The Effect of Dual-Modification by Heat-Moisture Treatment and Octenylsuccinylation on Physicochemical and Pasting Properties of Arrowroot Starch
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Arrowroot Starch Isolation
2.3. Heat-Moisture Treated (HMT) Starch Preparation
2.4. Octenylsuccinilated (OSA) Starch Preparation
2.5. Dual Modification by HMT Followed by OSA (HMT-OSA)
2.6. Dual Modification by OSA Followed by HMT (OSA-HMT)
2.7. Granule Morphology Observation Using Scanning Electron Microscopy (SEM)
2.8. Starch Crystallinity Using X-ray Diffractometer (XRD)
2.9. Thermal Properties Determination Using Differential Scanning Calorimetry (DSC)
2.10. Pasting Properties Determination Using Rapid Visco Analyzer (RVA)
2.11. Texture Properties Evaluation Using Texture Analyzer (TA)
2.12. Functional Properties
2.13. Color Analysis Using CM-5 Spectrophotometer
2.14. Statistical Analysis
3. Results
3.1. Granule Morphology
3.2. Starch Crystallinity
3.3. Thermal Properties
3.4. Pasting Properties
3.5. Texture Properties
3.6. Functional Properties
3.7. Color Characteristics
4. Discussion
4.1. Granule Morphology
4.2. Crystallinity
4.3. Thermal Properties
4.4. Pasting Properties
4.5. Texture Properties
4.6. Functional Properties
4.7. Color Analysis
5. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Treatment | To (°C) | Tp (°C) | Tc (°C) | Tc–To (°C) | ∆H (J/g) |
---|---|---|---|---|---|
Native | 21.70 ± 3.86 a | 50.46 ± 5.89 a | 62.29 ± 3.60 b | 40.60 ± 7.21 bc | 1117.08 ± 56.09 a |
OSA | 14.39 ± 0.69 b | 39.83 ± 3.96 b | 58.99 ± 6.67 bc | 44.60 ± 7.08 b | 647.30 ± 45.86 d |
HMT | 20.43 ± 2.60 a | 44.36 ± 2.60 ab | 53.75 ± 1.65 c | 33.32 ± 2.55 c | 936.44 ± 35.08 b |
HMT-OSA | 10.89 ± 3.01 b | 42.98 ± 3.62 ab | 85.76 ± 1.11 a | 74.87 ± 2.44 a | 781.64 ± 30.73 c |
OSA-HMT | 11.38 ± 2.21 b | 39.98 ± 5.51 b | 83.96 ± 1.70 a | 72.58 ± 1.32 a | 902.26 ± 87.22 b |
Treatment | Pasting Temperature (°C) | Peak Viscosity (cP) | Hold Viscosity (cP) | Final Viscosity (cP) | Breakdown (cP) | Setback (cP) |
---|---|---|---|---|---|---|
Native | 75.74 ± 0.26 a | 4857 ± 42.52 d | 2119 ± 37.58 bc | 3087 ± 41.15 a | 2738 ± 7.00 d | 967 ± 15.50 a |
OSA | 73.02 ± 0.08 a | 6094 ± 60.86 e | 3033 ± 157.88 d | 3956 ± 167.62 c | 3060 ± 216.75 e | 923 ± 316.74 a |
HMT | 86.91 ± 0.42 c | 1604 ± 57.50 a | 1486 ± 60.00 a | 2860 ± 61.49 a | 118 ± 3.61 a | 1373 ± 9.50 b |
HMT-OSA | 86.78 ± 0.46 c | 3111 ± 263.28 c | 2261 ± 79.00 c | 4081 ± 221.72 c | 850 ± 188.80 c | 1787 ± 122.11 c |
OSA-HMT | 83.21 ± 4.03 b | 2544 ± 63.58 b | 2063 ± 99.00 b | 3621 ± 242.31 b | 481 ± 35.59 b | 1557 ± 166.08 bc |
Treatment | Hardness (gF) | Adhesiveness | Springiness | Cohesiveness | Gumminess |
---|---|---|---|---|---|
Native | 244.51 ± 36.93 b | −3.10 ± 2.74 c | 1.58 ± 1.02 a | 0.86 ± 0.02 c | 208.95 ± 27.82 b |
OSA | 485.03 ± 35.65 d | −34.20 ± 0.85 b | 0.90 ± 0.01 a | 0.76 ± 0.01 b | 368.29 ± 21.10 d |
HMT | 406.78 ± 36.95 c | −47.50 ± 24.71 b | 0.90 ± 0.04 a | 0.68 ± 0.05 a | 274.39 ± 21.43 c |
HMT-OSA | 43.68 ± 5.89 a | −54.14 ± 6.61 b | 0.83 ± 0.00 a | 0.60 ± 0.02 a | 29.21 ± 3.49 a |
OSA-HMT | 76.95 ± 14.88 a | −103.14 ± 6.12 a | 0.86 ± 0.02 a | 0.64 ± 0.06 a | 59.59 ± 10.38 a |
Treatment | Swelling Volume (mL/g db) | Solubility (%) | WAC (g/g db) | OAC (g/g db) | Syneresis (%) |
---|---|---|---|---|---|
Native | 16.27 ± 0.12 c | 9.33 ± 0.14 c | 1.13 ± 0.20 b | 2.33 ± 0.03 b | 7.02 ± 0.06 a |
OSA | 25.84 ± 0.56 e | 9.13 ± 0.21 b | 0.83 ± 0.10 a | 2.31 ± 0.07 b | 18.71 ± 0.96 b |
HMT | 11.46 ± 0.54 a | 8.92 ± 0.14 a | 1.35 ± 0.05 c | 2.15 ± 0.12 a | 38.76 ± 0.49 c |
HMT-OSA | 17.66 ± 0.17 d | 9.08 ± 0.09 b | 1.41 ± 0.07 c | 2.21 ± 0.09 a | 59.06 ± 2.27 d |
OSA-HMT | 14.31 ± 0.34 b | 8.90 ± 0.04 a | 1.60 ± 0.06 d | 2.20 ± 0.04 a | 65.80 ± 3.54 e |
Treatment | L* | a* | b* | Whiteness Index | ∆E |
---|---|---|---|---|---|
Native | 96.26 ± 0.03 d | −0.25 ± 0.01 a | 3.18 ± 0.03 c | 95.09 ± 0.01 d | - |
OSA | 96.39 ± 0.19 d | −0.29 ± 0.01 a | 2.13. ± 0.10 a | 95.80 ± 0.11 e | 1.08 ± 0.11 |
HMT | 94.96 ± 0.12 a | 0.09 ± 0.00 b | 4.07 ± 0.01 d | 93.52 ± 0.09 a | 1.61 ± 0.09 |
HMT-OSA | 95.44 ± 0.24 b | 0.05 ± 0.03 b | 3.07 ± 0.23 bc | 94.51 ± 0.33 b | 0.92 ± 0.13 |
OSA-HMT | 95.80 ± 0.09 c | 0.07 ± 0.07 b | 2.97 ± 0.25 b | 94.86 ± 0.22 c | 0.64 ± 0.09 |
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Marta, H.; Rismawati, A.; Soeherman, G.P.; Cahyana, Y.; Djali, M.; Yuliana, T.; Sondari, D. The Effect of Dual-Modification by Heat-Moisture Treatment and Octenylsuccinylation on Physicochemical and Pasting Properties of Arrowroot Starch. Polymers 2023, 15, 3215. https://doi.org/10.3390/polym15153215
Marta H, Rismawati A, Soeherman GP, Cahyana Y, Djali M, Yuliana T, Sondari D. The Effect of Dual-Modification by Heat-Moisture Treatment and Octenylsuccinylation on Physicochemical and Pasting Properties of Arrowroot Starch. Polymers. 2023; 15(15):3215. https://doi.org/10.3390/polym15153215
Chicago/Turabian StyleMarta, Herlina, Ari Rismawati, Giffary Pramafisi Soeherman, Yana Cahyana, Mohamad Djali, Tri Yuliana, and Dewi Sondari. 2023. "The Effect of Dual-Modification by Heat-Moisture Treatment and Octenylsuccinylation on Physicochemical and Pasting Properties of Arrowroot Starch" Polymers 15, no. 15: 3215. https://doi.org/10.3390/polym15153215