Nanomaterials

14 pages, 2505 KiB

Open AccessArticle

Metal Organic Framework Derived MnO₂-Carbon Nanotubes for Efficient Oxygen Reduction Reaction and Arsenic Removal from Contaminated Water

by Vadahanambi Sridhar, Inwon Lee, Kwang Hyo Jung and Hyun Park

Nanomaterials 2020, 10(9), 1895; https://doi.org/10.3390/nano10091895 - 22 Sep 2020

Cited by 6 | Viewed by 3841

Abstract

Even though manganese oxides are attractive materials for batteries, super-capacitors and electro-catalysts for oxygen reduction reactions, in most practical applications MnO₂ needs to be hybridized with conductive carbon nano-structures to overcome its inherent poor electrical conductivity. In this manuscript we report microwave-assisted [...] Read more.

Even though manganese oxides are attractive materials for batteries, super-capacitors and electro-catalysts for oxygen reduction reactions, in most practical applications MnO₂ needs to be hybridized with conductive carbon nano-structures to overcome its inherent poor electrical conductivity. In this manuscript we report microwave-assisted synthesis of MnO₂ embedded carbon nanotubes (MnO₂@CNT) from Mn-H₃BTC (benzene-1,3,5-carboxylic acid) metal organic frameworks (MOF) precursors. Using graphene oxide as microwave susceptible surface, MnO₂ nano-particles embedded in three dimensional reduced graphene oxide (rGO) -CNT frameworks (MnO₂@CNT-rGO) were synthesized which when applied as electro-catalysts in oxygen reduction reaction (ORR) demonstrated comparable half-wave potential to commercial Pt/C, better stability, and excellent immunity to methanol crossover effect in alkaline media. When carbon fiber (CF) was used as substrate, three-dimensional MnO₂@CNT-CF were obtained whose utility as effective adsorbents for arsenic removal from contaminated waters is demonstrated. Full article

(This article belongs to the Special Issue Microwave Technology and Nanomaterials: Synthesis and Application)

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25 pages, 5855 KiB

Open AccessReview

Ferritin Nanocage: A Versatile Nanocarrier Utilized in the Field of Food, Nutrition, and Medicine

by Chenxi Zhang, Xiaorong Zhang and Guanghua Zhao

Nanomaterials 2020, 10(9), 1894; https://doi.org/10.3390/nano10091894 - 22 Sep 2020

Cited by 55 | Viewed by 6980

Abstract

Compared with other nanocarriers such as liposomes, mesoporous silica, and cyclodextrin, ferritin as a typical protein nanocage has received considerable attention in the field of food, nutrition, and medicine owing to its inherent cavity size, excellent water solubility, and biocompatibility. Additionally, ferritin nanocage [...] Read more.

Compared with other nanocarriers such as liposomes, mesoporous silica, and cyclodextrin, ferritin as a typical protein nanocage has received considerable attention in the field of food, nutrition, and medicine owing to its inherent cavity size, excellent water solubility, and biocompatibility. Additionally, ferritin nanocage also serves as a versatile bio-template for the synthesis of a variety of nanoparticles. Recently, scientists have explored the ferritin nanocage structure for encapsulation and delivery of guest molecules such as nutrients, bioactive molecules, anticancer drugs, and mineral metal ions by taking advantage of its unique reversible disassembly and reassembly property and biomineralization. In this review, we mainly focus on the preparation and structure of ferritin-based nanocarriers, and regulation of their self-assembly. Moreover, the recent advances of their applications in food nutrient delivery and medical diagnostics are highlighted. Finally, the main challenges and future development in ferritin-directed nanoparticles’ synthesis and multifunctional applications are discussed. Full article

(This article belongs to the Special Issue Advances in Food Nanotechnology)

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10 pages, 3593 KiB

Open AccessArticle

Electrospinning Synthesis of Carbon-Supported Pt₃Mn Intermetallic Nanocrystals and Electrocatalytic Performance towards Oxygen Reduction Reaction

by Lechao Peng, Lan Zhou, Wenjun Kang, Rui Li, Konggang Qu, Lei Wang and Haibo Li

Nanomaterials 2020, 10(9), 1893; https://doi.org/10.3390/nano10091893 - 22 Sep 2020

Cited by 4 | Viewed by 2748

Abstract

To realize the large-scale application of fuel cells, it is still a great challenge to improve the performance and reduce the cost of cathode catalysts towards oxygen reduction reaction (ORR). In this work, carbon-supported ordered Pt₃Mn intermetallic catalysts were prepared by [...] Read more.

To realize the large-scale application of fuel cells, it is still a great challenge to improve the performance and reduce the cost of cathode catalysts towards oxygen reduction reaction (ORR). In this work, carbon-supported ordered Pt₃Mn intermetallic catalysts were prepared by thermal annealing electrospun polyacrylonitrile nanofibers containing Platinum(II) acetylacetonate/ Manganese(III) acetylacetonate. Compared with its counterparts, the ordered Pt₃Mn intermetallic obtained at 950 °C exhibits a more positive half-potential and higher kinetic current density during the ORR process. Benefiting from their defined stoichiometry and crystal structure, the Mn atoms in Pt₃Mn intermetallic can modulate well the geometric and electronic structure of surface Pt atoms, endowing Pt₃Mn catalyst with an enhanced ORR catalytic activity. Moreover, it also has a better catalytic stability and methanol tolerance than commercial Pt/C catalyst. Our study provides a new strategy to fabricate a highly active and durable Pt₃Mn intermetallic electrocatalyst towards ORR. Full article

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12 pages, 3124 KiB

Open AccessArticle

Polyethylene Glycol as Shape and Size Controller for the Hydrothermal Synthesis of SrTiO₃ Cubes and Polyhedra

by Francesco Pellegrino, Fabrizio Sordello, Lorenzo Mino, Marco Prozzi, Ulrich Mansfeld, Vasile-Dan Hodoroaba and Claudio Minero

Nanomaterials 2020, 10(9), 1892; https://doi.org/10.3390/nano10091892 - 21 Sep 2020

Cited by 9 | Viewed by 2956

Abstract

Understanding the correlation between the morphological and functional properties of particulate materials is crucial across all fields of physical and natural sciences. This manuscript reports on the investigation of the effect of polyethylene glycol (PEG) employed as a capping agent in the synthesis [...] Read more.

Understanding the correlation between the morphological and functional properties of particulate materials is crucial across all fields of physical and natural sciences. This manuscript reports on the investigation of the effect of polyethylene glycol (PEG) employed as a capping agent in the synthesis of SrTiO₃ crystals. The crucial influence of PEG on both the shape and size of the strontium titanate particles is revealed, highlighting the effect on the photocurrents measured under UV–Vis irradiation. Full article

(This article belongs to the Section Synthesis, Interfaces and Nanostructures)

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20 pages, 8558 KiB

Open AccessArticle

Synthesis of the ZnTiO₃/TiO₂ Nanocomposite Supported in Ecuadorian Clays for the Adsorption and Photocatalytic Removal of Methylene Blue Dye

by Ximena Jaramillo-Fierro, Silvia González, Hipatia Alvarado Jaramillo and Francesc Medina

Nanomaterials 2020, 10(9), 1891; https://doi.org/10.3390/nano10091891 - 21 Sep 2020

Cited by 37 | Viewed by 4163

Abstract

Currently, the study of semiconductor materials is very promising for the photocatalytic remediation of hazardous organic substances present in the air and water. Various semiconductors have been investigated in this interesting photo-assisted methodology, among them metal oxides such as ZnO, TiO₂ and [...] Read more.

Currently, the study of semiconductor materials is very promising for the photocatalytic remediation of hazardous organic substances present in the air and water. Various semiconductors have been investigated in this interesting photo-assisted methodology, among them metal oxides such as ZnO, TiO₂ and their derivatives. In this study, ZnTiO₃/TiO₂ was synthesized by the sol-gel method using Ti(OC₃H₇)₄ and Zn(CH₃COO)₂ · 2H₂O as reagents. The role of several conditions such as synthesis temperature and TiO₂:ZnO proportion on the morphology and purity of compounds obtained was studied, and the suitable conditions for the synthesis of photocatalysts were determined. Various techniques were used to conduct a systematic investigation on the structural, morphological, and photocatalytic properties of ZnTiO₃/TiO₂. Scanning Electron Microscopy (SEM) images show that ZnTiO₃/TiO₂ have a typical particle size of approximately 100 nm with a quasi-spherical shape. The adsorption and photocatalytic activity were investigated by the decolorization of Methylene Blue (MB) as an organic contaminant under UV irradiation both in TiO₂ and ZnTiO₃/TiO₂ supported over some Ecuadorian clays. The materials evaluated were prepared in the shape of 0.2 cm (diameter) and 1.0 cm (length) cylindrical extrudates. The degradation percentage of MB obtained was 85% approximately after 150 min of irradiation. The results obtained allow us to conclude that these synthesized materials can be used as adsorbents and photocatalysts. Full article

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9 pages, 2515 KiB

Open AccessArticle

Improving the Cycling Stability of Fe₃O₄/NiO Anode for Lithium Ion Battery by Constructing Novel Bimodal Nanoporous Urchin Network

by Xiaomin Zhang, Xiaoli Liu, Jun Zhou, Chunling Qin and Zhifeng Wang

Nanomaterials 2020, 10(9), 1890; https://doi.org/10.3390/nano10091890 - 21 Sep 2020

Cited by 8 | Viewed by 2424

Abstract

The development of facile preparation methods and novel three-dimensional structured anodes to improve cycling stability of lithium ion batteries (LIBs) is urgently needed. Herein, a dual-network ferroferric oxide/nickel oxide (Fe₃O₄/NiO) anode was synthesized through a facile dealloying technology, which [...] Read more.

The development of facile preparation methods and novel three-dimensional structured anodes to improve cycling stability of lithium ion batteries (LIBs) is urgently needed. Herein, a dual-network ferroferric oxide/nickel oxide (Fe₃O₄/NiO) anode was synthesized through a facile dealloying technology, which is suitable for commercial mass manufacturing. The dual-network with high specific surface area contains a nanoplate array network and a bimodal nanoporous urchin network. It exhibits excellent electrochemical performance as an anode material for LIB, delivering a reversible capacity of 721 mAh g⁻¹ at 100 mA g⁻¹ after 100 cycles. The good lithium storage performance is related to the ample porous structure, which can relieve stress and mitigate the volume change in the charge/discharge process, the interconnected porous network that enhances ionic mobility and permeability, and synergistic effects of two kinds of active materials. The paper provides a new idea for the design and preparation of anode materials with a novel porous structure by a dealloying method and may promote the development of the dealloying field. Full article

(This article belongs to the Section Energy and Catalysis)

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17 pages, 7668 KiB

Open AccessArticle

Characterization of Enamel and Dentine about a White Spot Lesion: Mechanical Properties, Mineral Density, Microstructure and Molecular Composition

by Evgeniy Sadyrin, Michael Swain, Boris Mitrin, Igor Rzhepakovsky, Andrey Nikolaev, Vladimir Irkha, Diana Yogina, Nikolay Lyanguzov, Stanislav Maksyukov and Sergei Aizikovich

Nanomaterials 2020, 10(9), 1889; https://doi.org/10.3390/nano10091889 - 21 Sep 2020

Cited by 34 | Viewed by 4568

Abstract

The study focuses on in vitro tracing of some fundamental changes that emerge in teeth at the initial stage of caries development using multiple approaches. The research was conducted on a mostly sound maxillary molar tooth but with a clearly visible natural proximal [...] Read more.

The study focuses on in vitro tracing of some fundamental changes that emerge in teeth at the initial stage of caries development using multiple approaches. The research was conducted on a mostly sound maxillary molar tooth but with a clearly visible natural proximal white spot lesion (WSL). Values of mineral density, reduced Young’s modulus, indentation hardness and creep as well as the molecular composition and surface microstructure of the WSL and bordering dentine area were studied. The results obtained were compared to those of sound enamel and dentine on the same tooth. A decrease of mechanical properties and mineral density both for the WSL and bordering dentine was detected in comparison to the sound counterparts, as well as increase of creep for the enamel WSL. Differences in molecular composition and surface microstructure (including the indenter impressions) were found and described. WSL induces a serious change in the state of not only the visually affected enamel but also surrounding visually intact enamel and dentine in its vicinity. The results provide the basis for future studies of efficacy of minimal invasive treatments of caries. Full article

(This article belongs to the Special Issue Advances in Micro- and Nanomechanics)

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14 pages, 2601 KiB

Open AccessArticle

Magnetic and Magneto-Optical Oroperties of Iron Oxides Nanoparticles Synthesized under Atmospheric Pressure

by Aleksandr Spivakov, Chun-Rong Lin, Yu-Chuan Chang, Cheng-Chien Wang and Dmitriy Sarychev

Nanomaterials 2020, 10(9), 1888; https://doi.org/10.3390/nano10091888 - 21 Sep 2020

Cited by 5 | Viewed by 2430

Abstract

Magnetite nanoparticles were synthesized by a simple thermal decomposition process, involving only iron (III) nitrate nonahydrate as a precursor, and hexadecylamine as a solvent and stabilizer at reaction temperatures varied from 200 to 380 °C. The results of the structural analysis showed that [...] Read more.

Magnetite nanoparticles were synthesized by a simple thermal decomposition process, involving only iron (III) nitrate nonahydrate as a precursor, and hexadecylamine as a solvent and stabilizer at reaction temperatures varied from 200 to 380 °C. The results of the structural analysis showed that the average crystallite size depends on the reaction temperature and increases from 4.8 to 13.3 nm. The behavior of the coercivity indicates that all synthesized samples are single domain; herewith, it was found that the critical size corresponding to the transition to the superparamagnetic state at room temperature is about 9 nm. The effect of the reaction temperature on changes in the saturation magnetization was studied. It was found that the size effect in the MCD spectra is observed for the IVCT transition and one ISCT transition, and the influence of the reaction temperature on the change in the MCD spectra was discussed. Full article

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13 pages, 6727 KiB

Open AccessArticle

Ta Doping Effect on Structural and Optical Properties of InTe Thin Films

by Chunmin Liu, Yafei Yuan, Xintong Zhang, Jing Su, Xiaoxiao Song, Hang Ling, Yuanjie Liao, Hao Zhang, Yuxiang Zheng and Jing Li

Nanomaterials 2020, 10(9), 1887; https://doi.org/10.3390/nano10091887 - 21 Sep 2020

Cited by 10 | Viewed by 2497

Abstract

The objective of this work was to study the influence of Ta doping on the structural, transmittance properties, linear absorption parameter, and nonlinear absorption properties of InTe thin films. The as-deposited samples with different Ta doping concentrations were prepared by a magnetron co-sputtering [...] Read more.

The objective of this work was to study the influence of Ta doping on the structural, transmittance properties, linear absorption parameter, and nonlinear absorption properties of InTe thin films. The as-deposited samples with different Ta doping concentrations were prepared by a magnetron co-sputtering technique and then annealed in nitrogen atmosphere. Structural investigations by X-ray diffraction revealed the tetragonal structure of InTe samples and that the crystallinity decreases with increasing Ta doping concentration. Further structural analysis by Raman spectra also showed good agreement with X-ray diffraction results. The Ta doping concentration and sample thickness determined by energy-dispersive X-ray spectroscopy and scanning electron microscopy increased as Ta dopant increased. In addition, X-ray photoelectron spectroscopic was carried out to analyze the chemical states of the elements. UV–VIS–NIR transmittance spectra were applied to study the transmittance properties and calculate the linear absorption coefficient. Due to Burstein–Moss effect, the absorption edge moved to shorter wavelengths. Meanwhile, the values of band gap were found to increase from 1.71 ± 0.02 eV to 1.85 ± 0.01 eV with the increase of Ta doping concentration. By performing an open aperture Z-scan technique, we found that all Ta-doped InTe samples exhibited two-photon absorption behaviors. The nonlinear optical absorption parameters, such as modulation depth, two-photon absorption coefficient, and two-photon absorption cross-section, decrease with increasing Ta concentration, whereas the damage threshold increases from 176 ± 0.5 GW/cm² to 242 ± 0.5 GW/cm². These novel properties show the potential for applications in traditional optoelectronic devices and optical limiters. Full article

(This article belongs to the Special Issue Photonic Nanomaterials)

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18 pages, 7075 KiB

Open AccessArticle

Navigation of Silver/Carbon Nanoantennas in Organic Fluids Explored by a Two-Wave Mixing

by Geselle García-Beltrán, Cecilia Mercado-Zúñiga, Christopher René Torres-SanMiguel, Martín Trejo-Valdez, Isaela Villalpando and Carlos Torres-Torres

Nanomaterials 2020, 10(9), 1886; https://doi.org/10.3390/nano10091886 - 21 Sep 2020

Cited by 3 | Viewed by 2256

Abstract

Within this work are analyzed third-order nonlinear optical properties with a potential influence on the dynamic mechanics exhibited by metal/carbon nanofluids. The nanofluids were integrated by multiwall carbon nanotubes decorated with Ag nanoparticles suspended in ethanol or in acetone. Optical third-order nonlinearities were [...] Read more.

Within this work are analyzed third-order nonlinear optical properties with a potential influence on the dynamic mechanics exhibited by metal/carbon nanofluids. The nanofluids were integrated by multiwall carbon nanotubes decorated with Ag nanoparticles suspended in ethanol or in acetone. Optical third-order nonlinearities were experimentally explored by vectorial two-wave mixing experiments with a Nd-YAG laser system emitting nanosecond pulses at a 532 nm wavelength. An optically induced birefringence in the metal/organic samples seems to be responsible for a significant modification in density and compressibility modulus in the nanosystems. The measured nonlinear refractive index was associated with a thermal process together with changes in density, compressibility modulus and speed of sound in the samples. Nanofluid diffusivity was studied to characterize the dynamic concentration gradients related to the precipitation of nanostructures in the liquid solutions. The evolution of the nanoparticle density suspended in the nanofluids was considered as a temporal-resolved probabilistic system. It is stated that the incorporation of Ag nanoparticles in carbon nanotubes produces strong mechanical changes in carbon-based nanofluids. According to numerical simulations and optical evaluations, immediate applications for developing dynamic nanoantennas optical logic gates and quantum-controlled metal/carbon systems can be contemplated. Full article

(This article belongs to the Special Issue Applications of Nanofluids)

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14 pages, 7137 KiB

Open AccessArticle

Synthesis of Au, Ag, and Au–Ag Bimetallic Nanoparticles Using Pulicaria undulata Extract and Their Catalytic Activity for the Reduction of 4-Nitrophenol

by Merajuddin Khan, Khaleel Al-hamoud, Zainab Liaqat, Mohammed Rafi Shaik, Syed Farooq Adil, Mufsir Kuniyil, Hamad Z. Alkhathlan, Abdulrahman Al-Warthan, Mohammed Rafiq H. Siddiqui, Mihail Mondeshki, Wolfgang Tremel, Mujeeb Khan and Muhammad Nawaz Tahir

Nanomaterials 2020, 10(9), 1885; https://doi.org/10.3390/nano10091885 - 20 Sep 2020

Cited by 51 | Viewed by 5427

Abstract

Plant extract of Pulicaria undulata (L.) was used as both reducing agent and stabilizing ligand for the rapid and green synthesis of gold (Au), silver (Ag), and gold–silver (Au–Ag) bimetallic (phase segregated/alloy) nanoparticles (NPs). These nanoparticles with different morphologies were prepared in two [...] Read more.

Plant extract of Pulicaria undulata (L.) was used as both reducing agent and stabilizing ligand for the rapid and green synthesis of gold (Au), silver (Ag), and gold–silver (Au–Ag) bimetallic (phase segregated/alloy) nanoparticles (NPs). These nanoparticles with different morphologies were prepared in two hours by stirring corresponding metal precursors in the aqueous solution of the plant extracts at ambient temperature. To infer the role of concentration of plant extract on the composition and morphology of NPs, we designed two different sets of experiments, namely (i) low concentration (LC) and (ii) high concentration (HC) of plant extract. In the case of using low concentration of the plant extract, irregular shaped Au, Ag, or phase segregated Au–Ag bimetallic NPs were obtained, whereas the use of higher concentrations of the plant extract resulted in the formation of spherical Au, Ag, and Au–Ag alloy NPs. The as-prepared Au, Ag, and Au–Ag bimetallic NPs showed morphology and composition dependent catalytic activity for the reduction of 4-nitrophenol (4-NPh) to 4-aminophenol (4-APh) in the presence of NaBH₄. The bimetallic Au–Ag alloy NPs showed the highest catalytic activity compared to all other NPs. Full article

(This article belongs to the Section Environmental Nanoscience and Nanotechnology)

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54 pages, 6852 KiB

Open AccessReview

Three-Dimensional Cathodes for Electrochemical Reduction of CO₂: From Macro- to Nano-Engineering

by Shiqiang (Rob) Hui, Nima Shaigan, Vladimir Neburchilov, Lei Zhang, Kourosh Malek, Michael Eikerling and Phil De Luna

Nanomaterials 2020, 10(9), 1884; https://doi.org/10.3390/nano10091884 - 20 Sep 2020

Cited by 22 | Viewed by 6901

Abstract

Rising anthropogenic CO₂ emissions and their climate warming effects have triggered a global response in research and development to reduce the emissions of this harmful greenhouse gas. The use of CO₂ as a feedstock for the production of value-added fuels and [...] Read more.

Rising anthropogenic CO₂ emissions and their climate warming effects have triggered a global response in research and development to reduce the emissions of this harmful greenhouse gas. The use of CO₂ as a feedstock for the production of value-added fuels and chemicals is a promising pathway for development of renewable energy storage and reduction of carbon emissions. Electrochemical CO₂ conversion offers a promising route for value-added products. Considerable challenges still remain, limiting this technology for industrial deployment. This work reviews the latest developments in experimental and modeling studies of three-dimensional cathodes towards high-performance electrochemical reduction of CO₂. The fabrication–microstructure–performance relationships of electrodes are examined from the macro- to nanoscale. Furthermore, future challenges, perspectives and recommendations for high-performance cathodes are also presented. Full article

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17 pages, 4220 KiB

Open AccessArticle

Ultrasensitive Detection of Tetracycline Using Boron and Nitrogen Co-Doped Graphene Quantum Dots from Natural Carbon Source as the Paper-Based Nanosensing Probe in Difference Matrices

by Hai Linh Tran, Win Darmanto and Ruey-An Doong

Nanomaterials 2020, 10(9), 1883; https://doi.org/10.3390/nano10091883 - 20 Sep 2020

Cited by 24 | Viewed by 3540

Abstract

Herein, the boron and nitrogen co-doped 0-dimensional graphene quantum dots (B,N-GQDs) with high quantum yield (QY) were synthesized via microwave-assisted hydrothermal method at 170 °C for 20 min using fresh passion fruit juice and boric acid as the starting materials. The 3–6 layers [...] Read more.

Herein, the boron and nitrogen co-doped 0-dimensional graphene quantum dots (B,N-GQDs) with high quantum yield (QY) were synthesized via microwave-assisted hydrothermal method at 170 °C for 20 min using fresh passion fruit juice and boric acid as the starting materials. The 3–6 layers of B,N-GQDs with mean particle size of 9 ± 1 nm were then used for ultra-sensitive and selective detection of tetracycline in aqueous and biological media. The hybridization of boron and nitrogen atoms into the GQD structures increases the intensity of electronegative, resulting in the enhancement of QY to 50 ± 1%. The B,N-GQDs show their excellent analytical performance on tetracycline determination after 2 min of reaction under an optimal condition at pH 5. The linear range of 0.04–70 µM and with limits of detection (LOD) of 1 nM in phosphate buffer saline (PBS), 1.9 nM in urine and 2.2 nM in human serum are obtained. Moreover, the high selectivity of tetracycline by B,N-GQDs over the other 23 interferences is observed. The π-π interaction and electron donor-acceptor principle play pivotal roles in enhancing the ultra-sensitivity and selectivity of B,N-GQDs toward TC detection. Moreover, the B, N-GQD based paper nanosensor exhibits an excellent analytical performance on visual detection of 0.1–30 µM TC in human serum. Results of this study clearly indicate the feasibility of synthesis of B,N-GQDs derived from passion fruit juice for ultrasensitive tetracycline detection, which can open an avenue to use natural products for the preparation of environmentally benign and biocompatible carbon nanomaterials for highly sensitive detection of drugs, antibiotics, organic compounds and biomarkers. Full article

(This article belongs to the Section Nanoelectronics, Nanosensors and Devices)

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14 pages, 2574 KiB

Open AccessArticle

Fabrication of Carbon-Like, π-Conjugated Organic Layer on a Nano-Porous Silica Surface

by Hiroki Noguchi, Marzia Sultana, Nanami Hano, Yutaka Kuwahara, Makoto Takafuji, Shoji Nagaoka, Hongdeng Qiu and Hirotaka Ihara

Nanomaterials 2020, 10(9), 1882; https://doi.org/10.3390/nano10091882 - 20 Sep 2020

Cited by 9 | Viewed by 2970

Abstract

This paper presents a new type of black organic material-porous silica composite providing an extremely highly selective adsorption surface. This black composite was prepared by lamination on nano-sized pores with a carbon-like, π-extended structure, which can be converted via the on-site polymerization of [...] Read more.

This paper presents a new type of black organic material-porous silica composite providing an extremely highly selective adsorption surface. This black composite was prepared by lamination on nano-sized pores with a carbon-like, π-extended structure, which can be converted via the on-site polymerization of 1,5-dihydroxynaphthalene with a triazinane derivative and a thermally induced condensation reaction with denitrification. This bottom-up fabrication method on porous materials had the great advantage of maintaining the pore characteristics of a raw porous material, but also the resultant black surface exhibited an extremely high molecular-shape selectivity; for example, that for trans- and cis-stilbenes reached 14.0 with the black layer-laminated porous silica, whereas it was below 1.2 with simple hydrophobized silica. Full article

(This article belongs to the Section Synthesis, Interfaces and Nanostructures)

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9 pages, 2243 KiB

Open AccessArticle

Plasmon-Enhanced Photothermal and Optomechanical Deformations of a Gold Nanoparticle

by Jiunn-Woei Liaw, Guanting Liu, Yun-Cheng Ku and Mao-Kuen Kuo

Nanomaterials 2020, 10(9), 1881; https://doi.org/10.3390/nano10091881 - 20 Sep 2020

Cited by 3 | Viewed by 2138

Abstract

Plasmon-enhanced photothermal and optomechanical effects on deforming and reshaping a gold nanoparticle (NP) are studied theoretically. A previous paper (Wang and Ding, ACS Nano 13, 32–37, 2019) has shown that a spherical gold nanoparticle (NP) irradiated by a tightly focused laser beam can [...] Read more.

Plasmon-enhanced photothermal and optomechanical effects on deforming and reshaping a gold nanoparticle (NP) are studied theoretically. A previous paper (Wang and Ding, ACS Nano 13, 32–37, 2019) has shown that a spherical gold nanoparticle (NP) irradiated by a tightly focused laser beam can be deformed into an elongated nanorod (NR) and even chopped in half (a dimer). The mechanism is supposed to be caused by photothermal heating for softening NP associated with optical traction for follow-up deformation. In this paper, our study focuses on deformation induced by Maxwell’s stress provided by a linearly polarized Gaussian beam upon the surface of a thermal-softened NP/NR. We use an elastic model to numerically calculate deformation according to optical traction and a viscoelastic model to theoretically estimate the following creep (elongation) as temperature nears the melting point. Our results indicate that a stretching traction at the two ends of the NP/NR causes elongation and a pinching traction at the middle causes a dent. Hence, a bigger NP can be elongated and then cut into two pieces (a dimer) at the dent due to the optomechanical effect. As the continuous heating process induces premelting of NPs, a quasi-liquid layer is formed first and then an outer liquid layer is induced due to reduction of surface energy, which was predicted by previous works of molecular dynamics simulation. Subsequently, we use the Young–Laplace model to investigate the surface tension effect on the following deformation. This study may provide an insight into utilizing the photothermal effect associated with optomechanical manipulation to tailor gold nanostructures. Full article

(This article belongs to the Section Nanofabrication and Nanomanufacturing)

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10 pages, 4406 KiB

Open AccessArticle

Single Crystalline Higher Manganese Silicide Nanowire Arrays with Outstanding Physical Properties through Double Tube Chemical Vapor Deposition

by Chin-Li Shen, Shu-Meng Yang and Kuo-Chang Lu

Nanomaterials 2020, 10(9), 1880; https://doi.org/10.3390/nano10091880 - 19 Sep 2020

Cited by 4 | Viewed by 2755

Abstract

In this work, we report a novel and efficient silicidation method to synthesize higher manganese silicide (HMS) nanowires with interesting characterization and physical properties. High density silicon nanowire arrays fabricated by chemical etching reacted with MnCl₂ precursor through a unique double tube [...] Read more.

In this work, we report a novel and efficient silicidation method to synthesize higher manganese silicide (HMS) nanowires with interesting characterization and physical properties. High density silicon nanowire arrays fabricated by chemical etching reacted with MnCl₂ precursor through a unique double tube chemical vapor deposition (CVD) system, where we could enhance the vapor pressure of the precursor and provide stable Mn vapor with a sealing effect. It is crucial that the method enables the efficient formation of high quality higher manganese silicide nanowires without a change in morphology and aspect ratio during the process. X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were utilized to characterize the HMS nanowires. High-resolution TEM studies confirm that the HMS nanowires were single crystalline Mn₂₇Si₄₇ nanowires of Nowotny Chimney Ladder crystal structures. Magnetic property measurements show that the Mn₂₇Si₄₇ nanowire arrays were ferromagnetic at room temperature with a Curie temperature of over 300 K, highly depending on the relationship between the direction of the applied electric field and the axial direction of the standing nanowire arrays. Field emission measurements indicate that the 20 μm long nanowires possessed a field enhancement factor of 3307. The excellent physical properties of the HMS nanowires (NWs) make them attractive choices for applications in spintronic devices and field emitters. Full article

(This article belongs to the Section Nanofabrication and Nanomanufacturing)

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11 pages, 3067 KiB

Open AccessFeature PaperArticle

Printed and Flexible Microheaters Based on Carbon Nanotubes

by Aniello Falco, Francisco J. Romero, Florin C. Loghin, Alina Lyuleeva, Markus Becherer, Paolo Lugli, Diego P. Morales, Noel Rodriguez, Jose F. Salmerón and Almudena Rivadeneyra

Nanomaterials 2020, 10(9), 1879; https://doi.org/10.3390/nano10091879 - 19 Sep 2020

Cited by 7 | Viewed by 3367

Abstract

This work demonstrates a cost-effective manufacturing method of flexible and fully printed microheaters, using carbon nanotubes (CNTs) as the heating element. Two different structures with different number of CNT layers have been characterized in detail. The benchmarking has been carried out in terms [...] Read more.

This work demonstrates a cost-effective manufacturing method of flexible and fully printed microheaters, using carbon nanotubes (CNTs) as the heating element. Two different structures with different number of CNT layers have been characterized in detail. The benchmarking has been carried out in terms of maximum operating temperature, as well as nominal resistance and input power for different applied voltages. Their performances have been compared with previous reports for similar devices, fabricated with other technologies. The results have shown that the heaters presented can achieve high temperatures in a small area at lower voltages and lower input power. In particular, the fully printed heaters fabricated on a flexible substrate covering an area of 3.2 mm² and operating at 9.5 V exhibit a maximum temperature point above 70 °C with a power consumption below 200 mW. Therefore, we have demonstrated that this technology paves the way for a cost-effective large-scale fabrication of flexible microheaters aimed to be integrated in flexible sensors. Full article

(This article belongs to the Special Issue Functional Nanomaterials for Sensor Applications)

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22 pages, 4238 KiB

Open AccessPerspective

Perspectives on Nickel Hydroxide Electrodes Suitable for Rechargeable Batteries: Electrolytic vs. Chemical Synthesis Routes

by Baladev Ash, Venkata Swamy Nalajala, Ashok Kumar Popuri, Tondepu Subbaiah and Manickam Minakshi

Nanomaterials 2020, 10(9), 1878; https://doi.org/10.3390/nano10091878 - 19 Sep 2020

Cited by 33 | Viewed by 5315

Abstract

A significant amount of work on electrochemical energy storage focuses mainly on current lithium-ion systems with the key markets being portable and transportation applications. There is a great demand for storing higher capacity (mAh/g) and energy density (Wh/kg) of the electrode material for [...] Read more.

A significant amount of work on electrochemical energy storage focuses mainly on current lithium-ion systems with the key markets being portable and transportation applications. There is a great demand for storing higher capacity (mAh/g) and energy density (Wh/kg) of the electrode material for electronic and vehicle applications. However, for stationary applications, where weight is not as critical, nickel-metal hydride (Mi-MH) technologies can be considered with tolerance to deep discharge conditions. Nickel hydroxide has gained importance as it is used as the positive electrode in nickel-metal hydride and other rechargeable batteries such as Ni-Fe and Ni-Cd systems. Nickel hydroxide is manufactured industrially by chemical methods under controlled conditions. However, the electrochemical route is relatively better than the chemical counterpart. In the electrochemical route, a well-regulated OH⁻ is generated at the cathode forming nickel hydroxide (Ni(OH)₂) through controlling and optimizing the current density. It produces nickel hydroxide of better purity with an appropriate particle size, well-oriented morphology, structure, et cetera, and this approach is found to be environmentally friendly. The structures of the nickel hydroxide and its production technologies are presented. The mechanisms of product formation in both chemical and electrochemical preparation of nickel hydroxide have been presented along with the feasibility of producing pure nickel hydroxide in this review. An advanced Ni(OH)₂-polymer embedded electrode has been reported in the literature but may not be suitable for scalable electrochemical methods. To the best of our knowledge, no such insights on the Ni(OH)₂ synthesis route for battery applications has been presented in the literature. Full article

(This article belongs to the Special Issue Applications of Nanomaterials and Nanotechnology in Energy Storage Device)

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17 pages, 2831 KiB

Open AccessArticle

Effects of Few-Layer Graphene on the Sexual Reproduction of Seed Plants: An In Vivo Study with Cucurbita pepo L.

by Davide Zanelli, Fabio Candotto Carniel, Marina Garrido, Lorenzo Fortuna, Massimo Nepi, Giampiero Cai, Cecilia Del Casino, Ester Vázquez, Maurizio Prato and Mauro Tretiach

Nanomaterials 2020, 10(9), 1877; https://doi.org/10.3390/nano10091877 - 19 Sep 2020

Cited by 5 | Viewed by 3632

Abstract

Products containing graphene-related materials (GRMs) are becoming quite common, raising concerns for environmental safety. GRMs have varying effects on plants, but their impact on the sexual reproduction process is largely unknown. In this study, the effects of few-layer graphene (FLG) and a similarly [...] Read more.

Products containing graphene-related materials (GRMs) are becoming quite common, raising concerns for environmental safety. GRMs have varying effects on plants, but their impact on the sexual reproduction process is largely unknown. In this study, the effects of few-layer graphene (FLG) and a similarly layered phyllosilicate, muscovite mica (MICA), were tested in vivo on the reproductive structures, i.e., pollen and stigma, of Cucurbita pepo L. ssp. pepo ‘greyzini’ (summer squash, zucchini). Pollen was exposed to FLG or MICA, after careful physical-chemical characterization, at concentrations of 0.5 and 2 mg of nanomaterial (NM) per g of pollen for up to six hours. Following this, pollen viability was tested. Stigmas were exposed to FLG or MICA for three hours and then analyzed by environmental scanning electron microscopy to verify possible alterations to their surface. Stigmas were then hand-pollinated to verify the effects of the two NMs on pollen adhesion and in vivo pollen germination. FLG and MICA altered neither pollen viability nor the stigmatic surface. However, both NMs equivalently decreased pollen adhesion and in vivo germination compared with untreated stigmas. These effects deserve further attention as they could impact on production of fruits and seeds. Importantly, it was shown that FLG is as safe as a naturally occurring nanomaterial. Full article

(This article belongs to the Special Issue Nanotechnology in Agriculture and Food Industry)

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18 pages, 1844 KiB

Open AccessArticle

Evaluation of the NLRP3 Inflammasome Activating Effects of a Large Panel of TiO₂ Nanomaterials in Macrophages

by Julia Kolling, Jonas Tigges, Bryan Hellack, Catrin Albrecht and Roel P. F. Schins

Nanomaterials 2020, 10(9), 1876; https://doi.org/10.3390/nano10091876 - 19 Sep 2020

Cited by 14 | Viewed by 2949

Abstract

TiO₂ nanomaterials are among the most commonly produced and used engineered nanomaterials (NMs) in the world. There is controversy regarding their ability to induce inflammation-mediated lung injuries following inhalation exposure. Activation of the NACHT, LRR and PYD domains-containing protein 3 (NALP3) inflammasome [...] Read more.

TiO₂ nanomaterials are among the most commonly produced and used engineered nanomaterials (NMs) in the world. There is controversy regarding their ability to induce inflammation-mediated lung injuries following inhalation exposure. Activation of the NACHT, LRR and PYD domains-containing protein 3 (NALP3) inflammasome and subsequent release of the cytokine interleukin (IL)-1β in pulmonary macrophages has been postulated as an essential pathway for the inflammatory and associated tissue-remodeling effects of toxic particles. Our study aim was to determine and rank the IL-1β activating properties of TiO₂ NMs by comparing a large panel of different samples against each other as well as against fine TiO₂, synthetic amorphous silica and crystalline silica (DQ12 quartz). Effects were evaluated in primary bone marrow derived macrophages (BMDMs) from NALP3-deficient and proficient mice as well as in the rat alveolar macrophage cell line NR8383. Our results show that specific TiO₂ NMs can activate the inflammasome in macrophages albeit with a markedly lower potency than amorphous SiO₂ and quartz. The heterogeneity in IL-1β release observed in our study among 19 different TiO₂ NMs underscores the relevance of case-by-case evaluation of nanomaterials of similar chemical composition. Our findings also further promote the NR8383 cell line as a promising in vitro tool for the assessment of the inflammatory and inflammasome activating properties of NMs. Full article

(This article belongs to the Special Issue Toxicology and Biocompatibility of Nanomaterials)

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18 pages, 4129 KiB

Open AccessArticle

A New Zinc Phosphate-Tellurite Glass for Magneto-Optical Applications

by Mihail Elisa, Raluca Constantina Stefan, Ileana Cristina Vasiliu, Stefan Marian Iordache, Ana-Maria Iordache, Bogdan Alexandru Sava, Lucica Boroica, Marius Catalin Dinca, Ana Violeta Filip, Aurelian Catalin Galca, Cristina Bartha, Nicusor Iacob, Madalin Ion Rusu, Mihai Eftimie and Victor Kuncser

Nanomaterials 2020, 10(9), 1875; https://doi.org/10.3390/nano10091875 - 18 Sep 2020

Cited by 17 | Viewed by 2551

Abstract

This work investigates the structural, magnetic and magneto-optical properties of a new zinc phosphate-tellurite glass belonging to the 45ZnO-10Al₂O₃-40P₂O₅-5TeO₂ system. The glass was prepared by a wet method of processing the starting reagents followed [...] Read more.

This work investigates the structural, magnetic and magneto-optical properties of a new zinc phosphate-tellurite glass belonging to the 45ZnO-10Al₂O₃-40P₂O₅-5TeO₂ system. The glass was prepared by a wet method of processing the starting reagents followed by suitable melting–stirring–quenching–annealing steps. Specific parameters such as density, average molecular mass, molar volume, oxygen packaging density, refractive index, molar refractivity, electronic polarizability, reflection loss, optical transmission, band gap and optical basicity have been reported together with thermal, magnetic and magneto-optical characteristics. Absorption bands appear in the blue and red visible region, while over 600 nm the glass becomes more transparent. FTIR and Raman spectra evidenced phosphate-tellurite vibration modes proving the P₂O₅ and TeO₂ network forming role. Magnetic measurements reveal the diamagnetic character of the Te-doped glass with an additional weak ferromagnetic signal, specific to diluted ferromagnetic oxides. Positive Faraday rotation angle with monotonous decreasing value at increasing wavelength was evidenced from magneto-optical measurements. The final product is a composite material comprising of a non-crystalline vitreous phase and Te-based nanoclusters accompanied by oxygen vacancies. The metallic-like Te colloids are responsible for the dark reddish color of the glass whereas the accompanying oxygen vacancies might be responsible for the weak ferromagnetic signal persisting up to room temperature. Full article

(This article belongs to the Special Issue Multifunctional Magnetic Nanocomposites: Innovative Processing and Applications)

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9 pages, 1752 KiB

Open AccessArticle

Effect of Al₂O₃ Dot Patterning on CZTSSe Solar Cell Characteristics

by Se-Yun Kim, Sanghun Hong, Seung-Hyun Kim, Dae-Ho Son, Young-Ill Kim, Sammi Kim, Young-Woo Heo, Jin-Kyu Kang and Dae-Hwan Kim

Nanomaterials 2020, 10(9), 1874; https://doi.org/10.3390/nano10091874 - 18 Sep 2020

Cited by 4 | Viewed by 2462

Abstract

In this study, a 5-nm thick Al₂O₃ layer was patterned onto the Mo electrode in the form of a dot to produce a local rear contact, which looked at the effects of this contact structure on Cu₂ZnSn(S_1-x [...] Read more.

In this study, a 5-nm thick Al₂O₃ layer was patterned onto the Mo electrode in the form of a dot to produce a local rear contact, which looked at the effects of this contact structure on Cu₂ZnSn(S_1-xSe_x)₄ (CZTSSe) growth and solar cell devices. Mo was partially exposed through open holes having a square dot shape, and the closed-ratios of Al₂O₃ passivated areas were 56%, 75%, and 84%. The process of synthesizing CZTSSe is the same as that of the previous process showing 12.62% efficiency. When the 5-nm-Al₂O₃ dot patterning was applied to the Mo surface, we observed that the MoSSe formation was well suppressed under the area coated of 5-nm-Al₂O₃ film. The self-alignment phenomenon was observed in the back-contact area. CZTSSe was easily formed in the Mo-exposed area, while voids were formed near the Al₂O₃-coated area. The efficiency of the CZTSSe solar cell decreased when the Al₂O₃ passivated area increased. The exposure area and pitch of Mo, the collecting path of the hole, and the supplying path of Na seemed to be related to efficiency. Thus, it was suggested that the optimization of the Mo-exposed pattern and the additional Na supply are necessary to develop the optimum self-aligned CZTSSe light absorber. Full article

(This article belongs to the Section Energy and Catalysis)

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17 pages, 9297 KiB

Open AccessArticle

Innovative Low-Cost Carbon/ZnO Hybrid Materials with Enhanced Photocatalytic Activity towards Organic Pollutant Dyes’ Removal

by Petronela Pascariu, Niculae Olaru, Aurelian Rotaru and Anton Airinei

Nanomaterials 2020, 10(9), 1873; https://doi.org/10.3390/nano10091873 - 18 Sep 2020

Cited by 10 | Viewed by 2705

Abstract

A new type of material based on carbon/ZnO nanostructures that possesses both adsorption and photocatalytic properties was obtained in three stages: cellulose acetate butyrate (CAB) microfiber mats prepared by the electrospinning method, ZnO nanostructures growth by dipping and hydrothermal methods, and finally thermal [...] Read more.

A new type of material based on carbon/ZnO nanostructures that possesses both adsorption and photocatalytic properties was obtained in three stages: cellulose acetate butyrate (CAB) microfiber mats prepared by the electrospinning method, ZnO nanostructures growth by dipping and hydrothermal methods, and finally thermal calcination at 600 °C in N₂ for 30 min. X-ray diffraction (XRD) confirmed the structural characteristics. It was found that ZnO possesses a hexagonal wurtzite crystalline structure. The ZnO nanocrystals with star-like and nanorod shapes were evidenced by scanning electron microscopy (SEM) measurements. A significant decrease in E_g value was found for carbon/ZnO hybrid materials (2.51 eV) as compared to ZnO nanostructures (3.21 eV). The photocatalytic activity was evaluated by studying the degradation of three dyes, Methylene Blue (MB), Rhodamine B (RhB) and Congo Red (CR) under visible-light irradiation. Therefore, the maximum color removal efficiency (both adsorption and photocatalytic processes) was: 97.97% of MB (C₀ = 10 mg/L), 98.34% of RhB (C₀ = 5 mg/L), and 91.93% of CR (C₀ = 10 mg/L). Moreover, the value of the rate constant (k) was found to be 0.29 × 10⁻² min⁻¹. The novelty of this study relies on obtaining new photocatalysts based on carbon/ZnO using cheap and accessible raw materials, and low-cost preparation techniques. Full article

(This article belongs to the Special Issue Novel Nanocomposites: Optical, Electrical, Mechanical and Surface Related Properties)

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19 pages, 5407 KiB

Open AccessArticle

Biocompatible PEO-b-PCL Nanosized Micelles as Drug Carriers: Structure and Drug–Polymer Interactions

by Angeliki Chroni, Thomas Mavromoustakos and Stergios Pispas

Nanomaterials 2020, 10(9), 1872; https://doi.org/10.3390/nano10091872 - 18 Sep 2020

Cited by 18 | Viewed by 3687

Abstract

We report on the preparation of drug nanocarriers by encapsulating losartan potassium (LSR) into amphiphilic block copolymer micelles, utilizing the biocompatible/biodegradable poly(ethylene oxide)-b-poly(ε-caprolactone) (PEO-b-PCL) diblock copolymer. The PEO-b-PCL micelles and LSR-loaded PEO-b-PCL nanocarriers were prepared by organic solvent evaporation method (OSEM). Light scattering [...] Read more.

We report on the preparation of drug nanocarriers by encapsulating losartan potassium (LSR) into amphiphilic block copolymer micelles, utilizing the biocompatible/biodegradable poly(ethylene oxide)-b-poly(ε-caprolactone) (PEO-b-PCL) diblock copolymer. The PEO-b-PCL micelles and LSR-loaded PEO-b-PCL nanocarriers were prepared by organic solvent evaporation method (OSEM). Light scattering and nuclear magnetic resonance (NMR) provide information on micelle structure and polymer–drug interactions. According to dynamic light scattering (DLS) analysis, the PEO-b-PCL micelles and LSR-loaded PEO-b-PCL nanocarriers formed nanostructures in the range of 17–26 nm in aqueous milieu. Attenuated total reflection Fourier transform infrared (ATR-FTIR) and ultraviolet-visible (UV-Vis) measurements confirmed the presence of LSR in the polymeric drug solutions. NMR results proved the successful encapsulation of LSR into the PEO-b-PCL micelles by analyzing the drug–micelles intermolecular interactions. Specifically, 2D-NOESY experiments clearly evidenced the intermolecular interactions between the biphenyl ring and butyl chain of LSR structure with the methylene signals of PCL. Additionally, NMR studies as a function of temperature demonstrated an unexpected, enhanced proton mobility of the PEO-b-PCL micellar core in D₂O solutions, probably caused by the melting of the PCL hydrophobic core. Full article

(This article belongs to the Special Issue Nanodispersions Based on Biocompatibility)

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37 pages, 4566 KiB

Open AccessReview

Photoactive Tungsten-Oxide Nanomaterials for Water-Splitting

by Yerkin Shabdan, Aiymkul Markhabayeva, Nurlan Bakranov and Nurxat Nuraje

Nanomaterials 2020, 10(9), 1871; https://doi.org/10.3390/nano10091871 - 18 Sep 2020

Cited by 44 | Viewed by 6142

Abstract

This review focuses on tungsten oxide (WO₃) and its nanocomposites as photoactive nanomaterials for photoelectrochemical cell (PEC) applications since it possesses exceptional properties such as photostability, high electron mobility (~12 cm² V⁻¹ s⁻¹) and a long hole-diffusion [...] Read more.

This review focuses on tungsten oxide (WO₃) and its nanocomposites as photoactive nanomaterials for photoelectrochemical cell (PEC) applications since it possesses exceptional properties such as photostability, high electron mobility (~12 cm² V⁻¹ s⁻¹) and a long hole-diffusion length (~150 nm). Although WO₃ has demonstrated oxygen-evolution capability in PEC, further increase of its PEC efficiency is limited by high recombination rate of photogenerated electron/hole carriers and slow charge transfer at the liquid–solid interface. To further increase the PEC efficiency of the WO₃ photocatalyst, designing WO₃ nanocomposites via surface–interface engineering and doping would be a great strategy to enhance the PEC performance via improving charge separation. This review starts with the basic principle of water-splitting and physical chemistry properties of WO₃, that extends to various strategies to produce binary/ternary nanocomposites for PEC, particulate photocatalysts, Z-schemes and tandem-cell applications. The effect of PEC crystalline structure and nanomorphologies on efficiency are included. For both binary and ternary WO₃ nanocomposite systems, the PEC performance under different conditions—including synthesis approaches, various electrolytes, morphologies and applied bias—are summarized. At the end of the review, a conclusion and outlook section concluded the WO₃ photocatalyst-based system with an overview of WO₃ and their nanocomposites for photocatalytic applications and provided the readers with potential research directions. Full article

(This article belongs to the Special Issue Photoactive Nanomaterials)

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16 pages, 4511 KiB

Open AccessArticle

Protective Spinel Coating for Li_1.17Ni_0.17Mn_0.50Co_0.17O₂ Cathode for Li-Ion Batteries through Single-Source Precursor Approach

by Andrey Shevtsov, Haixiang Han, Anatolii Morozov, Jesse C. Carozza, Aleksandra A. Savina, Iaroslava Shakhova, Nellie R. Khasanova, Evgeny V. Antipov, Evgeny V. Dikarev and Artem M. Abakumov

Nanomaterials 2020, 10(9), 1870; https://doi.org/10.3390/nano10091870 - 18 Sep 2020

Cited by 10 | Viewed by 2916

Abstract

The Li_1.17Ni_0.17Mn_0.50Co_0.17O₂ Li-rich NMC positive electrode (cathode) for lithium-ion batteries has been coated with nanocrystals of the LiMn_1.5Co_0.5O₄ high-voltage spinel cathode material. The coating was applied through a single-source [...] Read more.

The Li_1.17Ni_0.17Mn_0.50Co_0.17O₂ Li-rich NMC positive electrode (cathode) for lithium-ion batteries has been coated with nanocrystals of the LiMn_1.5Co_0.5O₄ high-voltage spinel cathode material. The coating was applied through a single-source precursor approach by a deposition of the molecular precursor LiMn_1.5Co_0.5(thd)₅ (thd = 2,2,6,6-tetramethyl-3,5-heptanedionate) dissolved in diethyl ether, followed by thermal decomposition at 400 °C inair resulting in a chemically homogeneous cubic spinel. The structure and chemical composition of the coatings, deposited on the model SiO₂ spheres and Li-rich NMC crystallites, were analyzed using powder X-ray diffraction, electron diffraction, high angle annular dark-field scanning transmission electron microscopy (HAADF-STEM), and energy-dispersive X-ray (EDX) mapping. The coated material containing 12 wt.% of spinel demonstrates a significantly improved first cycle Coulombic efficiency of 92% with a high first cycle discharge capacity of 290 mAhg⁻¹. The coating also improves the capacity and voltage retention monitored over 25 galvanostatic charge–discharge cycles, although a complete suppression of the capacity and voltage fade is not achieved. Full article

(This article belongs to the Section Energy and Catalysis)

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12 pages, 3565 KiB

Open AccessArticle

Green Synthesis and Characterization of Gold Nanoparticles Using Lignin Nanoparticles

by Baobin Wang, Guihua Yang, Jiachuan Chen and Guigan Fang

Nanomaterials 2020, 10(9), 1869; https://doi.org/10.3390/nano10091869 - 18 Sep 2020

Cited by 22 | Viewed by 3354

Abstract

With the development of nanotechnology, gold nanoparticles (Au NPs) have attracted enormous attention due to their special properties. The green synthesis of Au NPs from lignin would inspire the utilization of lignin and its related functional materials. In this study, a rapid preparation [...] Read more.

With the development of nanotechnology, gold nanoparticles (Au NPs) have attracted enormous attention due to their special properties. The green synthesis of Au NPs from lignin would inspire the utilization of lignin and its related functional materials. In this study, a rapid preparation process of Au NPs was investigated by utilizing lignin nanoparticles (LNPs) under room temperature without chemical addition. The LNPs acted as a reducing agent, stabilizing agent, and template for the preparation of LNPs@AuNPs. The obtained LNPs@AuNPs were characterized by UV-Vis spectrum, Transmission Electron Microscope (TEM), and X-ray photoelectron spectroscopy (XPS). The possible mechanism was illustrated by Fourier Transform Infrared Spectroscopy (FT-IR), ³¹P, XPS, and UV analyses. The abundant hydroxyl groups (24.96 mmol/g) favored the preparation of Au NPs. Au NPs diameters of 10–30 nm were well dispersed in the LNPs. The optimal reaction conditions were a ratio of 10 mg of LNPs to 0.05 mmol HAuCl₄, room temperature, and a reaction time of 30 min. The LNPs@AuNPs exhibited excellent stability in the suspension for more than seven days. The reduction process could be related to the disruption of side chains of lignin, hydroxyl group oxidation, and hydroquinones and quinones from the comproportionation reaction. The LNPs@AuNPs would open a door for the design of Au NP/lignin-derived novel functional materials. Full article

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12 pages, 11660 KiB

Open AccessArticle

Silver Nanoparticles Alter Cell Viability Ex Vivo and in Vitro and Induce Proinflammatory Effects in Human Lung Fibroblasts

by Anna Löfdahl, Andreas Jern, Samuel Flyman, Monica Kåredal, Hanna L Karlsson and Anna-Karin Larsson-Callerfelt

Nanomaterials 2020, 10(9), 1868; https://doi.org/10.3390/nano10091868 - 18 Sep 2020

Cited by 14 | Viewed by 2790

Abstract

Silver nanoparticles (AgNPs) are commonly used in commercial and medical applications. However, AgNPs may induce toxicity, extracellular matrix (ECM) changes and inflammatory responses. Fibroblasts are key players in remodeling processes and major producers of the ECM. The aims of this study were to [...] Read more.

Silver nanoparticles (AgNPs) are commonly used in commercial and medical applications. However, AgNPs may induce toxicity, extracellular matrix (ECM) changes and inflammatory responses. Fibroblasts are key players in remodeling processes and major producers of the ECM. The aims of this study were to explore the effect of AgNPs on cell viability, both ex vivo in murine precision cut lung slices (PCLS) and in vitro in human lung fibroblasts (HFL-1), and immunomodulatory responses in fibroblasts. PCLS and HFL-1 were exposed to AgNPs with different sizes, 10 nm and 75 nm, at concentrations 2 µg/mL and 10 μg/mL. Changes in synthesis of ECM proteins, growth factors and cytokines were analyzed in HFL-1. Ag10 and Ag75 affected cell viability, with significantly reduced metabolic activities at 10 μg/mL in both PCLS and HFL-1 after 48 h. AgNPs significantly increased procollagen I synthesis and release of IL-8, prostaglandin E₂, RANTES and eotaxin, whereas reduced IL-6 release was observed in HFL-1 after 72 h. Our data indicate toxic effects of AgNP exposure on cell viability ex vivo and in vitro with altered procollagen and proinflammatory cytokine secretion in fibroblasts over time. Hence, careful characterizations of AgNPs are of importance, and future studies should include timepoints beyond 24 h. Full article

(This article belongs to the Special Issue Silver Nanoparticles: Synthesis, Detection, Characterization and Assessment in Environment)

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15 pages, 1871 KiB

Open AccessFeature PaperArticle

Developing a Highly Stable Carlina acaulis Essential Oil Nanoemulsion for Managing Lobesia botrana

by Giovanni Benelli, Lucia Pavoni, Valeria Zeni, Renato Ricciardi, Francesca Cosci, Gloria Cacopardo, Saverio Gendusa, Eleonora Spinozzi, Riccardo Petrelli, Loredana Cappellacci, Filippo Maggi, Roman Pavela, Giulia Bonacucina and Andrea Lucchi

Nanomaterials 2020, 10(9), 1867; https://doi.org/10.3390/nano10091867 - 18 Sep 2020

Cited by 60 | Viewed by 4409

Abstract

The growing interest in the development of green pest management strategies is leading to the exploitation of essential oils (EOs) as promising botanical pesticides. In this respect, nanotechnology could efficiently support the use of EOs through their encapsulation into stable nanoformulations, such as [...] Read more.

The growing interest in the development of green pest management strategies is leading to the exploitation of essential oils (EOs) as promising botanical pesticides. In this respect, nanotechnology could efficiently support the use of EOs through their encapsulation into stable nanoformulations, such as nanoemulsions (NEs), to improve their stability and efficacy. This technology assures the improvement of the chemical stability, hydrophilicity, and environmental persistence of EOs, giving an added value for the fabrication of natural insecticides effective against a wide spectrum of insect vectors and pests of public and agronomical importance. Carlina acaulis (Asteraceae) root EO has been recently proposed as a promising ingredient of a new generation of botanical insecticides. In the present study, a highly stable C. acaulis-based NE was developed. Interestingly, such a nanosystem was able to encapsulate 6% (w/w) of C. acaulis EO, showing a mean diameter of around 140 nm and a SOR (surfactant-to-oil ratio) of 0.6. Its stability was evaluated in a storage period of six months and corroborated by an accelerated stability study. Therefore, the C. acaulis EO and C. acaulis-based NE were evaluated for their toxicity against 1st instar larvae of the European grapevine moth (EGVM), Lobesia botrana (Denis & Schiffermüller, 1775) (Lepidoptera: Tortricidae), a major vineyard pest. The chemical composition of C. acaulis EO was investigated by gas chromatography–mass spectrometry (GC–MS) revealing carlina oxide, a polyacetylene, as the main constituent. In toxicity assays, both the C. acaulis EO and the C. acaulis-based NE were highly toxic to L. botrana larvae, with LC₅₀ values of 7.299 and 9.044 µL/mL for C. acaulis EO and NE, respectively. The C. acaulis-based NE represents a promising option to develop highly stable botanical insecticides for pest management. To date, this study represents the first evidence about the insecticidal toxicity of EOs and EO-based NEs against this major grapevine pest. Full article

(This article belongs to the Special Issue Green Synthesis of Nanomaterials and Their Biological Applications)

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17 pages, 5217 KiB

Open AccessArticle

Plasmon-Assisted Direction- and Polarization-Sensitive Organic Thin-Film Detector

by Michael J. Haslinger, Dmitry Sivun, Hannes Pöhl, Battulga Munkhbat, Michael Mühlberger, Thomas A. Klar, Markus C. Scharber and Calin Hrelescu

Nanomaterials 2020, 10(9), 1866; https://doi.org/10.3390/nano10091866 - 17 Sep 2020

Cited by 10 | Viewed by 2703

Abstract

Utilizing Bragg surface plasmon polaritons (SPPs) on metal nanostructures for the use in optical devices has been intensively investigated in recent years. Here, we demonstrate the integration of nanostructured metal electrodes into an ITO-free thin film bulk heterojunction organic solar cell, by direct [...] Read more.

Utilizing Bragg surface plasmon polaritons (SPPs) on metal nanostructures for the use in optical devices has been intensively investigated in recent years. Here, we demonstrate the integration of nanostructured metal electrodes into an ITO-free thin film bulk heterojunction organic solar cell, by direct fabrication on a nanoimprinted substrate. The nanostructured device shows interesting optical and electrical behavior, depending on angle and polarization of incidence and the side of excitation. Remarkably, for incidence through the top electrode, a dependency on linear polarization and angle of incidence can be observed. We show that these peculiar characteristics can be attributed to the excitation of dispersive and non-dispersive Bragg SPPs on the metal–dielectric interface on the top electrode and compare it with incidence through the bottom electrode. Furthermore, the optical and electrical response can be controlled by the organic photoactive material, the nanostructures, the materials used for the electrodes and the epoxy encapsulation. Our device can be used as a detector, which generates a direct electrical readout and therefore enables the measuring of the angle of incidence of up to 60° or the linear polarization state of light, in a spectral region, which is determined by the active material. Our results could furthermore lead to novel organic Bragg SPP-based sensor for a number of applications. Full article

(This article belongs to the Special Issue Nanoimprint Lithography Technology and Applications)

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