Nanomaterial-Based Membranes and Applications

A special issue of Micromachines (ISSN 2072-666X). This special issue belongs to the section "D:Materials and Processing".

Deadline for manuscript submissions: closed (31 August 2023) | Viewed by 8395

Special Issue Editor


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Guest Editor
Department of Physics, Marshall University, Huntington, WV 25755, USA
Interests: nanotechnology; atomic force microscopy; nanoparticle membranes; slip length; line tension; water purification
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

Over the last decade, nanomaterial-based membranes have generated significant momentum in the scientific community and now stand at the forefront of many advanced separation technologies and applications. For example, as a result of an ever-increasing global population with regions of expanding industrialization in locations where water scarcity is already an issue, such nanomaterial-based membranes have demonstrated their potential to help meet the future demand for economical sources of freshwater. Similar to freshwater, fossil fuels have a limited global supply. Such nanomaterial-based membranes have advanced the development of fuel cells and energy storage devices that could work in conjunction with natural renewable energy sources, and these membranes have found further implementation in biosensors used to detect DNA. The potential and diversity of nanomaterial-based membranes are vast, as is their prospective application across many disciplines. Accordingly, this Special Issue will provide an overview of the latest innovative utilization techniques and recent developments of novel nanomaterial-based membranes, ranging from their use in the wastewater treatment and water purification, fuel cell, and pharmaceutical industries to the healthcare industry, highlighting all the new and exciting applications in between. Research papers, communications, and review articles are all welcome. 

Dr. Sean P. McBride
Guest Editor

Manuscript Submission Information

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Keywords

  • nanomaterial
  • membranes
  • wastewater treatment
  • water purification
  • freshwater
  • fuel cells
  • energy storage
  • renewable energy
  • biosensors
  • pharmaceutical
  • and healthcare industry

Published Papers (4 papers)

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Research

12 pages, 2454 KiB  
Article
A Closed Cavity Ultrasonic Resonator Formed by Graphene/PMMA Membrane for Acoustic Application
by Jing Xu, Graham S. Wood, Enrico Mastropaolo, Peter Lomax, Michael Newton and Rebecca Cheung
Micromachines 2023, 14(4), 810; https://doi.org/10.3390/mi14040810 - 01 Apr 2023
Cited by 1 | Viewed by 1288
Abstract
A graphene/poly(methyl methacrylate) (PMMA) closed cavity resonator with a resonant frequency at around 160 kHz has been fabricated. A six-layer graphene structure with a 450 nm PMMA laminated layer has been dry-transferred onto the closed cavity with an air gap of 105 μ [...] Read more.
A graphene/poly(methyl methacrylate) (PMMA) closed cavity resonator with a resonant frequency at around 160 kHz has been fabricated. A six-layer graphene structure with a 450 nm PMMA laminated layer has been dry-transferred onto the closed cavity with an air gap of 105 μm. The resonator has been actuated in an atmosphere and at room temperature by mechanical, electrostatic and electro-thermal methods. The (1,1) mode has been observed to dominate the resonance, which suggests that the graphene/PMMA membrane has been perfectly clamped and seals the closed cavity. The degree of linearity of the membrane’s displacement versus the actuation signal has been determined. The resonant frequency has been observed to be tuned to around 4% by applying an AC voltage through the membrane. The strain has been estimated to be around 0.08%. This research puts forward a graphene-based sensor design for acoustic sensing. Full article
(This article belongs to the Special Issue Nanomaterial-Based Membranes and Applications)
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12 pages, 3888 KiB  
Article
The Effect of Acetylene Carbon Black (ACB) Loaded on Polyacrylonitrile (PAN) Nanofiber Membrane Electrolyte for DSSC Applications
by Herlin Pujiarti, Zahrotul Ayu Pangestu, Nabella Sholeha, Nasikhudin Nasikhudin, Markus Diantoro, Joko Utomo and Muhammad Safwan Abd Aziz
Micromachines 2023, 14(2), 394; https://doi.org/10.3390/mi14020394 - 04 Feb 2023
Cited by 1 | Viewed by 1645
Abstract
Nanofiber membranes are starting to be used as an electrolyte storage medium because of their high porosity, which causes ionic conductivity, producing high energy. The ability of nanofiber membranes to absorb electrolytes proves their stability when used for a long time. In this [...] Read more.
Nanofiber membranes are starting to be used as an electrolyte storage medium because of their high porosity, which causes ionic conductivity, producing high energy. The ability of nanofiber membranes to absorb electrolytes proves their stability when used for a long time. In this study, the loading of acetylene carbon black (ACB) on polyacrylonitrile (PAN) is made by the electrospun method, which in turn is applied as an electrolyte medium in DSSC. Materials characterization was carried out through FTIR to determine the functional groups formed and SEM to observe morphology and diameter distribution. Furthermore, for DSSC performance, efficiency and EIS tests were carried out. The optimum nanofiber membrane was shown by esPACB1, with the highest efficiency reaching 1.92% with a porosity of 73.43%, nanofiber diameter of 172.9 ± 2.2 nm, an absorbance of 1850, and an electron lifetime of 0.003 ms. Full article
(This article belongs to the Special Issue Nanomaterial-Based Membranes and Applications)
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13 pages, 3407 KiB  
Article
Membrane Surface Modification via In Situ Grafting of GO/Pt Nanoparticles for Nitrate Removal with Anti-Biofouling Properties
by Mohammad Khajouei, Mahsa Najafi, Seyed Ahmad Jafari and Mohammad Latifi
Micromachines 2023, 14(1), 128; https://doi.org/10.3390/mi14010128 - 03 Jan 2023
Cited by 6 | Viewed by 1693
Abstract
Nanofiltration processes for the removal of emerging contaminants such as nitrate are a focus of attention of research works as an efficient technique for providing drinking water for people. Polysulfone (PSF) nanofiltration membranes containing graphene oxide (GO)/Pt (0, 0.25, 0.5, 0.75, 1 wt%) [...] Read more.
Nanofiltration processes for the removal of emerging contaminants such as nitrate are a focus of attention of research works as an efficient technique for providing drinking water for people. Polysulfone (PSF) nanofiltration membranes containing graphene oxide (GO)/Pt (0, 0.25, 0.5, 0.75, 1 wt%) nanoparticles were generated with the phase inversion pathway. The as-synthesized samples were characterized by FTIR, SEM, AFM, and contact angle tests to study the effect of GO/Pt on hydrophilicity and antibacterial characteristics. The results conveyed that insertion of GO/Pt dramatically improved the biofouling resistance of the membranes. Permeation experiments indicated that PSF membrane embracing 0.75 wt% GO/Pt nanoparticles had the highest nitrate flux and rejection ability. The membrane’s configuration was simulated using OPEN-MX simulating software indicating membranes maintaining 0.75 wt% of GO/Pt nanoparticles revealed the highest stability, which is well in accordance with experimental outcomes. Full article
(This article belongs to the Special Issue Nanomaterial-Based Membranes and Applications)
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25 pages, 7197 KiB  
Article
Azo-Dye-Functionalized Polycarbonate Membranes for Textile Dye and Nitrate Ion Removal
by Carrie Cockerham, Ashton Caruthers, Jeremy McCloud, Laura M. Fortner, Sungmin Youn and Sean P. McBride
Micromachines 2022, 13(4), 577; https://doi.org/10.3390/mi13040577 - 07 Apr 2022
Cited by 4 | Viewed by 2835
Abstract
Challenges exist in the wastewater treatment of dyes produced by the world’s growing textiles industry. Common problems facing traditional wastewater treatments include low retention values and breaking the chemical bonds of some dye molecules, which in some cases can release byproducts that can [...] Read more.
Challenges exist in the wastewater treatment of dyes produced by the world’s growing textiles industry. Common problems facing traditional wastewater treatments include low retention values and breaking the chemical bonds of some dye molecules, which in some cases can release byproducts that can be more harmful than the original dye. This research illustrates that track-etched polycarbonate filtration membranes with 100-nanometer diameter holes can be functionalized with azo dye direct red 80 at 1000 µM, creating a filter that can then be used to remove the entire negatively charged azo dye molecule for a 50 µM solution of the same dye, with a rejection value of 96.4 ± 1.4%, at a stable flow rate of 114 ± 5 µL/min post-functionalization. Post-functionalization, Na+ and NO3 ions had on average 17.9%, 26.0%, and 31.1% rejection for 750, 500, and 250 µM sodium nitrate solutions, respectively, at an average flow rate of 177 ± 5 µL/min. Post-functionalization, similar 50 µM azo dyes had increases in rejection from 26.3% to 53.2%. Rejection measurements were made using ultraviolet visible-light spectroscopy for dyes, and concentration meters using ion selective electrodes for Na+ and NO3 ions. Full article
(This article belongs to the Special Issue Nanomaterial-Based Membranes and Applications)
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