Chitosan-Strontium Oxide Nanocomposite: Preparation, Characterization, and Catalytic Potency in Thiadiazoles Synthesis
Abstract
:1. Introduction
2. Materials and Methods
2.1. CS-SrO Nanocomposite Film Preparation
2.2. Reactions of 2-{1-[4-(2,4-Dihydroxyphenylazo)phenyl]ethylidene}thiosemicarbazide (1) with N-Aryl Arenecarbohydrazonyl Halides 2a–e
3. Results and Discussion
3.1. Characterization of Chitosan-Strontium Oxide Nanocomposite Film
3.1.1. Characterization via FTIR
3.1.2. SEM and Morphological Characteristics
3.1.3. Energy-Dispersive X-ray Spectroscopy (EDS) and Estimation of Strontium Amount
3.1.4. X-ray Diffraction Pattern (XRD)
3.2. Synthesis of 2-Hydrazono [1,3,4]thiadiazole Derivatives
3.2.1. Catalyst Loading and Reaction Conditions Optimization
3.2.2. Utility of CS-SrO as Nanocatalyst in the Synthesis of -1,3,4-Thiadiazole Derivatives
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Compd. No. | Ar1 | Ar2 | Yield (%) Thermal | Yield (%) MW | ||
---|---|---|---|---|---|---|
TEA | CS/SrO | TEA | CS/SrO | |||
5a | C6H5 | C6H5 | 72 | 84 | 78 | 95 |
5b | 4-CH3C6H4 | C6H5 | 70 | 81 | 75 | 92 |
5c | 4-CH3OC6H4 | C6H5 | 70 | 82 | 76 | 91 |
5d | 4-ClC6H4 | C6H5 | 68 | 80 | 73 | 91 |
5e | C6H5 | 4-NO2C6H4 | 70 | 83 | 77 | 93 |
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Khalil, K.D.; Riyadh, S.M.; Alkayal, N.S.; Bashal, A.H.; Alharbi, K.H.; Alharbi, W. Chitosan-Strontium Oxide Nanocomposite: Preparation, Characterization, and Catalytic Potency in Thiadiazoles Synthesis. Polymers 2022, 14, 2827. https://doi.org/10.3390/polym14142827
Khalil KD, Riyadh SM, Alkayal NS, Bashal AH, Alharbi KH, Alharbi W. Chitosan-Strontium Oxide Nanocomposite: Preparation, Characterization, and Catalytic Potency in Thiadiazoles Synthesis. Polymers. 2022; 14(14):2827. https://doi.org/10.3390/polym14142827
Chicago/Turabian StyleKhalil, Khaled D., Sayed M. Riyadh, Nazeeha S. Alkayal, Ali H. Bashal, Khadijah H. Alharbi, and Walaa Alharbi. 2022. "Chitosan-Strontium Oxide Nanocomposite: Preparation, Characterization, and Catalytic Potency in Thiadiazoles Synthesis" Polymers 14, no. 14: 2827. https://doi.org/10.3390/polym14142827