 14. Notably, both 1 and 2 as electrode materials are active for the selective oxidation of benzyl alcohol to benzaldehyde. Under ambient conditions without adding an alkaline additive, compound 1 as a noble metal free electrocatalyst can achieve 92% conversion of benzyl alcohol, giving a Faraday efficiency of 93%; comparatively, 2 converted 79% of the substrate with a Faraday efficiency of 84%. The control experiments indicate that both the alkaline polyoxoniobate cluster and the capped vanadium atoms play an important role during the electrocatalytic oxidation process. Full article

(This article belongs to the Special Issue Research on Polyoxometalate Materials)

► Show Figures

Figure 1

Review

Jump to: Editorial, Research

17 pages, 4076 KiB

Open AccessReview

Recent Advances of Ti/Zr-Substituted Polyoxometalates: From Structural Diversity to Functional Applications

by Zhihui Ni, Hongjin Lv and Guoyu Yang

Molecules 2022, 27(24), 8799; https://doi.org/10.3390/molecules27248799 - 12 Dec 2022

Cited by 5 | Viewed by 1833

Abstract

Polyoxometalates (POMs), a large family of anionic polynuclear metal–oxo clusters, have received considerable research attention due to their structural versatility and diverse physicochemical properties. Lacunary POMs are key building blocks for the syntheses of functional POMs due to their highly active multidentate O-donor sites. In this review, we have addressed the structural diversities of Ti/Zr-substituted POMs based on the polymerization number of POM building blocks and the number of Ti and Zr centers. The synthetic strategies and relevant catalytic applications of some representative Ti/Zr-substituted POMs have been discussed in detail. Finally, the outlook on the future development of this area is also prospected. Full article

(This article belongs to the Special Issue Research on Polyoxometalate Materials)

► Show Figures

Figure 1

13 pages, 3589 KiB

Open AccessReview

Recent Advances of Anderson-Type Polyoxometalates as Catalysts Largely for Oxidative Transformations of Organic Molecules

by Zheyu Wei, Jingjing Wang, Han Yu, Sheng Han and Yongge Wei

Molecules 2022, 27(16), 5212; https://doi.org/10.3390/molecules27165212 - 16 Aug 2022

Cited by 23 | Viewed by 2634

Abstract

Anderson-type ([XM₆O₂₄]ⁿ⁻) polyoxometalates (POMs) are a class of polymetallic-oxygen cluster inorganic compounds with special structures and properties. They have been paid extensive attention by researchers now, due to their chemical modification and designability, which have been widely applied in the fields of materials, catalysis and medicine. In contemporary years, the application of Anderson-type POMs in catalytic organic oxidation reaction has gradually shown great significance for the research of green catalytic process. In this paper, we investigate the application of Anderson-type POMs in organic synthesis reaction, and these works are summarized according to the different structure of POMs. This will provide a new strategy for further investigation of the catalytic application of Anderson-type POMs and the study of green catalysis. Full article

(This article belongs to the Special Issue Research on Polyoxometalate Materials)

► Show Figures

Journal Menu

Journal Browser

Research on Polyoxometalate Materials

Share This Special Issue

Special Issue Editor

Special Issue Information

Keywords

Published Papers (12 papers)

Editorial

Research

Review

Further Information

Guidelines

MDPI Initiatives

Follow MDPI