Bionic Synthesis of Mussel-like Adhesive L-DMA and Its Effects on Asphalt Properties
Abstract
:1. Introduction
2. Materials and Experiments
2.1. Raw Materials
2.2. Synthesis of L-DMA
2.3. Chemical Structure and Thermal Stability Characterizations of L-DMA
2.4. Preparation of L-DMA-Modified Asphalt
2.5. Property Characterizations of L-DMA-Modified Asphalt
2.5.1. DSR Test
2.5.2. BBR Test
2.5.3. FTIR Spectroscopy Analysis
3. Results and Discussion
3.1. Structural Analysis and Thermal Stability Analysis of L-DMA
3.2. Modification Mechanism of L-DMA
3.3. Rheological Properties of L-DMA-Modified Asphalt
3.4. Low-Temperature Crack Resistance of L-DMA Modified Asphalt
4. Conclusions
- Comparing with MAA and L-DOPA, the infrared spectrum of L-DMA has new characteristic peaks at 3370 cm−1, 3202 cm−1, 1730 cm−1, 1655 cm−1, 1520 cm−1, 1605 cm−1, 1450 cm−1, and 1260 cm−1, which proves that L-DMA was synthesized successfully. Moreover, L-DMA has good thermal stability and can be used in asphalt materials.
- The modification of L-DMA to asphalt is mainly a physical process. Hydrogen bond and aromatic ring conjugation introduced by catechol can improve the adhesion of asphalt.
- L-DMA has a noticeable improvement impact on the high-temperature performance of asphalt due to the strong hydrogen bonding, conjugation of benzene rings, and transformation of quinone and semiquinone by catechol at high temperatures. Compared with 70# asphalt, L-DMA-modified asphalt has a higher composite modulus, rutting factor, viscosity, and creep recovery rate.
- The impact of LDMA on the low-temperature fracture resistance of asphalt is complicated. With the rise of L-DMA content, the low-temperature performance of modified asphalt drops initially and later increases. When the L-DMA content reaches 10%, the low-temperature fracture resistance of L-DMA modified asphalt will be higher than that of 70# asphalt due to the layered structure formed by aromatic ring conjugation.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Acknowledgments
Conflicts of Interest
References
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Properties | Test Value | Requirements |
---|---|---|
Penetration (25 °C, 0.1 mm) | 68.9 | 60–80 |
Ductility (15 °C, cm) | 184 | ≥100 |
Softening point (°C) | 48.4 | ≥46 |
Density (g/cm3) | 1.034 | - |
Temperature | Plate Diameter | Plate Gap | Shear Frequency | Heating Rate |
---|---|---|---|---|
−10–30 °C | 25 mm | 1 mm | 10 rad/s | 2 °C/min |
30–80 °C | 8 mm | 2 mm |
Samples | R-100 | R-3200 | -100 | -3200 |
---|---|---|---|---|
70# Base asphalt | 4.05 | 2.55 | 2.66 | 3.56 |
1% L-DMA | 5.67 | 2.95 | 2.62 | 2.75 |
2.5% L-DMA | 6.29 | 3.58 | 2.48 | 2.43 |
5% L-DMA | 6.32 | 3.62 | 2.18 | 2.23 |
7.5% L-DMA | 6.49 | 3.91 | 2.14 | 2.17 |
10% L-DMA | 7.32 | 4.11 | 1.78 | 1.83 |
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Wu, J.; Liu, Q.; Wu, S. Bionic Synthesis of Mussel-like Adhesive L-DMA and Its Effects on Asphalt Properties. Materials 2022, 15, 5351. https://doi.org/10.3390/ma15155351
Wu J, Liu Q, Wu S. Bionic Synthesis of Mussel-like Adhesive L-DMA and Its Effects on Asphalt Properties. Materials. 2022; 15(15):5351. https://doi.org/10.3390/ma15155351
Chicago/Turabian StyleWu, Jinyi, Quantao Liu, and Shaopeng Wu. 2022. "Bionic Synthesis of Mussel-like Adhesive L-DMA and Its Effects on Asphalt Properties" Materials 15, no. 15: 5351. https://doi.org/10.3390/ma15155351