Special Issue "Investigation on Corrosion Behaviour of Metallic Materials"

A special issue of Coatings (ISSN 2079-6412). This special issue belongs to the section "Corrosion, Wear and Erosion".

Deadline for manuscript submissions: 10 July 2024 | Viewed by 3042

Special Issue Editors

Faculty of Mechanical Engineering and Naval Architecture, University of Zagreb, Ivana Lučića 5, 10000 Zagreb, Croatia
Interests: stainless steels; coatings; design consideration

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Assistant Guest Editor
Faculty of Mechanical Engineering and Naval Architecture, University of Zagreb, 10000 Zagreb, Croatia
Interests: aluminium alloys; corrosion inhibitors; stainless steels; coatings

Special Issue Information

Dear Colleagues,

Historically speaking, the intensive development and the aspiration of humanity to convert available natural resources into various products and thus meet the needs of modern humankind causes a daily growing range of pressures on all aspects of the environment and thus suppresses ecological awareness as part of social awareness determined by the historical state and degree of social development. The task of every modern society is therefore the introduction of ecological criteria and standards in all spheres of life and their support, especially in the areas of production, transport, culture and politics, in order to protect human health and life on Earth. A significant part of environmental problems can be solved by improving existing or applying modern harmless technologies, while the other part must be solved by changes in menkind's understanding and understanding of the possibilities and needs of living, thus creating a foundation for a reasonable, responsible, sustainable and harmonious relationship between man and the environment. The importance of the application of modern scientific knowledge about materials and their protection technology is represented by an unavoidable set of procedures and methods necessary to achieve a sophisticated way of designing, exploitation and maintenance, while at the same time, generating, understanding and structuring them directs production towards more environmentally friendly production processes and protection systems of materials, and ensures that the exploited material is reused after the recycling process.

Since nowadays corrosion destruction of metallic materials is one of the key factors in economic, safety and environmental issues, which has significantly increased interest in this topic, modern solutions of corrosion reduction should be based on the application of highly effective and environmentally friendly solutions, such as green corrosion inhibitors. Their extreme effectiveness and multifunctionality, in addition to individual application, is a fundamental determinant of other surface protection systems, such as conventional and self-healing coatings, so it is not surprising that the great interest of academic and industrial communities encourages a great amount of scientific research in order to find an inhibitor with a wide application area, which at the same time affects the self-sustainability of protective surface systems. Since such sustainable innovations can generally be broadly ranked from incremental to transformative, with each category having its own typical improvement potential, timescale, technological and operational challenges, global research activities are largely focused on the intensive improvement of such modern systems.

The potential topics are:

  • Commercial application of "Rare-Earth" elements as a promising and environmentally friendly representative of next-generation corrosion inhibitors
  • Influence of exploitation parameters on the corrosion resistance of aluminum alloys in aviation
  • Modification of the surface layers of metal materials by the process of heat treatment in order to achieve greater hardness and corrosion resistance of metallic substrates.
  • Recent developments of protection of metal materials obtained by wire and electric arc additive manufacturing (WAAM)
  • Encapsulation and integration of lanthanide compounds in a porous anodized passive film.

We look forward to receiving your contributions.

Dr. Biserka Runje
Guest Editor

Dr. Marin Kurtela
Assistant Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Coatings is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • green corrosion inhibitors
  • corrosion resistance
  • wire and electric arc additive manufacturing
  • surface modification of metals
  • multifunctional anodized coatings

Published Papers (4 papers)

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Research

Article
Experimental Study of Atmospherically and Infrared-Dried Industrial Topcoats
Coatings 2023, 13(8), 1343; https://doi.org/10.3390/coatings13081343 - 30 Jul 2023
Viewed by 461
Abstract
In this paper, five different solvent-borne industrial topcoats were dried with infrared (IR) radiation and under atmospheric conditions. A comparison of physical, mechanical, chemical, and electrochemical properties of differently dried topcoats was made. The results of differential scanning calorimetry (DSC), Fourier-Transform Infrared Spectroscopy [...] Read more.
In this paper, five different solvent-borne industrial topcoats were dried with infrared (IR) radiation and under atmospheric conditions. A comparison of physical, mechanical, chemical, and electrochemical properties of differently dried topcoats was made. The results of differential scanning calorimetry (DSC), Fourier-Transform Infrared Spectroscopy (FTIR), and adhesion of a topcoat to the metal substrate (determined by the pull-off test) indicate a higher degree of crosslinking of examined topcoats, which improves the coating’s protective properties. Scratch hardness was determined by the pencil hardness test. Impact resistance was examined with a falling-weight test. Changes in the shade of the coating were examined by visual inspection and using a gloss meter. The electrochemical measurements of open circuit potential (OCP) and electrochemical impedance spectroscopy (EIS) were conducted. The thermal stability of topcoats was tested by thermogravimetric analysis (TGA). The results show overall better properties of IR-dried topcoats. In addition, topcoats dry significantly faster when IR radiation is applied, which makes this drying method very interesting for industrial application. Full article
(This article belongs to the Special Issue Investigation on Corrosion Behaviour of Metallic Materials)
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Article
Epoxy Coating Modification with Metal Nanoparticles to Improve the Anticorrosion, Migration, and Antibacterial Properties
Coatings 2023, 13(7), 1201; https://doi.org/10.3390/coatings13071201 - 04 Jul 2023
Viewed by 554
Abstract
Nanoparticles are capable of making more durable and stronger materials with better chemical resistance. They are used for a wide range of applications. Likewise, the potential of metal nanoparticles as antimicrobial agents has been widely studied. In this work, we investigate various nanoparticles [...] Read more.
Nanoparticles are capable of making more durable and stronger materials with better chemical resistance. They are used for a wide range of applications. Likewise, the potential of metal nanoparticles as antimicrobial agents has been widely studied. In this work, we investigate various nanoparticles (Al, Ni, Ag) incorporated into epoxy coating. The anticorrosion and antibacterial properties of the unmodified and modified coatings were evaluated. According to the SEM and EDS analyses, the coating did not contain agglomerates, which confirms the quality of the dispersion of inorganic nanoparticles in the coating. After 24 h and 10days immersions in a 3.5 wt.% NaCl solution, the corrosion behaviour for all nanocomposite was studied by means of EIS investigations. The study included the evaluation of the inhibition zone of the nanoparticles and the antimicrobial properties of the nanocomposite. It was found that the nanoparticles of Al and Ag provide excellent antibacterial properties. The epoxy nanocomposite with Al NP showed the migration of ions in the range from 0.75 to 1 mg/L in a wastewater solution for 30 days, indicating a potential for antimicrobe activity. The 1% Al NP epoxy nanocomposite showed good anticorrosion and antibacterial properties and demonstrated great potential for applications in pipelines. Full article
(This article belongs to the Special Issue Investigation on Corrosion Behaviour of Metallic Materials)
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Article
Anticorrosion and Antibacterial Properties of Al NP–Epoxy Nanocomposite Coating on Grey Cast Iron
Coatings 2023, 13(5), 898; https://doi.org/10.3390/coatings13050898 - 10 May 2023
Cited by 1 | Viewed by 1021
Abstract
In this study, different concentrations of aluminium nanoparticles (Al NP) were incorporated into epoxy resin and epoxy paint. Here, we present a detailed systematic study of different methods of incorporating inorganic nanoparticles into epoxy coating. This work aims to obtain an epoxy coating [...] Read more.
In this study, different concentrations of aluminium nanoparticles (Al NP) were incorporated into epoxy resin and epoxy paint. Here, we present a detailed systematic study of different methods of incorporating inorganic nanoparticles into epoxy coating. This work aims to obtain an epoxy coating with anticorrosion and antibacterial properties. The physical properties of coatings such as thickness, hardness, colour, and adhesion did not change with the addition of nanoparticles. According to the SEM and EDS analyses, the distribution effect of Al NPs in epoxy coating was better with ultrasonic homogenisation than with mechanical stirring. The EIS and SECM measurements were used to investigate corrosion resistance. The coating with 1.0 wt.% Al NP showed the best physical and chemical properties. SECM examination indicated that nanoparticles in epoxy resin increase the protection efficiency by 25.75% and in the epoxy paint by 40.89%. The results also showed the antibacterial activity of aluminium nanoparticles by inhibiting the growth of biofilm-forming bacteria such as P. aeruginosa and B. subtilis. Full article
(This article belongs to the Special Issue Investigation on Corrosion Behaviour of Metallic Materials)
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Article
Localized Corrosion Mechanism of Q125 Casing Steel in Residual Acid Solution during Oil Reservoir Acidizing
Coatings 2023, 13(4), 710; https://doi.org/10.3390/coatings13040710 - 31 Mar 2023
Cited by 1 | Viewed by 726
Abstract
This paper aims to investigate the localized corrosion mechanism of Q125 casing steel in residual acid solution with Mannich base type inhibitors during oil reservoir acidizing process. The corrosion behavior of Q125 casing steel in fresh acid (20% HCl) and residual acid solution [...] Read more.
This paper aims to investigate the localized corrosion mechanism of Q125 casing steel in residual acid solution with Mannich base type inhibitors during oil reservoir acidizing process. The corrosion behavior of Q125 casing steel in fresh acid (20% HCl) and residual acid solution (pH 1.0 and pH 3.0 HCl) with and without 3-(4-chlorophenylimino)-1-(piperidine-1-ylmethyl) indolin-2-one (Mannich base type, Mb) inhibitor was studied by electrochemical test, weight loss, and surface analysis. The morphology and composition of corrosion products were analyzed by SEM/EDS and XPS; the local corrosion rate of casing steel with or without inhibitor was obtained by 3D profilometry. It was determined that the inhibitor had higher inhibition efficiency in fresh acid conditions than in residual acid conditions. Under the condition of residual acid, the decrease in inhibitor molecular coverage on the substrate surface promotes the occurrence of local corrosion. Pitting corrosion was detected in the residual acid solution containing Mannich base inhibitor, which may be related to the fact that FeCO3 hinders the adsorption of inhibitor molecules on the substrate surface. Full article
(This article belongs to the Special Issue Investigation on Corrosion Behaviour of Metallic Materials)
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