Dehydrogenation of Ethylene on Supported Palladium Nanoparticles: A Double View from Metal and Hydrocarbon Sides
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. In Situ XAFS and XRD Measurements and Analysis
2.3. In Situ DRIFTS Measurements
2.4. DFT Calculations
3. Results
3.1. Evolution of the Bulk Structure of the NPs
3.2. Detection of Surface Species by In Situ DRIFTS
3.3. DFT Relaxation of CnHm on Pd Surfaces and Their Vibrational Spectra
4. Discussion
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Usoltsev, O.A.; Pnevskaya, A.Y.; Kamyshova, E.G.; Tereshchenko, A.A.; Skorynina, A.A.; Zhang, W.; Yao, T.; Bugaev, A.L.; Soldatov, A.V. Dehydrogenation of Ethylene on Supported Palladium Nanoparticles: A Double View from Metal and Hydrocarbon Sides. Nanomaterials 2020, 10, 1643. https://doi.org/10.3390/nano10091643
Usoltsev OA, Pnevskaya AY, Kamyshova EG, Tereshchenko AA, Skorynina AA, Zhang W, Yao T, Bugaev AL, Soldatov AV. Dehydrogenation of Ethylene on Supported Palladium Nanoparticles: A Double View from Metal and Hydrocarbon Sides. Nanomaterials. 2020; 10(9):1643. https://doi.org/10.3390/nano10091643
Chicago/Turabian StyleUsoltsev, Oleg A., Anna Yu. Pnevskaya, Elizaveta G. Kamyshova, Andrei A. Tereshchenko, Alina A. Skorynina, Wei Zhang, Tao Yao, Aram L. Bugaev, and Alexander V. Soldatov. 2020. "Dehydrogenation of Ethylene on Supported Palladium Nanoparticles: A Double View from Metal and Hydrocarbon Sides" Nanomaterials 10, no. 9: 1643. https://doi.org/10.3390/nano10091643