Sulfonated Hydrogel Formed via CO2-in-Water Emulsion: Potential in Antibiotic Removal
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation of the Monolith
2.3. Characterization
2.4. Swelling Behavior
2.5. Mechanical Property
2.6. Adsorption Process
3. Results and Discussion
3.1. Characterization of COS-Based Monoliths
3.2. Swelling Property
3.3. Mechanical Properties of the Monoliths
3.4. Adsorption Properties
3.5. State-of-the-Art Comparison of the TC Adsorbents
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Entry | PVA b | COS | MBA | CO2 | H2O |
---|---|---|---|---|---|
(%, w/v) | (g) | (%, w/v) | (MPa) | (mL) | |
SHC0 | 5 | 0 | 8 | 10 ± 2 | 15 |
SHC0.1 | 5 | 0.1 | 8 | 10 ± 2 | 15 |
SHC0.1 c | 5 | 0.1 | 8 | 12 ± 2 c | 15 |
SHC0.2 | 5 | 0.2 | 8 | 10 ± 2 | 15 |
SHC0.3 | 5 | 0.3 | 8 | 10 ± 2 | 15 |
SHC0.4 | 5 | 0.4 | 8 | 10 ± 2 | 15 |
Pseudo-First-Order | Pseudo-Second-Order | Elovich | ||||||
---|---|---|---|---|---|---|---|---|
Qe | K1 | R2 | Qe | K2 | R2 | α | β | R2 |
(mg·g−1) | (min−1) | (mg·g−1) | (mg−1·g·min−1) | (mg·g−1·min−1) | (g·mg−1) | |||
174.3 | 0.010 | 0.956 | 211.4 | 0.7 × 10−3 | 0.996 | 6.20 | 0.021 | 0.984 |
Intra-particle diffusion | ||||||||
Kd1 | R2 | Kd1 | R2 | |||||
(mg·g−1·min−1/2) | (mg·g−1·min−1/2) | |||||||
11.68 | 0.992 | 4.95 | 0.992 | |||||
Langmuir | Freundlich | Temkin | ||||||
KL | qm | R2 | Kf | n | R2 | Kt | f | R2 |
(L·mg−1) | (mg g−1) | (J·mol−1) | ||||||
1.37 × 10−3 | 1981.4 | 0.978 | 35.64 | 1.56 | 0.837 | 489.17 | 0.102 | 0.954 |
T(K) | Kc | −ΔG (KJ·mol−1) | −ΔH (KJ·mol−1) | −ΔS (J·mol−1·k−1) |
---|---|---|---|---|
298 | 172.4 | 12.7 | 22.4 | 32.5 |
310 | 122.7 | 12.3 | ||
321 | 91.8 | 12.1 | ||
333 | 66.0 | 11.6 |
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Xu, K.; Cao, L. Sulfonated Hydrogel Formed via CO2-in-Water Emulsion: Potential in Antibiotic Removal. Gels 2023, 9, 703. https://doi.org/10.3390/gels9090703
Xu K, Cao L. Sulfonated Hydrogel Formed via CO2-in-Water Emulsion: Potential in Antibiotic Removal. Gels. 2023; 9(9):703. https://doi.org/10.3390/gels9090703
Chicago/Turabian StyleXu, Kaibo, and Liqin Cao. 2023. "Sulfonated Hydrogel Formed via CO2-in-Water Emulsion: Potential in Antibiotic Removal" Gels 9, no. 9: 703. https://doi.org/10.3390/gels9090703