Mineralogy, Petrology, and Geochemistry of Minerals and Rocks in the Carpathians, 2nd Edition

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Mineral Geochemistry and Geochronology".

Deadline for manuscript submissions: closed (16 February 2024) | Viewed by 973

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Geophysics and Environmental Protection, Faculty of Geology, AGH University of Science and Technology, 30 Mickiewicz Av., 30-059 Krakow, Poland
Interests: crystallochemistry of sulphosalts; geochemistry; mineralogy and genesis of ore deposits; Nb-Ta mineralogy
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Dear Colleagues,

The Carpathians (1500 km) are the third-longest European mountain range after the Urals (2500 km) and the Scandinavian Mountains (1700 km). Geologically, the Carpathians are a young European mountain chain forming the eastward continuation of the Alps. The Carpathians are part of the Alpine-Carpathian belt and were formed during the Alpine orogeny in the Mesozoic and Tertiary by moving the ALCAPA, Tisza and Dacia plates over subducting oceanic crust. However, the Carpathians have their specifics in development and metamorphism, but also in mineral and rock composition.

For this Special Issue, we invite authors to submit papers on mineralogical, petrological, geochemical, and geochronological investigations of various rocks and minerals from the whole Carpathians region. We also welcome contributions that address these topics and compare the composition of minerals and rocks from the Carpathians with other regions of the world.

Dr. Jaroslav Pršek
Guest Editor

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Keywords

  • mineralogy
  • petrology
  • geochemistry
  • isotopic composition
  • minerals and rocks
  • ore deposits
  • carpathians

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Published Papers (1 paper)

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Research

21 pages, 7530 KiB  
Article
Ammonium-Bearing Fluorapophyllite-(K) in the Magnesian Skarns from Aleului Valley, Pietroasa, Romania
by Ştefan Marincea, Delia-Georgeta Dumitraş, Cristina Sava Ghineţ, Andra Elena Filiuţă, Fabrice Dal Bo, Frédéric Hatert and Gelu Costin
Minerals 2023, 13(11), 1362; https://doi.org/10.3390/min13111362 - 25 Oct 2023
Viewed by 687
Abstract
An ammonium-bearing fluorapophyllite-(K) occurs as a late hydrothermal product in the outer endoskarn zone from Aleului Valley (N 46°37′04″, E 22°35′22″), located at the contact of the granodiorite laccolith from Pietroasa, of Upper Cretaceous age, with Anisian dolostones. Associated minerals are wollastonite, K [...] Read more.
An ammonium-bearing fluorapophyllite-(K) occurs as a late hydrothermal product in the outer endoskarn zone from Aleului Valley (N 46°37′04″, E 22°35′22″), located at the contact of the granodiorite laccolith from Pietroasa, of Upper Cretaceous age, with Anisian dolostones. Associated minerals are wollastonite, K feldspar, diopside, fluorapatite, talc, and pectolite. The chemical structural formula is [K0.985Na0.012(NH4)0.076]Σ=1.073(Ca4.009Mn0.001Fe2+0.003Mg0.002Ba0.001)Σ=4.016(Si7.953Al0.047) O20.029[F0.899(OH)0.101]·8.059H2O. The structure was successfully refined as tetragonal, space group P4/mnc, with cell parameters of a = 8.9685(1) Å and c = 15.7885(5) Å. The indices of refraction are ω = 1.534(1) and ε = 1.536(1). The calculated density is Dx = 2.381 g/cm3, in good agreement with the measured density, Dm = 2.379(4) g/cm3. The thermal analysis shows that the mineral completely dehydrates at up to 450 °C (endothermic effects at 330, 371, and 448 °C) and loses ammonium at 634 °C. In the infrared spectra, the multiplicity of the bands assumed to be silicate modes (1ν1 + 3ν3 + 2ν2 + 3ν4) agrees with the reduction in the symmetry of the SiO44− ion from Td to Cδ. Fluorapophyllite-(K) from Aleului Valley is of late hydrothermal origin and crystallized from F-rich fluids originating from the granodiorite intrusion, which mobilized K, Ca, and Si from the pre-existing feldspar. Full article
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