Effect of Bimetallic-Activated Carbon Impregnation on Adsorption–Desorption Performance for Hydrogen Sulfide (H2S) Capture
Abstract
:1. Introduction
2. Materials and Methods
2.1. Adsorbent Preparation
2.2. Characterization of Adsorbents
2.3. Real Test of Adsorption–Desorption of H2S Gas
3. Results and Discussion
3.1. Characterization Analysis for Fresh Adsorbent
- (a)
- SEM-EDX analysis
- (b)
- BET analysis
- (c)
- FTIR analysis
- (d)
- TGA
3.2. Real Test of Adsorption–Desorption of H2S
3.3. Effect of Temperature on Desorption
3.4. Analysis of Spent Adsorbents
- (a)
- SEM-EDX analysis
- (b)
- BET analysis
- (c)
- TGA
- (d)
- FTIR
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Adsorbents | C | Ca | O | K | Ti | Zn |
---|---|---|---|---|---|---|
ZnAc2/ZnO/CAC_DCM (F) | 37.2 | 1.31 | 33.26 | 0 | 0 | 30.14 |
ZnAc2/TiO2/CAC_DCM (F) | 36.70 | 1.01 | 28.60 | 0 | 18.83 | 14.95 |
ZnAc2/KOH/CAC_DCM (F) | 43.92 | 0.92 | 24.86 | 13.39 | 0 | 16.91 |
ZnAc2/CAC_SI (F) | 86.36 | 0.43 | 6.93 | 0 | 0 | 6.28 |
Raw CAC (F) | 96.94 | 0.73 | 2.33 | 0 | 0 | 0 |
Adsorbents | BET Surface Area, SBET (m2/g) | Total Pore Volume (cm3/g) | Micropore Area (m2/g) | Pore Size (Å) |
---|---|---|---|---|
ZnAc2/ZnO/CAC_DCM (F) | 847.10 | 0.41 | 688.14 | 19.21 |
ZnAc2/TiO2/CAC_DCM (F) | 902.25 | 0.44 | 706.03 | 19.33 |
ZnAc2/KOH/CAC_DCM (F) | 887.54 | 0.43 | 709.92 | 19.17 |
ZnAc2/CAC_SI (F) | 868.05 | 0.41 | 702.89 | 19.34 |
Raw CAC (F) | 899.05 | 0.42 | 730.02 | 18.82 |
Adsorbents | Temperature Derivative (°C) | Weight Loss (%) |
---|---|---|
ZnAc2/ZnO/CAC_DCM | 25–100 | 10.23 |
100–400 | 3.90 | |
400–600 | 3.76 | |
ZnAc2/TiO2/CAC_DCM | 25–100 | 10.29 |
100–400 | 2.62 | |
400–600 | 4.55 | |
ZnAc2/KOH/CAC_DCM | 25–100 | 11.92 |
100–400 | 4.27 | |
400–600 | 4.29 | |
ZnAc2/CAC_SI | 25–100 | 6.9 |
100–400 | 6.1 | |
400–600 | 3.1 | |
Raw CAC | 25–100 | 15.4 |
100–400 | 4.80 | |
400–600 | 4.90 |
Adsorbents | Breakthrough Time (Min) | Adsorption Capacity (mg H2S/g) |
---|---|---|
ZnAc2/ZnO/CAC_DCM | 46 | 1.92 |
ZnAc2/KOH/CAC_DCM | 39 | 1.49 |
ZnAc2/TiO2/CAC_DCM | 42 | 1.88 |
ZnAc2/CAC_SI | 25 | 1.04 |
Raw CAC | 5 | 0.21 |
Adsorbent | No. of Cycles | Blower Temperature (°C) | Breakthrough Time (Min) | H2S Adsorption Capacity (mg H2S/g) | Degradation Percentage (%) |
---|---|---|---|---|---|
ZnAc2/ZnO/CAC_DCM | 1 | 50 | 43 | 1.80 | 0 |
2 | 23 | 0.96 | 46.7 | ||
3 | 17 | 0.71 | 26.0 | ||
1 | 100 | 46 | 1.92 | 0 | |
2 | 25 | 1.04 | 45.8 | ||
3 | 19 | 0.79 | 24.0 | ||
1 | 150 | 42 | 1.65 | 0 | |
2 | 27 | 1.01 | 38.8 | ||
3 | 24 | 0.94 | 6.9 | ||
ZnAc2/KOH/CAC_DCM | 1 | 50 | 37 | 1.54 | 0 |
2 | 27 | 1.13 | 26.6 | ||
3 | 24 | 1.0 | 11.5 | ||
1 | 100 | 34 | 1.42 | 0 | |
2 | 23 | 0.96 | 32.4 | ||
3 | 20 | 0.84 | 12.5 | ||
1 | 150 | 30 | 1.25 | 0 | |
2 | 19 | 0.79 | 36.8 | ||
3 | 16 | 0.67 | 15.2 | ||
ZnAc2/TiO2/CAC_DCM | 1 | 50 | 40 | 1.67 | 0 |
2 | 19 | 0.79 | 52.7 | ||
3 | 15 | 0.63 | 20.3 | ||
1 | 100 | 44 | 1.84 | 0 | |
2 | 22 | 0.92 | 50.0 | ||
3 | 17 | 0.67 | 27.2 | ||
1 | 150 | 47 | 1.96 | 0 | |
2 | 24 | 1.0 | 49.0 | ||
3 | 17 | 0.71 | 29.0 | ||
ZnAc2/CAC_SI | 1 | 50 | 26 | 1.09 | 0 |
2 | 12 | 0.50 | 54.1 | ||
3 | 9 | 0.38 | 24.0 | ||
1 | 100 | 24 | 1.00 | 0 | |
2 | 13 | 0.54 | 46.0 | ||
3 | 10 | 0.42 | 22.2 | ||
1 | 150 | 25 | 1.04 | 0 | |
2 | 15 | 0.63 | 39.4 | ||
3 | 13 | 0.54 | 14.3 | ||
Raw CAC | 1 | 50 | 16 | 0.67 | 0 |
2 | 9 | 0.38 | 43.3 | ||
3 | 6 | 0.25 | 34.2 | ||
1 | 100 | 19 | 0.79 | 0 | |
2 | 16 | 0.67 | 15.19 | ||
3 | 13 | 0.54 | 19.4 | ||
1 | 150 | 18 | 0.75 | 0 | |
2 | 14 | 0.58 | 22.7 | ||
3 | 13 | 0.54 | 6.9 |
Adsorbents | C | Ca | O | Zn | S |
---|---|---|---|---|---|
ZnAc2/ZnO/CAC_DCM (D) at 50 °C | 76.42 | 0.61 | 6.73 | 11.11 | 5.13 |
ZnAc2/ZnO/CAC_DCM (D) at 100 °C | 76.21 | 0.23 | 8.11 | 10.68 | 4.77 |
ZnAc2/ZnO/CAC_DCM (D) at 150 °C | 76.41 | 0.19 | 9.32 | 10.93 | 3.15 |
ZnAc2/CAC_SI (D) at 50 °C | 83.86 | 0.69 | 3.31 | 6.71 | 5.43 |
ZnAc2/CAC_SI (D) at 100 °C | 85.35 | 0.72 | 4.92 | 6.23 | 2.78 |
ZnAc2/CAC_SI (D) at 150 °C | 84.97 | 0.83 | 5.70 | 6.58 | 1.92 |
Raw CAC at 50 °C | 94.27 | 0.45 | 1.13 | 0.00 | 4.15 |
Raw CAC at 100 °C | 94.23 | 0.43 | 2.17 | 0.00 | 3.17 |
Raw CAC at 150 °C | 94.07 | 0.39 | 4.32 | 0.00 | 1.22 |
Adsorbents | BET Surface Area (m2/g) | Total Pore Volume (cm3/g) | Micropore Surface Area (m2/g) | Pore Size (Å) |
---|---|---|---|---|
ZnAc2/ZnO/CAC_DCM (D) | 812.73 | 0.38 | 667.12 | 18.93 |
ZnAc2/TIO2/CAC_DCM (D) | 876.61 | 0.39 | 703.88 | 18.72 |
ZnAc2/KOH/CAC_DCM (D) | 862.14 | 0.41 | 702.70 | 18.91 |
ZnAc2/CAC_SI (D) | 745.16 | 0.36 | 591.87 | 18.96 |
Raw CAC (D) | 872.22 | 0.41 | 728.50 | 18.59 |
Adsorbents | Temperature Derivative (°C) | Weight Loss (F) (%) | Weight Loss (D) (%) |
---|---|---|---|
ZnAc2/ZnO/CAC_DCM (D) | 29–100 | 10.23 | 8.13 |
100–400 | 3.90 | 12.68 | |
400–600 | 3.76 | 16.36 | |
ZnAc2/TiO2/CAC_DCM (D) | 29–100 | 10.29 | 5.78 |
100–400 | 2.62 | 11.26 | |
400–600 | 4.55 | 15.83 | |
ZnAc2/KOH/CAC_DCM (D) | 29–100 | 11.92 | 10.86 |
100–400 | 4.27 | 14.76 | |
400–600 | 4.29 | 18.35 |
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Zulkefli, N.N.; Mathuray Veeran, L.S.; Noor Azam, A.M.I.; Masdar, M.S.; Wan Isahak, W.N.R. Effect of Bimetallic-Activated Carbon Impregnation on Adsorption–Desorption Performance for Hydrogen Sulfide (H2S) Capture. Materials 2022, 15, 5409. https://doi.org/10.3390/ma15155409
Zulkefli NN, Mathuray Veeran LS, Noor Azam AMI, Masdar MS, Wan Isahak WNR. Effect of Bimetallic-Activated Carbon Impregnation on Adsorption–Desorption Performance for Hydrogen Sulfide (H2S) Capture. Materials. 2022; 15(15):5409. https://doi.org/10.3390/ma15155409
Chicago/Turabian StyleZulkefli, Nurul Noramelya, Loshinni S. Mathuray Veeran, Adam Mohd Izhan Noor Azam, Mohd Shahbudin Masdar, and Wan Nor Roslam Wan Isahak. 2022. "Effect of Bimetallic-Activated Carbon Impregnation on Adsorption–Desorption Performance for Hydrogen Sulfide (H2S) Capture" Materials 15, no. 15: 5409. https://doi.org/10.3390/ma15155409