Mineralogy of the Supergene Zone

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Mineral Deposits".

Deadline for manuscript submissions: closed (31 December 2022) | Viewed by 2070

Special Issue Editors


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Guest Editor
Department of Geology, University of Namur, 5000 Namur, Belgium
Interests: Mn-Fe supergene deposits; Mn oxides; 40Ar/39Ar geochronology; geochemistry; weathering processes

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Guest Editor
Chrono-Environnement, Université Bourgogne Franche-Comté, 25000 Besancon, France
Interests: tectonics; structural geology; ore deposits; geodynamics; fold and thrust belts; stable isotopes

Special Issue Information

Dear Colleagues,

Supergene minerals form when rocks or buried primary orebodies are exposed at or near the Earth’s surface and undergo oxidation, dissolution and reconcentration of elements. These interactions lead “immobile” elements to be concentrated and the released mobile cations to be recombined, forming supergene minerals. Supergene fluids change the distribution patterns of many elements, which diversifies the class mineralogy. It offers potential new mineral species to be discovered. The study of these minerals is important to reveal key information about earth-surface processes: element mobility, meteoric fluid–rock interactions, the oxidation-reduction process, landscape evolution and geodynamics, and critical roles of global climate regulation. They are also natural scavengers of toxic elements released in the environment and potential hosts of strategic and precious metals. Supergene ore-forming minerals have an economic importance at the first stage of mining activity: they increase the ore grade and ease the extraction process. However, they remain understudied because of their complex mineralogy and are often considered as obstacles to metal recovery. This Special Issue is dedicated to this mineral group with a special focus on their mineralogy and processes that lead to their formation.

Dr. Augustin Dekoninck
Dr. Flavien Choulet
Guest Editors

Manuscript Submission Information

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Keywords

  • Supergene
  • Weathering
  • Mineralogy
  • Geochemistry
  • Geochronology
  • Ore deposit

Published Papers (1 paper)

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Research

17 pages, 9106 KiB  
Article
Unravelling the Temporal and Chemical Evolution of a Mineralizing Fluid in Karst-Hosted Deposits: A Record from Goethite in the High Atlas Foreland (Morocco)
by Michèle Verhaert, Cécile Gautheron, Augustin Dekoninck, Torsten Vennemann, Rosella Pinna-Jamme, Abdellah Mouttaqi and Johan Yans
Minerals 2022, 12(9), 1151; https://doi.org/10.3390/min12091151 - 11 Sep 2022
Cited by 1 | Viewed by 1546
Abstract
Timing and duration of ore deposit formation are crucial to understanding the mineralization process. To address this, the geochronological (U-Th)/He method, geochemical and H- and O-isotope compositions of pure goethite formed in the Imini karst-hosted Mn district (High Atlas, Morocco) were examined in [...] Read more.
Timing and duration of ore deposit formation are crucial to understanding the mineralization process. To address this, the geochronological (U-Th)/He method, geochemical and H- and O-isotope compositions of pure goethite formed in the Imini karst-hosted Mn district (High Atlas, Morocco) were examined in detail. Two main generations of cavity-filling and fracture-filling goethite are identified, and both precipitated prior to the massive Mn oxide ore. The δD and δ18O values reveal that the mineralizing fluid of cavity and fracture-filling goethite is meteoric-derived but enriched in 18O due to fluid–rock interactions with the host rock dolostone or mixing with O2-rich surface water resident in an open karst system. The cavity-filling goethite precipitated between 95 to 80 Ma, whereas fracture-filling goethite formed between 80 to 50 Ma. Ore deposition occurred discontinuously during the early Atlas doming associated with one or more early compressional events in the Atlas tectonism. The increase in δD values and depletion in U content result from a change in the mineralizing fluid within the karst system. At about 50 Ma, the fluid is notably enriched in U, Cu and trace metals. Full article
(This article belongs to the Special Issue Mineralogy of the Supergene Zone)
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