Study on Pyrolysis–Mechanics–Seepage Behavior of Oil Shale in a Closed System Subject to Real-Time Temperature Variations
Abstract
:1. Introduction
2. Methods
2.1. Closed, High-Temperature, and High-Pressure Thermal Simulations
2.2. Pyrolysis Reaction Kinetics Analysis Software
2.3. Real-Time Uniaxial Compressive Strength Tests on Oil Shale at High Temperatures
2.4. High-Temperature, Triaxial Permeability Test of Oil Shale
3. Results and Discussion
3.1. Regularity of the Formation of Hydrocarbon Products from the Pyrolysis of Oil Shale
3.2. Kinetic Analysis of Hydrocarbon Generation via Oil Shale Pyrolysis
3.3. Real-Time Evolution of the Compressive Strength of Oil Shale at High Temperatures
3.4. Evolution of Oil Shale Permeability with Increasing Temperatures
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Fischer Assay Analysis (wt.%, ad) | Composition (%) |
---|---|
Oil yield | 8.07 |
Water yield | 1.78 |
Residue | 86.73 |
Gas + loss | 3.42 |
Activation Energy (kJ/mol) | The Pre-Exponential Factor (min−1) | Reaction Fraction of Organic Matter to Methane | Reaction Fraction of Organic Matter to Gas |
---|---|---|---|
150 | 1016 | 5.38 × 10−4 | 4.35 × 10−3 |
160 | 5.38 × 10−4 | 4.35 × 10−3 | |
170 | 5.38 × 10−4 | 4.35 × 10−3 | |
180 | 5.27 × 10−4 | 4.34 × 10−3 | |
190 | 6.80 × 10−4 | 5.64 × 10−5 | |
200 | 1.64 × 10−4 | 1.77 × 10−4 | |
210 | 1.75 × 10−2 | 1.32 × 10−7 | |
220 | 8.57 × 10−3 | 6.64 × 10−2 | |
230 | 8.92 × 10−2 | 1.64 × 10−1 | |
240 | 7.45 × 10−2 | 2.31 × 10−1 | |
250 | 2.68 × 10−1 | 2.26 × 10−1 | |
260 | 1.51 × 10−1 | 1.64 × 10−1 | |
270 | 2.67 × 10−1 | 9.29 × 10−2 | |
280 | 1.21 × 10−1 | 2.71 × 10−2 | |
290 | 6.89 × 10−6 | 2.89 × 10−4 | |
300 | 3.18 × 10−4 | 1.64 × 10−4 | |
310 | 2.51 × 10−5 | 2.89 × 10−4 | |
320 | 1.30 × 10−6 | 1.61 × 10−4 | |
330 | 6.13 × 10−7 | 4.90 × 10−3 | |
340 | 5.92 × 10−6 | 5.01 × 10−3 | |
Average activation energy (kJ/mol) | 256.81 | 246.13 |
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Wang, L.; Su, J.; Yang, D. Study on Pyrolysis–Mechanics–Seepage Behavior of Oil Shale in a Closed System Subject to Real-Time Temperature Variations. Materials 2022, 15, 5368. https://doi.org/10.3390/ma15155368
Wang L, Su J, Yang D. Study on Pyrolysis–Mechanics–Seepage Behavior of Oil Shale in a Closed System Subject to Real-Time Temperature Variations. Materials. 2022; 15(15):5368. https://doi.org/10.3390/ma15155368
Chicago/Turabian StyleWang, Lei, Jianzheng Su, and Dong Yang. 2022. "Study on Pyrolysis–Mechanics–Seepage Behavior of Oil Shale in a Closed System Subject to Real-Time Temperature Variations" Materials 15, no. 15: 5368. https://doi.org/10.3390/ma15155368