The Kinetic Aspects of the Dissolution of Slightly Soluble Lanthanoid Carbonates
Abstract
:1. Introduction
2. Materials and Methods
3. Results
4. Discussion
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
- Binnemans, K.; Jones, P.T.; Blanpain, B.; Gerven, T.V.; Pontikes, Y. Towards zero-waste valorization of rare-earth-containing industrial process residues. J. Clean. Prod. 2015, 99, 17–38. [Google Scholar] [CrossRef] [Green Version]
- Bykhovsky, L.Z.; Arkhangelskаya, V.V.; Tigunov, L.P.; Anufrieva, S.I. Prospects for the development of the mineral resource base and the development of production. VIMS Miner. Raw Mater. 2007, 22, 45. [Google Scholar]
- Pyagai, I.N.; Kozhevnikov, V.L.; Pasechnik, L.A.; Skachkov, V.M. Processing of slime of alumina production with extraction of scandium concentrate. J. Min. Inst. 2016, 218, 225–232. [Google Scholar]
- Chaschina, E.S.; Bagnavets, N.L. Use of phosphoric acid purified by extraction method for production of phosphorus fertilizers. News RSAU-MTAA 2010, 5, 151–155. [Google Scholar]
- Kochetkov, S.P.; Smirnov, N.N.; Ilyin, A. Concentration and Purification of Extraction Phosphoric Acid. Solvent Extr. Res. Dev. Jpn. 2007, 304, 23–35. [Google Scholar]
- Rutherford, P.M.; Dudas, M.J.; Samek, R.A. Environmental impacts of phosphogypsum. Sci. Total Environ. 1994, 149, 1–38. [Google Scholar] [CrossRef]
- Evan, K. The history, challenges and new developments in the management and use of bauxite residue. J. Sustain. Met. 2016, 2, 316–331. [Google Scholar] [CrossRef] [Green Version]
- Ritters, S.K. Making the most of red mud. C EN 2014, 92, 33. [Google Scholar]
- Utkov, V.A.; Sizyakov, V.M. Modern issues of metallurgical processing of red sludge. J. Min. Inst. 2013, 202, 39–43. [Google Scholar]
- Trushko, V.L.; Utkov, V.A.; Bazhin, V.Y. Relevance and ways of full processing of red mud from alumina production. J. Min. Inst. 2017, 227, 547–553. [Google Scholar]
- Besedin, A.A.; Utkov, V.A.; Brichkin, V.N.; Sizyakov, V.M. Agglomeration sintering of red sludge. Obogashchenie Rud 2014, 2, 28–31. [Google Scholar]
- Sabirzyanov, N.A.; Yatsenko, S.P. Hydrochemical Methods of Complex Processing of Bauxite; Ural RAS: Ekaterinburg, Russia, 2006. [Google Scholar]
- Tsakiridis, P.E.; Agatzini-Leonardou, S.; Oustadakis, P. Red mud addition in the raw meal for the production of Portland cement clinker. J. Hazard. Mater. 2004, 116, 103–110. [Google Scholar] [CrossRef]
- Cakici, A.I.; Yanik, J.; Karayildirim, T.; Anil, H. Utilization of red mud as catalyst in conversion of waste oil and waste plastics to fuel. J. Mater. Cycles Waste Manag. 2004, 6, 20–26. [Google Scholar]
- Stepanov, S.I.; Aung, M.M.; Aung, H.J.; Boyarintsev, A.V. Chemical aspects of carbonate leaching of scandium from red sludges. Bull. VGUIT 2018, 4, 349–355. [Google Scholar]
- Dubovikov, O.A.; Brichkin, V.N.; Besedin, A.A. Dehydration of red sludge and the main directions of its processing. Obogashchenie Rud 2014, 1, 44–49. [Google Scholar]
- Zubkova, O.S.; Alekseev, A.I.; Zalilova, M.M. Research of combined use of carbon and aluminum compounds for wastewater treatment. Izv. Vyss. Uchebnykh Zaved. Seriya Khim. Khim. Tekhnol. 2020, 63, 86–91. [Google Scholar] [CrossRef]
- Borra, C.R.; Mermans, J.; Blanpain, B.; Pontikes, Y.; Binnemans, K.; Gerven, T.V. Selective leaching of rare earths from bauxite residue after sulphation roasting. In Proceedings of the Bauxite Residue Valorization and Best Practices Conference, Leuven, Belgium, 5–7 October 2015; pp. 301–308. [Google Scholar]
- Tsai, H.S.; Tsai, T.H. Extraction Equilibrium of Indium(III) from Nitric Acid Solutions by Di(2-ethylhexyl)phosphoric Acid Dissolved in Kerosene. Molecules 2012, 17, 408–419. [Google Scholar] [CrossRef] [Green Version]
- Wu, S.; Wang, L.; Zhang, P.; El-Shall, H.; Moudgil, B.; Huang, X.; Zhao, L.; Zhang, L.; Feng, Z. Simultaneous recovery of rare earths and uranium from wet process phosphoric acid using solvent extraction with D2EHPA. Hydrometallurgy 2018, 175, 109–116. [Google Scholar] [CrossRef] [Green Version]
- Batchu, N.K.; Binnemans, K. Effect of the diluent on the solvent extraction of neodymium(III) by bis(2-ethylhexyl)phosphoric acid (D2EHPA). Hydrometallurgy 2018, 177, 146–151. [Google Scholar] [CrossRef]
- Alberts, E. Stripping Rare Earth Elements and Iron from D2EHPA during Zinc Solvent Extraction; Stellenbosch University: Stellenbosch, South Africa, 2011; p. 121. [Google Scholar]
- Papkova, M.V.; Mikhailichenko, A.I.; Konkova, T.V. Sorption extraction of rare-earth elements from phosphoric acid solutions. Sorption Chromatogr. Process. 2016, 16, 163–172. [Google Scholar]
- Martín, D.M.; Jalaff, L.D.; García, M.A.; Faccini, M. Selective recovery of europium and yttrium ions with cyanex 272-polyacrylonitrile nanofibers. Nanomaterials 2019, 9, 1648. [Google Scholar] [CrossRef] [Green Version]
- Weilert, A.V.; Pyagai, I.N.; Kozhevnikov, V.L.; Pasechnik, L.A.; Yatsenko, S.P. Autoclave-hydrometallurgical processing of red clay sludge. Non-Ferr. Met. 2014, 3, 31–35. [Google Scholar]
- Medvedev, A.S.; Khayrullina, R.T.; Kirov, S.S.; Suss, A.G. Technical scandium oxide obtaining from red mud of Urals Aluminium Smelter. Non-Ferr. Met. 2015, 12, 47–52. [Google Scholar] [CrossRef]
- Medvedev, A.S.; Kirov, S.S.; Khayrullina, R.T.; Suss, A.G. Carbonization leaching of scandium from red mud with preliminary pulp gassing by carbonic acid. Non-Ferr. Met. 2016, 6, 67–73. [Google Scholar] [CrossRef]
- Cheremisina, O.V.; Sergeev, V.V.; Fedorov, A.T.; Alferova, D.A. Separation of rare-earth metals and titanium in complex apatite concentrate processing. Obogashchenie Rud 2020, 5, 30–34. [Google Scholar] [CrossRef]
- Cheremisina, O.V.; Cheremisina, E.; Ponomareva, M.A.; Fedorov, A.T. Sorption of rare earth coordination compounds. J. Min. Inst. 2020, 244, 474–481. [Google Scholar] [CrossRef]
- Lebedev, I.A.; Kulyako, Y.M. Thermodynamic stability constants of phosphate complexes. WNH 1978, 23, 3215–3227. [Google Scholar]
- Spahiu, K.; Bruno, J. A Selected Thermodynamic Database for REE to be Used in HLNW Performance Assessment Exercises. MBT Tecnol. Ambient. 1995, 28, 2–22. [Google Scholar]
- Ravikumar, B.; Ramaswamy, S.; Pandiarajan, S. FTIR and laser RAMAN spectral analysis of crystalline DL–valinium dihydrogen phosphate. Int. J. Eng. Sci. Technol. 2012, 4, 1658–1666. [Google Scholar]
- Kashurin, R.R.; Gerasev, S.A.; Litvinova, T.E.; Zhadovskiy, I.T. Prospective recovery of rare earth elements from waste. J. Phys. Conf. Ser. 2020, 1679, 052070. [Google Scholar] [CrossRef]
- Ermakova, N.V.; Burmaa, D.; Ivanov, V.M.; Figurovskaya, V.N. Definition of lanthanum (III), terbium (III) and erbium (III) in alkali metal halides and sulphates doped with rare earth elements. Mosc. Univ. Chem. Bull. 2000, 41, 305–308. [Google Scholar]
- Gupta, C.K. Chemical Metallurgy: Principles and Practice; Wiley-VCH Verlag GmbH & Co.: Hoboken, NJ, USA, 2003; pp. 322–327. [Google Scholar]
- Liu, Z.; Dreybrodt, W. Dissolution kinetics of calcium carbonate minerals in H2O-CO2 solutions in turbulent flow: The role of the diffusion boundary layer and the slow reaction H2O + CO2 = H+ + HCO3-. Geochim. Cosmochim. Acta 1997, 61, 2879–2889. [Google Scholar] [CrossRef]
- Wang, Y.; Abrahamsson, B.; Lindfors, L.; Brasseur, J. Analysis of Diffusion-Controlled Dissolution from Polydisperse Collections of Drug Particles with an Assessed Mathematical Model. J. Pharm. Sci. 2015, 104, 2998–3017. [Google Scholar] [CrossRef] [PubMed]
Element | logK |
---|---|
La | −35.1 |
Ce | −35.3 |
Pr | −34.8 |
Nd | −34.65 |
Sm | −34.5 |
Eu | −35.0 |
Gd | −34.7 |
Tb | −34.2 |
Dy | −34.0 |
Ho | −33.8 |
Er | −33.6 |
Tm | −33.4 |
Yb | −33.3 |
Lu | −33.0 |
Element | P, % | ||||||||
---|---|---|---|---|---|---|---|---|---|
Ce | 0.1 | 0.5 | 1.4 | 3.2 | 6.2 | 11.0 | 18.1 | 27.6 | 37.8 |
Nd | 2.1 | 3.4 | 5.3 | 7.8 | 11.4 | 16.3 | 22.7 | 30.2 | 37.1 |
Yb | 2.4 | 4.1 | 6.3 | 9.5 | 13.9 | 19.9 | 27.5 | 36.5 | 45.7 |
D, microns | 2.02 | 2.54 | 3.2 | 4.03 | 5.08 | 6.40 | 8.06 | 10.2 | 12.8 |
Ce | 48.5 | 59.5 | 69.7 | 75.8 | 81.5 | 86.1 | 89.6 | 95.0 | 97.7 |
Nd | 43.9 | 51.4 | 58.6 | 64.3 | 69.8 | 74.4 | 77.6 | 83.1 | 88.4 |
Yb | 56.1 | 68.1 | 79.8 | 87.8 | 93.6 | 97.1 | 99.0 | 99.7 | 99.7 |
D, microns | 16.1 | 20.0 | 25.6 | 32.3 | 40.6 | 50 | 60 | 81.3 | 102.0 |
Process Parameter | Value | Dimension |
---|---|---|
Concentration CO32− in solution | 0.5–1.5 | mol/L |
Agitation intensity | 1000 | rpm |
Temperature | 293–313 | К |
Mixing time | 0.5–50 | min |
pH | 11.5–12.0 | - |
Ratio l:s | 2100 | mL/g |
[K2СO3], mol/L | Dependency Equation (Nd) | Dependency Equation (Yb) |
---|---|---|
0.5 | y = 0.1346ln(x) + 0.0972 | y = 0.1282ln(x) + 0.2724 |
0.7 | y = 0.1452ln(x) + 0.1752 | y = 0.1161ln(x) + 0.3738 |
1 | y = 0.1492ln(x) + 0.2393 | y = 0.1008ln(x) + 0.4667 |
[K2СO3], mol/L | Dependency Equation (Ce) | - |
0.5 | y = 0.1424ln(x) + 0.1059 | - |
1 | y = 0.1127ln(x) + 0.2983 | - |
1.5 | y = 0.0857ln(x) + 0.5645 | - |
Т, °С | Nd | Yb | Ce |
---|---|---|---|
20 | y = 0.1719ln(x) + 0.2658 | y = 0.1158ln(x) + 0.4679 | y = 0.0898ln(x) + 0.5625 |
30 | y = 0.1724ln(x) + 0.3395 | y = 0.1201ln(x) + 0.5243 | y = 0.0938ln(x) + 0.6295 |
40 | y = 0.1719ln(x) + 0.4461 | y = 0.1154ln(x) + 0.6063 | y = 0.0944ln(x) + 0.7087 |
Т, oС | Nd | Yb | Ce |
---|---|---|---|
20 | y = 0.0819x + 3.3162 | y = 0.0722x + 3.6451 | y = 0.0642x + 3.8559 |
30 | y = 0.0961x + 3.4225 | y = 0.0668x + 3.8901 | y = 0.087x + 4.0255 |
40 | y = 0.1552x + 3.4563 | y = 0.0994x + 4.0251 | y = 0.139x + 4.2301 |
[K2СO3], mol/L | Dependency Equation (Nd) | Dependency Equation (Yb) |
---|---|---|
0.5 | y = 0.0559x + 3.0316 | y = 0.0729x + 3.2243 |
0.7 | y = 0.0678x + 3.1042 | y = 0.0735x + 3.3784 |
1 | y = 0.0708x + 3.1905 | y = 0.0754x + 3.5312 |
[K2СO3], mol/L | Dependency Equation (Ce) | - |
0.5 | y = 0.0611x + 3.037 | - |
1 | y = 0.0639x + 3.278 | - |
1.5 | y = 0.0642x + 3.856 | - |
Т, oС | Nd | Yb | Ce |
---|---|---|---|
20 | y = 4.7987x − 13.22 | y = 5.4689x − 16.199 | y = 7.1671x − 22.721 |
30 | y = 4.7989x − 12.639 | y = 5.4584x − 15.311 | y = 7.4179x − 22.47 |
40 | y = 4.799x − 12.059 | y = 5.448x − 14.422 | y = 7.6687x − 22.218 |
Element | Activation Energy, kJ/mol | Arrhenius Constant, min−1 | Apparent Order of Reaction n |
---|---|---|---|
Ce | 61.6 | 1.29 × 1010 | 1.00 |
Nd | 39.9 | 1.85 × 1010 | 1.00 |
Yb | 45.4 | 1.47 × 1010 | 1.00 |
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Litvinova, T.; Kashurin, R.; Zhadovskiy, I.; Gerasev, S. The Kinetic Aspects of the Dissolution of Slightly Soluble Lanthanoid Carbonates. Metals 2021, 11, 1793. https://doi.org/10.3390/met11111793
Litvinova T, Kashurin R, Zhadovskiy I, Gerasev S. The Kinetic Aspects of the Dissolution of Slightly Soluble Lanthanoid Carbonates. Metals. 2021; 11(11):1793. https://doi.org/10.3390/met11111793
Chicago/Turabian StyleLitvinova, Tatiana, Ruslan Kashurin, Ivan Zhadovskiy, and Stepan Gerasev. 2021. "The Kinetic Aspects of the Dissolution of Slightly Soluble Lanthanoid Carbonates" Metals 11, no. 11: 1793. https://doi.org/10.3390/met11111793