Technologies of Coatings and Surface Hardening for Tool Industry III

A special issue of Coatings (ISSN 2079-6412). This special issue belongs to the section "Surface Characterization, Deposition and Modification".

Deadline for manuscript submissions: closed (31 December 2023) | Viewed by 5492

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Guest Editor
Department of High-Efficiency Machining Technologies, Moscow State University of Technology STANKIN, 127055 Moscow, Russia
Interests: processing by concentrated energy flows; laser processing; electrophysical machining; heat and hardening treatment; surface finishing and coating; powder metallurgy; nanomaterials; nanocoatings and thin films; thermal spray technologies; process diagnostics and monitoring
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Special Issue Information

Dear Colleagues,

The innovative coating and surface-hardening technologies developed in recent years making it possible to obtain practically any complex of physical–mechanical and crystal–chemical properties of the metalworking tool surface layer. Today, the scientific approach related to the improvement of the operational characteristics of the tool surface layers produced from traditional materials in the tool industry, following the creation of new instrumental materials, is an extremely costly and time-consuming process. Different technological techniques, such as coatings (physical and chemical methods), surface hardening and alloying (chemical–thermal treatment, implantation), a combination of the above, and other solutions are used for this. Further, diversified energy sources (vacuum arc, laser beam, etc.) and varied working media (vacuum, gas–vapor medium, liquid solutions, etc.) can be used for coating and surface hardening.

The high efficiency of this approach may be explained by the fact that under the diversified operating conditions of the metalworking tool; in all cases, the most loaded is its surface layer. First, its specific properties define the workability of the tool piece during the machining of a part. It is evident that there is no all-purpose method for coating and surface hardening. Everything is very particular for each type of tool piece and its operating conditions.

It should additionally be emphasized that the metalworking tool as an object of research was not chosen accidentally. Production experience shows that even with the use of the most advanced machine tools it is not possible to achieve high technical and economical rates of the machining process of the part with a low work resource of the tool. Diverse conditions of the tool’s operation bring on diverse injuries and failures of the technological system. At the same time, the wear rate of the tool is significantly higher than the wear rate of the machine tool’s parts and units. Therefore, the operational ability of the technological system as a whole depends precisely on the used metalworking cutting and die tool. The roles of the tool multiply when it comes to machining composite materials, high-hardened steels, chrome-nickel, titanium, or other hard-to-machine alloys.

The aim of this Special Issue is to provide a review of the current state of the research and developments in the field of coatings and surface hardening technologies for cutting and die tools that can ensure a substantial increase of the work resource and reliability of the tool; an increase in productivity of machining, accuracy, and quality of the machined products; reduction of the material capacity of the production; and other important manufacturing factors. The main emphasis should be on the results of the engineering works that have had success in laboratory or real manufacturing conditions.

Some of the topics of particular interest to the Special Issue are as follows:

  • Development of self-adaptation in the process of contact interaction with machining material coatings through the formation of solid lubricants based on oxides and other compounds;
  • Development of coatings and processes of the surface hardening of a tool intended for the formation of hard-to-process materials such as composite materials, high-hardened steels, chrome–nickel, titanium, and other alloys with unique properties;
  • Application of diverse concentrated flows of energy (vacuum arc, laser beam, etc.) for the implementation of new coating processes and surface hardening of tools, including combined processes;
  • Original technology equipment and setups for coatings and surface hardening of tools, including low-temperature techniques;
  • Study of the influences of the physical–mechanical and crystal–chemical properties of the surface layer transformed by coatings and surface hardening on the stress–strain state and character of the tool wear in the conditions of action of the various heat and force loads;
  • Certification and testing methods for tools after coating and surface hardening;
  • Successful experience of the leading production enterprises in the introduction of innovative technologies for coating and surface hardening cutting and die tools.

Prof. Dr. Sergey N. Grigoriev
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Coatings is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Published Papers (6 papers)

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Research

12 pages, 4171 KiB  
Article
Finite Element Simulation of Orthogonal Cutting of H13-Hardened Steel to Evaluate the Influence of Coatings on Cutting Temperature
by Guangchao Hao, Aijun Tang, Zhenzhong Zhang, Hongyu Xing, Nan Xu and Ran Duan
Coatings 2024, 14(3), 293; https://doi.org/10.3390/coatings14030293 - 28 Feb 2024
Viewed by 664
Abstract
High cutting temperatures increase tool wear and reduce tool life. To achieve a longer tool life, coated carbide tools have been developed. In this study, the influence of tool coatings on the cutting temperature distribution during the orthogonal cutting of H13-hardened steel is [...] Read more.
High cutting temperatures increase tool wear and reduce tool life. To achieve a longer tool life, coated carbide tools have been developed. In this study, the influence of tool coatings on the cutting temperature distribution during the orthogonal cutting of H13-hardened steel is investigated. Firstly, four coating materials, including TiC, TiN, Al2O3, and TiAlN, with the same coating thickness, are selected to evaluate the effects of coating materials on cutting temperature with finite element simulation. The maximum temperatures at the tool rake face and the temperatures at the coating–substrate interface are evaluated. It was found that the maximum temperatures at the tool rake face were the lowest and the highest when TiN and Al2O3 coating materials were applied, respectively. The TiAlN coating material had the best thermal barrier property. Then, the temperature distribution along the direction perpendicular to the tool rake face is investigated for TiAlN-coated tools with different coating thicknesses ranging from 3 μm to 10 μm. It is shown that the temperature gradient increases with the coating thickness. The coating thickness should be kept below 5 μm. Finally, cutting experiments validate the availability of the finite element model. Full article
(This article belongs to the Special Issue Technologies of Coatings and Surface Hardening for Tool Industry III)
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22 pages, 22043 KiB  
Article
Development of Multicomponent Nanostructured Nitride Coatings to Protect against Corrosion Products from Titanium Alloy
by Alexey Vereschaka, Nikolai Cherenda, Catherine Sotova, Vladimir Uglov, Olga Reva, Anna Basalai, Alexander Isobello and Natalia Baranova
Coatings 2023, 13(12), 2028; https://doi.org/10.3390/coatings13122028 - 30 Nov 2023
Viewed by 744
Abstract
Phase-structural characteristics and the corrosion resistance of coatings ZrN, (Zr,Ti)N, (Zr,Hf)N, (Zr,Nb)N, (Ti,Zr,Hf)N and (Ti,Zr,Nb)N, which were deposited on a Ti6Al-4V titanium alloy substrate, were investigated. It was found that the titanium substrate has a crystalline structure, including grains with high (up to [...] Read more.
Phase-structural characteristics and the corrosion resistance of coatings ZrN, (Zr,Ti)N, (Zr,Hf)N, (Zr,Nb)N, (Ti,Zr,Hf)N and (Ti,Zr,Nb)N, which were deposited on a Ti6Al-4V titanium alloy substrate, were investigated. It was found that the titanium substrate has a crystalline structure, including grains with high (up to 24 at.%) and low (less than 2 at.%) vanadium content. Thus, during the deposition process, the coating can form adhesive bonds with local areas of the substrate that have quite different compositions. The diffusion of the coating elements into the substrate takes place up to a depth of 200 nm. The diffusion of titanium alloy elements (primarily titanium and vanadium) into the adhesive sublayer of the coating to a depth of 100 nm is also observed. Corrosion studies were carried out in 1M solutions with acidic (H2SO4), alkaline (NaOH) and neutral (NaCl) media at a constant temperature of 50 °C. The actual change in the mass of the samples during corrosion tests is extremely small. The protective coatings under study have very high anti-corrosion characteristics and practically do not react with solutions that imitate the liquid environments of the human body. Full article
(This article belongs to the Special Issue Technologies of Coatings and Surface Hardening for Tool Industry III)
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23 pages, 47462 KiB  
Article
Effect of Surface Modification via Laser Irradiation on the Operability of Carbide End Mills When Cutting Aircraft Alloys
by Andrey V. Gusarov, Mars S. Migranov, Artem P. Mitrofanov, Andrey S. Gusev, Artur M. Migranov and Roman S. Khmyrov
Coatings 2023, 13(11), 1823; https://doi.org/10.3390/coatings13111823 - 24 Oct 2023
Viewed by 833
Abstract
In modern aviation production, innovative hard-to-machine materials with unique physical and mechanical properties are being used increasingly. When processing such materials, the weakest link in the technological chain of production is the metal-cutting tool. In this paper, to improve the efficiency of the [...] Read more.
In modern aviation production, innovative hard-to-machine materials with unique physical and mechanical properties are being used increasingly. When processing such materials, the weakest link in the technological chain of production is the metal-cutting tool. In this paper, to improve the efficiency of the blade cutting of heat-resistant alloys, we propose the use of nanostructured multilayer wear-resistant coatings with subsequent laser processing of the cutting surfaces of the end milling cutters according to various schemes. In this case, an increase in the wear-resistant properties of the cutting edge by 15%–20% is provided due to the formation, at high temperatures, of secondary structures with increased wear resistance and a reduction of the temperature and force loading of contact processes. Methodologically, the work was carried out in several consecutive stages: the first stage was the determination of effective grades of wear-resistant coatings obtained via various installations with their subsequent laser processing during the «SharpMark™ Fiber» installation; at the second stage tribotechnical tests were carried out during the tribometer and adhesion installation; and in the third stage wear-resistant, temperature-force tests were carried out using milling machines in various cutting modes. According to the results of the field tests, the tool durability period was increased by 15%–20%. Full article
(This article belongs to the Special Issue Technologies of Coatings and Surface Hardening for Tool Industry III)
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23 pages, 12284 KiB  
Article
Influence of Cr-Al-Si-N and DLC-Si Thin Coatings on Wear Resistance of Titanium Alloy Samples with Different Surface Conditions
by Marina A. Volosova, Maxim A. Lyakhovetsky, Artem P. Mitrofanov, Yury A. Melnik, Anna A. Okunkova and Sergey V. Fedorov
Coatings 2023, 13(9), 1581; https://doi.org/10.3390/coatings13091581 - 11 Sep 2023
Cited by 1 | Viewed by 910
Abstract
The influence of Cr-Al-Si-N, DLC-Si, and Cr-Al-Si-N/DLC-Si thin coatings deposited on titanium alloy (Ti-Al-Zr-Sn-Nb system) samples with different surface reliefs on wear resistance under abrasion and fretting conditions was investigated. The influence of coatings on the initial microrelief after finishing milling and lapping [...] Read more.
The influence of Cr-Al-Si-N, DLC-Si, and Cr-Al-Si-N/DLC-Si thin coatings deposited on titanium alloy (Ti-Al-Zr-Sn-Nb system) samples with different surface reliefs on wear resistance under abrasion and fretting conditions was investigated. The influence of coatings on the initial microrelief after finishing milling and lapping with micro-grained abrasive was studied by profilometry. The Martens hardness (H) and the elastic modulus (E) were determined through nanoindentation. The H/E ratio was 0.08, 0.09, and 0.13, respectively. The adhesion bond strength and H/E ratio relationship was revealed using a scratch testing analysis. Volumetric wear after 20 min of abrasive exposure was reduced by 11, 25, and 31 times for Cr-Al-Si-N, DLC-Si, and Cr-Al-Si-N/DLC-Si coatings compared to uncoated ones after milling and by 15, 32, and 35 times after lapping. Volumetric wear under fretting conditions was reduced by 1.8 and 4 times for Cr-Al-Si-N coating after milling and lapping. It was reduced by tens of times for DLC-Si coating and by hundreds of times for Cr-Al-Si-N/DLC-Si coating. The Cr-Al-Si-N/DLC-Si coating (a thickness of 3.1 ± 0.15/2.0 ± 0.1 µm) is characterized by the best combination of hardness (24 ± 1 GPa), elastic modulus (185 ± 8 GPa), and friction coefficient (0.04–0.05 after milling and 0.1 after lapping) and ensures maximum wear resistance under a wide range of loads. The novelty of the work is that those coatings were not practically under study concerning the deposition on the titanium alloy regarding typical mechanical loads such as abrasive and fretting wear but are of interest to the aviation and aerospace industry. Full article
(This article belongs to the Special Issue Technologies of Coatings and Surface Hardening for Tool Industry III)
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11 pages, 4301 KiB  
Article
Investigation of the Structure and Properties of Molybdenum Coatings Produced by Laser-Directed Energy Deposition
by Tatiana Tarasova, Marina Volosova, Andrey Skorobogatov, Sergey Voldemarovich Fedorov, Pavel Podrabinnik, Andrey Kholopov and Sergey N. Grigoriev
Coatings 2023, 13(8), 1365; https://doi.org/10.3390/coatings13081365 - 03 Aug 2023
Viewed by 705
Abstract
The paper considers the possibility of replacing the process of conventional vacuum brazing of a molybdenum plate on carbon steel using copper brazing with the process of laser-directed energy deposition of domestically produced molybdenum powder. The research task is motivated by the demand [...] Read more.
The paper considers the possibility of replacing the process of conventional vacuum brazing of a molybdenum plate on carbon steel using copper brazing with the process of laser-directed energy deposition of domestically produced molybdenum powder. The research task is motivated by the demand for removing low-melting copper brazing from molybdenum coatings on carbon steel. The parameters for the process of manufacturing molybdenum coatings using the additive technology of laser-directed energy deposition (LDED), which provides the required operational properties without further processing, have been developed. A study of the microstructure of the coating was carried out, including an examination of the distribution of the main elements over the depth of the coating. We established the preferred parameters of laser-directed energy deposition, which provide a high-quality deposited layer of Mo on the 25L carbon steel. The wear resistance of the coatings was examined following the «ball-on-disc» scheme according to the ASTM G99 standard. The results show that wear rate of the brazed Mo plate is higher than that of the deposited Mo layer on the 25L carbon steel substrate. Full article
(This article belongs to the Special Issue Technologies of Coatings and Surface Hardening for Tool Industry III)
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14 pages, 5395 KiB  
Article
Removal of Wear-Resistant Coatings from Cutting Tools by Fast Argon Atoms
by Alexander S. Metel, Marina A. Volosova, Yury A. Melnik, Enver S. Mustafaev and Sergey N. Grigoriev
Coatings 2023, 13(6), 999; https://doi.org/10.3390/coatings13060999 - 28 May 2023
Cited by 2 | Viewed by 1060
Abstract
Wear-resistant coatings improve the machining capability of cutting tools and extend their useful life. However, when a tool needs to be reused, it is mandatory to remove the existing coating to facilitate resharpening and recoating. The existing technique uses electrochemical stripping, which is [...] Read more.
Wear-resistant coatings improve the machining capability of cutting tools and extend their useful life. However, when a tool needs to be reused, it is mandatory to remove the existing coating to facilitate resharpening and recoating. The existing technique uses electrochemical stripping, which is hazardous to the environment. The environmentally friendly pulsed laser stripping causes the melting and mixing of tools and coating materials, which makes it difficult to separate and remove the coating. This paper presents the results of coating stripping via a beam of fast argon atoms. Due to the twentyfold compression of the beam, a 3 µm thick AlTiN coating was removed from a rotating solid carbide end mill within 25 min. A subsequent one-hour-long irradiation of the cleaned tool with the same beam led to a decrease in the radius of the tool’s cutting edges from 10.5 to 3.5 µm. This allowed us to redeposit a 3.5 µm thick AlTiN coating and obtain a coated end mill with a cutting-edge radius of 7 µm. Full article
(This article belongs to the Special Issue Technologies of Coatings and Surface Hardening for Tool Industry III)
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