Recent Advancements in the Synthesis and Application of Carbon-Based Catalysts in the ORR
Abstract
:1. Introduction
2. Carbon Sources for Electrocatalysts
2.1. Biomass
2.2. Naturally Occurring Materials
2.3. Chemically Synthesized Starting Materials
3. Doping Methods
3.1. Nonmetal Heteroatoms
3.1.1. N-Doping
3.1.2. P-Doping
3.1.3. S-Doping
3.1.4. Co-Doped or Tri-Doped
3.2. Metal Doping
4. Synthetic Methods of Carbon Materials
4.1. Microwave
4.2. Hydrothermal and Pyrolysis
4.3. Templated Methods
5. Physical Property Influence on Electrocatalytic Performance
5.1. Surface Area
5.2. Pore Size
5.3. Elemental Composition
5.4. Morphology
6. Advances in Electrolytes/Membranes Used for Fuel Cell Applications
6.1. Polymer Electrolyte
6.2. Solid Oxides
6.3. Molten Carbonate
6.4. Alkaline Electrolyte
7. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Template | Sample | Onset Potential (V vs. RHE) | Electron Transfer | Electrolyte | Ref. |
---|---|---|---|---|---|
NaCl and ZnCl2 | N, S, and Cl tri-doped porous carbon | 0.892 | 3.93 | HClO4 | [84] |
NaCl and Fe3O4 NPs | Fe, N, and S tri-doped carbon | 0.932 | 3.95 | HClO4 | [85] |
NaCl and Fe3O4 NPs | N and S co-doped carbon | 0.878 | 3.9 | HClO4 | [85] |
Silica | Porous N and S co-doped carbon spheres | 1.00 | 3.94 | KOH | [86] |
Silica and MOF | Fe and N co-doped carbon | 1.02 | 4 | KOH | [87] |
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Macchi, S.; Denmark, I.; Le, T.; Forson, M.; Bashiru, M.; Jalihal, A.; Siraj, N. Recent Advancements in the Synthesis and Application of Carbon-Based Catalysts in the ORR. Electrochem 2022, 3, 1-27. https://doi.org/10.3390/electrochem3010001
Macchi S, Denmark I, Le T, Forson M, Bashiru M, Jalihal A, Siraj N. Recent Advancements in the Synthesis and Application of Carbon-Based Catalysts in the ORR. Electrochem. 2022; 3(1):1-27. https://doi.org/10.3390/electrochem3010001
Chicago/Turabian StyleMacchi, Samantha, Iris Denmark, Thuy Le, Mavis Forson, Mujeebat Bashiru, Amanda Jalihal, and Noureen Siraj. 2022. "Recent Advancements in the Synthesis and Application of Carbon-Based Catalysts in the ORR" Electrochem 3, no. 1: 1-27. https://doi.org/10.3390/electrochem3010001