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Review

A Review of Gas Measurement Practices and Sensors for Tunnels

Departamento de Ingeniería Civil: Construcción, E.T.S de Ingenieros de Caminos, Canales y Puertos, Universidad Politécnica de Madrid, 28040 Madrid, Spain
*
Author to whom correspondence should be addressed.
Sensors 2023, 23(3), 1090; https://doi.org/10.3390/s23031090
Submission received: 11 November 2022 / Revised: 23 December 2022 / Accepted: 15 January 2023 / Published: 17 January 2023
(This article belongs to the Special Issue Sensors and Smart Devices for Structure Health Monitoring)

Abstract

:
The concentration of pollutant gases emitted by traffic in a tunnel affects the indoor air quality and contributes to structural deterioration. Demand control ventilation systems incur high operating costs, so reliable measurement of the gas concentration is essential. Numerous commercial sensor types are available with proven experience, such as optical and first-generation electrochemical sensors, or novel materials in detection methods. However, all of them are subjected to measurement deviations due to environmental conditions. This paper presents the main types of sensors and their application in tunnels. Solutions will also be discussed in order to obtain reliable measurements and improve the efficiency of the extraction systems.

1. Introduction

The growing concern about indoor air quality [1,2,3], the emission of gases in industrial processes and transport [4,5,6], as well as the stringency of new regulations have led to further research focused on the development of effective sensors in gas measurement. Tunnel-type infrastructures have always been affected by gas concentration levels, so monitoring these levels has important applications in their operation and maintenance (O&M). Road tunnels support high levels of combustion gases, such as carbon oxides (COx), nitrogen (NOx), and particulate matter (PM), or organic compound species, such as volatile organic compound (VOC), or hydrocarbons (HCs), such as BTEX (benzene, toluene, ethylbenzene and xylene) [7,8,9,10,11,12,13,14,15,16,17,18]. Keeping adequate concentration levels of these gases is essential for their facility management (FM). High levels of pollutants affect health, so they should be kept at low values, it being advisable to keep them in the region of 400 ppm of CO2 in the domestic sphere, although these levels may be higher in the case of industrial facilities, as regulated by Spanish legislation [19]. The presence of these pollutants also affects the structure, accelerating degradation mechanisms, such as the carbonation of the concrete [16].
Monitoring the air quality inside the tunnel in real time is essential in order to be able to activate the ventilation system. The volume of air extracted by this fan system must be one which maintains tolerable levels of gases without incurring high operating costs, which are mainly due to the amount of energy used during its functioning. However, studies quantifying these costs are scarce. Some researchers have even reported that up to 75% of operating costs come from ventilation [20,21,22]. In addition, the continued use of exhaust fans leads to the accelerated wear and tear of their moving parts, resulting in a shortened service life and, consequently, further costs associated with their replacement [23]. In order to mitigate these high costs, some researchers propose the use of natural ventilation in long tunnels, which can lead to savings of up to 40% in smoke extraction costs [20,21,24].
Air quality monitoring can be performed from different approaches, depending on the chosen gas and sample measurement method. Within the gas mixture inside the tunnel, PM, CO, CO2, NO2, or BTEX have traditionally been measured [15,16,17], although other components of the gas mixture, such as oxygen (O2) [25] or VOC, can also be monitored [18,26]. Numerous types of sensors for gas detection are available on the market. They can be mainly classified as either optical sensors or electrochemical sensors based on measuring method [27,28,29]. Each of them has advantages and limitations, such as working temperature, its useful life, or response time. External factors, such as temperature, humidity, or the presence of other gases in urban atmospheric environments produce deviations in the measurement that are aggravated over time, regardless of the type of sensor [30,31,32]. Therefore, the regular recalibration of measurement systems is necessary to obtain reliable measurements.
Concern about indoor air quality has increased in recent years, leading to the proliferation of low-cost sensors for measuring indoor CO2 concentration levels [33]. Research and advances in this type of sensor, linked together and periodically recalibrated, can be extrapolated to the control of gas levels in tunnels, leading to a significant leap in the reduction in ventilation operating costs.
The following sections compare the main sensors used based on the published literature, focusing on their application for measuring gases in tunnels, as well as the issues in this type of infrastructure. Additionally, some new research with new materials and their possible applications in the sensorization of this type of structure will be presented.

2. Types of Sensors

Various approaches are currently known for gas detection, such as sensor type optical, semiconductor, catalytic, thermometric, photoacoustic, chemiluminescent, gas chromatographic and others [27,34]. Among detection methods, electrochemical sensors and optical non-dispersive infrared (NDIR) detectors are widely used in measurement technology [35]. This article focuses on the analysis of these two detection methods in sensors.
Furthermore, among the measurement parameters, there are several concepts to consider, such as sensitivity, selectivity, working temperature range, stability of the measurement under working conditions or lifetime. Sensitivity is related to the detection limit, which is a measure of the smallest concentration that can be determined with a specified accuracy or reproducibility. Selectivity refers to the ability of the sensor to determine the concentration of a specific gas in the presence of other gases. These concepts will be key to determining the capabilities of each detection method and their potential application in real-time monitoring of gas concentration inside a road tunnel.

2.1. NDIR Sensors

NDIR gas measurement falls into the category of optical sensors. This is an application of infrared spectroscopy. The NDIR technique for gas measurement aims at absorbing wavelengths in the infrared spectrum as a way to identify particular gases [36]. A simple NDIR gas sensor consists of an infrared emitter, a detector, an optical filter, a gas cell and circuit elements for signal processing [37,38]. The operation of this type of sensor is shown in Figure 1.
This type of sensor is the most widely used nowadays, with a large variety of simple devices on the market. The main advantage of NDIR sensors is their longer lifetime, which is more than 10 years, compared to other detection methods. However, they suffer from several problems, such as selectivity due to interference from nearby gases, sensitivity due to small signal output from weak gas absorption and the elevated cost owing to highly sophisticated optical components [39,40,41,42,43]. This sensitivity is determined by the detection limit, which depends on both the signal strength (or sensitivity) and the signal stability (signal-to-noise ratio). As such, they tend to have high power consumption, which makes them difficult to use in battery-powered devices for in situ monitoring applications. In addition, spectroscopic methods are voluminous and require a long response time for high concentrations [44].
The interference problem is between gas adsorption bands, such as the spectral signature of NO2 with water vapor shown in Figure 2. This can be mitigated with new optics techniques, although it has not yet been fully resolved. In addition, the presence of water vapor could affect other sensor electronics or cause artefacts to form for the target gases, distorting the measurement [36,43,45]. The water vapor problem can be avoided by operating the gas cell of the NDIR sensor at high temperatures, but this usually results in the generation of other artefacts, causing a measurement error.
More recent studies have shown the advantages of this type of sensor under ambient conditions. In addition, there has been an increasing need to measure indoor air quality, proliferating and making this type of sensor cheaper and extending its use to the domestic environment, where concentrations should not exceed 1000 ppm and the ambient temperature is around 20 °C and relative humidity is 50% [33,42,47]. They have also been used to measure atmospheric air quality by studying the influence of pressure, temperature and humidity on CO2 measurement [48,49].

2.2. Electrochemical Sensors

Within electrochemical sensors there are a multitude of device methods with different materials. They usually consist of at least two electrodes; one sensing or working and one reference electrode. These electrodes are connected through a thin layer of electrolyte [27]. Viable alternatives, such as sensors based on solid oxide electrolytes have been appearing recently. Such sensors are considered the most reliable way to detect COx in industrial applications. These sensors operate at temperatures of 450 °C and above to ensure sufficient ionic conductivity in a solid oxide electrolyte [29,50].
There are also electrochemical gas sensors in solution. These are characterized by high complexity, high sensitivity and stability of the sensor and work at room temperature [25,51,52,53,54,55]. Sensors can be found in aqueous solution, although other types of solutions are usually experimented with to improve the properties of the sensor and to reduce the dependence of the sensor on the pH of the solution. These types of sensors are often used in very specific engineering or medical applications, such as wastewater treatment [55] or clinical blood gas analysis, respectively [52].
Additionally, there are sensors based on metal oxide semiconductors (MOS). The detection principle of semiconductor-type sensors is based on the change of the electrical resistance of the MOS, depending on the composition of the gaseous atmosphere [56,57]. The schematic of this type of sensor is shown in Figure 3.
This type of sensor has good sensitivity, a fast response time and stable performance and is the most cost-effective [58,59,60,61]. However, the sensor signal can be affected by the adsorption of different components of the gaseous atmosphere on the semiconductor surface, such as other gases with atmospheres or humidity, which affects the selectivity [28,50,62]. In addition, such sensors typically have optimum operating temperatures of several hundred degrees Celsius [29,41,63,64].
Another material for chemical gas detection is polymer-based sensors [44]. This type of sensor has a short response time and an operating range at ambient temperature [65]. However, they have poor selectivity, as well as short- and long-term sensor deviation, which lead to inaccurate measurements over time [66,67].
Recently, new sensing materials, such as carbon nanotubes or graphene, have appeared [25,68,69,70,71,72]. Even though a lot of research has been carried out on these sensors, there are still some limitations which need to be addressed and rectified to improve the efficiency in the utilization of these sensors on a commercial basis [72].
Metal–organic frameworks (MOFs) have arisen as a promising option in the gas sensor industry. Such sensors are fabricated by assembling metal nodes with organic linkers [73,74,75,76,77,78]. MOFs sensors have different working principles, such us refractive index sensing [78,79,80], chemical resistance [81,82], mass sensitive mode [77,83], electrochemical impedance spectroscopy [67,84], responsive fluorescence [74,75,85] or variations in the luminescence properties [86]. Their high surface-area-to-volume ratio is especially beneficial for sensing applications, as it increases the possibility of interaction between sensing materials, leading to high sensitivity, as well as having high thermal and chemical stability [67,74,75,85]. Sensors require two main components: a sensing layer and a transducer, as shown in Figure 4. The sensing layer interacts selectively with the target analytes, so that various changes in the physicochemical properties of the system (e.g., capacitance, mass, conductivity, optical properties, etc.) are detected, and the transducer translates the changes into measurable signals.
MOF-type sensors have a promising future for selective gas detection due to their sensitivity, wide operating temperature range and structural and chemical adaptability [66,87]. However, although there is increasing research and diversity in these types of compounds and transducers, most investigation is focused on developing laboratory prototypes for CO2 detection, leaving aside the rest of the gases. Another problem that has arisen is the tendency of some of these materials to hydrolyse in humid conditions. Some authors have solved this problem by using materials that are stable in water, at the cost of losing sensitivity in favour of longer durability at room temperature [88].

2.3. Comparison between Sensors

All current technologies for gas detection, and especially CO2, have their own set of advantages and limitations that make them relevant for specific detection applications. Table 1 gives a published comparison of the main characteristics of the most used sensor types.
This comparison excludes the most recent developments. For example, in the case of optical sensors, numerous NDIR sensors have been developed and commercialized at lower costs, making them widely used in many domestic and industrial applications [9,48,90]. Response times for electrochemical and infrared absorption sensors are also described as poor, but recent studies report response times of less than 1 min for concentrations below 2000 ppm [27,42,43,45]. Although the selectivity of this type of sensor is rated as “excellent” in the comparative table, several authors identify difficulties in the selectivity of this type of sensor [39]. Furthermore, this comparison fails to cover some relevant aspects, such as the working temperature (very high in electrochemical sensors), or the influence of environmental factors, such as temperature and humidity.
Furthermore, there are nowadays a multitude of devices on the market for each measuring method. This results in a wide variety of sensors whose parameters, in terms of sensitivity, selectivity, response time or cost, cover the specific needs for each case. In addition, advances in data processing can predict trends in air quality. This can lead to more reliable measurements with lower capacities of sensors.

2.4. Sensor Calibration

Gas monitoring is becoming increasingly relevant in urban environments. It is used to measure air quality, both for air pollution in cities and indoor gas concentrations. CO2 sensors are often used to keep ventilation controlled on demand. However, the environment in which the measurement is taken is susceptible to changes in ambient conditions that result in erroneous measurements, regardless of the type of sensor. Gas concentration in a space depends on the concentration of the in-flowing air, the concentration of the out-flowing air and the internal generation rate of the gas in the space minus the degradation of the gas, as shown in Figure 5 [32].
Proper demand-controlled ventilation requires accurate CO2 measurements. However, some research has reported substantial measurement errors. In the case of infrared sensors, no association between sensor age and measurement accuracy can be established, as shown in Figure 6, and neither can these inaccuracies be attributed to errors in the translation of the sensor output signal. This research at malls in the USA determined that, in most cases, no calibration was performed during the lifetime of the sensor after the initial factory calibration.
External factors, such as temperature, humidity or the presence of other gases in urban atmospheric environments produce deviations that are aggravated over time and affect each type of sensor differently [30,31]. For example, for MOS-type sensors, the electrical conductivity of the sensor is reduced by NO2 gas in traffic situations [92]. Most authors seek to calibrate their sensor networks using recalibration algorithms. These can be based on comparisons with artificial gases measured in the laboratory or on reliable real measurements taken at fixed and controlled stations [17,93,94].
The most recent studies are in favour of large networks of low-cost NDIR sensors. To achieve the desired stability of measurements, the instruments must be corrected at regular intervals with data from a reference instrument or control parameters to which such sensors are cross-sensitive (gas mixture, atmospheric pressure, temperature, or relative humidity). In addition, sensor-specific corrections are required and must be considered dependent on time, e.g., by including a linear offset that only becomes more evident for long-term observations [48].
According to the published results, the practical error of these sensors was reduced by <5ppm, or approximately 1% of the observed value for response times of 60 s, by means of individual and periodic recalibration for each of the sensors in the network, using algorithms that consider these parameters. For average response times of 200 s, measurement noise is reduced by up to 30% [90].

3. Gas Measurement in Tunnels

The control of gas concentration in tunnels is a matter of concern for all administrations involved in tunnel management. Real-time monitoring of the air quality inside the tunnel is essential in order to be able to regulate the operation of the ventilation system [21,22,23,26]. The volume of air extracted by this ventilation system must be one that maintains tolerable levels of gases without incurring high operating costs, which are mainly due to the amount of energy used during its operation. In addition, the continued use of exhaust fans leads to accelerated wear and tear of their moving parts, resulting in a shortened service life and, consequently, further costs associated with their replacement [23]. In order to lessen these costs, some researchers have researched the use of natural ventilation in long tunnels, which can lead to savings of up to 40% in smoke extraction costs [20,21,24]. According to some research, smoke extraction costs have been quantified as up to 75% of energy costs [20,21,22].
The measurement of this concentration is therefore a long-standing line of research. Table 2 shows a compilation of specific infrastructures in which research projects aimed at measuring gas concentration have been carried out.
The studies in Table 2 have been carried out in tunnels around the world. Almost all of these studies have been carried out using NDIR sensors, although not all of them specify the type of sensor or have been able to verify the commercial sensor model used. Similarly, in each of them, the target gas is different, with NOx, COx and particulate matter being the most common gases measured, as these are the gases with the greatest presence in transport pollution.
A recent review of this research has been carried out by Marinello et al. [15], with more than 100 studies on tunnels of various types, tunnel sections and tunnel ventilation systems around the world. Figure 7 shows the distribution of the reviewed studies, demonstrating that these studies are generally carried out in countries with air quality regulations. Most of these articles relate to tunnels of about 2000 m in length, with four traffic lanes, with an average speed of 66 km/h and a location in urban environments. These tunnels are often associated with high traffic intensities and the accumulation of pollutants. In addition, the methods of dilution and pollutant gas extraction are critical for the FM of the tunnel and for the air quality in its surroundings.
Almost all the structures studied in this article are equipped with systems of forced ventilation. The concentration level of specific pollutants is one of the main factors determining the activation of these systems, which were switched off during data collection and air pollutant analysis. Sampling campaigns varied in duration from a few hours to a few days, or even longer periods in the cases where there were seasonal effects on gas concentration levels. The measurement campaigns were generally carried out by placing the instrumentation in the tunnel portals or in the middle of the tunnel.
The types of pollutants analysed are very different and characteristic of each study. The most analysed pollutants are PM, CO, NO2 or CO2. However, the concentration values detected by different authors show considerable differences for all pollutants. Some average values reported are 237 µg/m3 for PM10, 107 µg/m3 for PM2.5 or 551 µg/m3 for NO2. On the other hand, CO is the reference gas often used for the activation of automatic ventilation systems that are switched on when pollutant levels exceed specific critical limits. The average CO concentration is 17.4 mg/m3.
Almost half of the studies also provide meteorological data, which were closely associated with their territory. Temperatures ranged from −4 °C to 36 °C and relative humidity varied from 40% to 88%. However, these data in each individual tunnel remained virtually constant. The average temperature was 26.5 °C, and humidity was between 63.0% and 88.3% inside the tunnel for mild urban environments [14,17,26].
On the other hand, this study only classifies the concentration measurement methods as passive, semi-active or active, according to whether or not the air is forced through a filter, and their analysis is carried out in the laboratory. Regarding the type of sensors used in some of the more recent studies, there is some research using electrochemical sensors to measure PM and polycyclic aromatic hydrocarbon (PAH) compounds [14], but infrared optical sensors are frequently used [7,8,9,10,11,12,13].

Gas Measurement for Ventilation Indoors

In recent years, there has been a boom in the development of low-cost and portable sensors for the measurement of indoor CO2 concentration levels [2,47,124]. This has been the parameter used to determine the need for space ventilation [33]. NDIR sensors have generally occupied this market space and have even been used for more specific medical applications [125,126].
These low-cost sensors have many limitations in terms of sensitivity and stability. However, their use has become widespread and the number of studies on their use has proliferated [30]. Numerous recommendations have followed, mainly the development of regular maintenance and recalibration plans [127,128], as well as concentration prediction models [129,130,131,132,133].

4. Discussion and Future Developments

The measurement of combustion gases inside a road tunnel is a key factor in its proper FM. The volume of traffic or the concentration of several gases, such as CO or CO2, have been used to trigger the forced ventilation systems. A measurement of the concentration of these gases is essential to assess the operating level of the fans, whose operating costs due to energy consumption are a major item in the O&M of the infrastructure budgets [15,20,21,22].
There are a multitude of sensor types on the market, according to their approach to gas detection [27]. Electrochemical sensors based on solid oxide electrolytes are considered to have the most reliable method of detecting COx in industrial applications; however, they require very high operating temperatures of around 450 °C [29,50]. Therefore, such sensors can be discarded when measuring air quality inside a tunnel, where the average temperature is 26 °C. Having several such devices along the length of a road tunnel would increase costs and operational complexity. There are also electrochemical gas sensors in solution that are often used in specific engineering or medical applications [52,55]. Such sensors are characterized by their technical complexity, and their arrangement of a group of sensors along a tunnel would increase the operational constraints of the system.
MOS-type sensors are a breakthrough in electrochemical sensors, with high sensitivity, a fast response time and stable performance [58]. Nevertheless, their selectivity is reduced in environments with high concentrations of other gases or humidity [28,50,62], often requiring a high operating temperature range. Lastly, MOFs sensors have different operating principles allowing a wide variety of devices that are adjusted according to the needs of each specific case, so these types of sensors has a promising future due to their sensitivity, wide operating temperature range and structural and chemical adaptability [66,73,77,81]. However, such sensors are still under development and would not be reliable in practical application.
The other main group are optical sensors, NDIR sensors being the most widely used in both domestic and industrial applications [39]. They have good sensitivity, operate at ambient temperature and have a long lifetime; however, they have a worse response time and lower sensitivity and selectivity compared to electrochemical sensors. Their use has become more extensive and cheaper with the development of low-cost sensors for domestic use [33,42,47], although their implementation is influenced by the presence of other gases or humidity [36,43,45]. Both selectivity and sensitivity can be improved by optics, but this means increasing the size of the device, increasing its cost, response time and power consumption [44]. However, the growing concern about indoor air quality has caused the proliferation of this type of device, increasing the variety of NDIR sensors in the market and lowering its costs [33].
Table 3 classifies the references cited in this article. If we look at the type of sensor, the most recent studies on practical applications are strongly influenced by the increase in demand for sensors for monitoring CO2 concentration in domestic indoor environments, such as tunnels or underground parking. In the case of infrastructures, it is notable that among the articles reviewed, almost all of those that specify the type of sensor or model used are of the NDIR type. This is also the case for monitoring the concentration of gases in the environment. This could be since in all three cases rapid measurements are required, at ambient temperature and low-cost and portable sensors. Moreover, in these cases a certain measurement error can be assumed, i.e., lower sensitivity and selectivity can generally be assumed. On the other hand, when very reliable measurements are needed in industrial processes, research tends to focus on electrochemical-type sensors, where the reactive components of the sensor can be determined to suit each singular process within the wide variety of materials available. In addition, under the electrochemical sensor type, a wide variety of sensing forms are grouped together, which accounts for the largest number of review articles analysed.
Reliable measurements are necessary for demand-controlled ventilation, but the environment in which the measurement is carried out is susceptible to changes in ambient conditions that lead to errors in the measurement, regardless of the type of sensor [32]. Although the humidity and temperature conditions inside the tunnel are kept almost constant [14,17,45,94], changes are produced during the course of both the day and the year by outdoor environmental conditions. These oscillations cause a drift in gas measurements that is only evident in long-term observations [48]. In the case of infrared sensors, an association between sensor age and measurement accuracy cannot be correlated, nor can inaccuracies in measurement be attributed to errors in the translation of the sensor’s output signal, but rather to a measurement bias of the sensor itself [91] or environmental conditions [32].
Therefore, a recalibration of the sensors is essential during their lifetime, regardless of the detection method. However, most demand-controlled ventilation infrastructures only carry out an initial calibration after installation and testing of the sensor [91]. The combination of all these factors produces inaccurate measurements, which may not be perceptible at the time. This eventually results in cost overruns during operation due to excessive fan use or deficits in the air quality inside the tunnel [23].
New research is focusing on extensive networks of low-cost NDIR sensors. The sensors are corrected at regular intervals with data from a reference instrument, and the parameters that are cross-sensitive for this type of sensor are jointly monitored. Each sensor is individually recalibrated, and the practical error is reduced to 1% of the observed value for a response time of 60 s [48,90].
Furthermore, there has been a proliferation of low-cost NDIR-type sensors to measure CO2 concentration levels in domestic environments over the last few years [33]. These environments are maintained at room temperature and at a relative humidity of around 50% [33,42,47]. These atmospheric parameters are similar to those found in urban road tunnels [14,17,26]. Therefore, research and advances in these types of sensors, interconnected and periodically recalibrated, can be extrapolated to the control of gas levels in tunnels where concentrations should not exceed 1000 ppm. In addition, advances in data processing have allowed the development of prediction models [128,129,130,131,132,133], able to anticipate the operating needs of the ventilation system and reduce the operating time. This represents a significant leap in reducing the operating costs of ventilation [23], and it can make a better adjustment in the activation of extraction systems using a network of sensors with lower capacity but with lower operational complexity and greater robustness to the environment to which they are exposed, i.e., the quality of the measure is improved. However, research has shown that maintenance and recalibration plans are needed for the use of such sensors [127,128].
A network of sensors connected to each other [22,134] and to the control centre provides the system with information, not only on the gas concentration measurement, but also on traffic data and environmental conditions (temperature, relative humidity and the presence of other gases). The smart processing of this data allows recalibration and demand prediction algorithms to be generated, thus optimizing the available resources, and reducing the operating costs of the tunnel ventilation system, thereby increasing the quality of the air inside the infrastructure.

5. Conclusions

Tunnel gas concentration monitoring is essential to preserve air quality without incurring high operating costs from the ventilation system. The following conclusions are drawn from this study:
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A mixture of pollutant gases emitted by traffic accumulates inside tunnels, leading to a deterioration of indoor and outdoor air quality, with harmful consequences for health and the structural integrity.
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Real-time monitoring with accurate measurements requires an efficient sensor system to provide continuous data readings to control the use of the ventilation system, without raising operational costs.
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Environmental conditions, mainly temperature, relative humidity and gas mix, influence the reading of the sensors, causing measurement deviations regardless of the detection method. Periodic recalibration of the sensors becomes essential to maintain error-free monitoring.
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MOS-type sensors have high sensitivity, but their lifetime and high operating temperature lead to high operating costs. New electrochemical sensors can cover the main needs, but they are still under development and would not be effective for a real application.
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Optic sensors are the most widely available on the market, with a broad range of value for money in relation to the operational needs, with a useful life of above 10 years. Many types of NDIR sensors have been developed with the proliferation of applications for domestic use, reducing the cost of this type of sensor.
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A network of low-cost NDIR sensors which are linked together take all other ambient and traffic factors into consideration. Periodic recalibration and processing of (the) data will allow for an efficient ventilation system, optimising the available resources in the tunnel management.

Author Contributions

Conceptualization, M.G.A.; Data curation, J.J.C.; Formal analysis, J.J.C., R.M.P., M.G.A. and P.C.; Investigation, J.J.C., R.M.P. and P.C.; Methodology, J.J.C., R.M.P., M.G.A. and P.C.; Resources, M.G.A.; Software, J.J.C., R.M.P., M.G.A. and P.C.; Supervision, M.G.A.; Validation, M.G.A. and J.J.C.; Visualization, R.M.P. and M.G.A.; Writing—original draft, J.J.C., R.M.P., M.G.A. and P.C.; Writing—review and editing, J.J.C. and M.G.A. All authors have read and agreed to the published version of the manuscript.

Funding

This research was funded by the Enterprise University Chair Calle30-UPM.

Institutional Review Board Statement

Not applicable.

Informed Consent Statement

Not applicable.

Data Availability Statement

The data presented in this study are available on request from the corresponding author.

Acknowledgments

The authors gratefully acknowledge the financial support provided by the Ministry of Economy, Industry and Competitiveness of Spain by means of the Research Fund Project PID2019-108978RB-C31.

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Wolkoff, P. Indoor air humidity, air quality, and health—An overview. Int. J. Hyg. Environ. Health 2018, 221, 376–390. [Google Scholar] [CrossRef] [PubMed]
  2. Pavón, R.; Alvarez, A.; Alberti, M. Possibilities of BIM-FM for the Management of COVID in Public Buildings. Sustainability 2020, 12, 9974. [Google Scholar] [CrossRef]
  3. Rodríguez-Urrego, D.; Rodríguez-Urrego, L. Air quality during the COVID-19: PM2.5 analysis in the 50 most polluted capital cities in the world. Environ. Pollut. 2020, 266, 115042. [Google Scholar] [CrossRef] [PubMed]
  4. Agarwal, A.K.; Mustafi, N.N. Real-world automotive emissions: Monitoring methodologies, and control measures. Renew. Sustain. Energy Rev. 2020, 137, 110624. [Google Scholar] [CrossRef]
  5. Warneke, C.; McKeen, S.A.; de Gouw, J.; Goldan, P.D.; Kuster, W.C.; Holloway, J.S.; Williams, E.J.; Lerner, B.; Parrish, D.D.; Trainer, M.; et al. Determination of urban volatile organic compound emission ratios and comparison with an emissions database. J. Geophys. Res. Atmos. 2007, 112, 10–47. [Google Scholar] [CrossRef]
  6. Yang, Y.; Ji, D.; Sun, J.; Wang, Y.; Yao, D.; Zhao, S.; Yu, X.; Zeng, L.; Zhang, R.; Zhang, H.; et al. Ambient volatile organic compounds in a suburban site between Beijing and Tianjin: Concentration levels, source apportionment and health risk assessment. Sci. Total Environ. 2019, 695, 133889. [Google Scholar] [CrossRef]
  7. Blanco-Alegre, C.; Calvo, A.; Alves, C.; Fialho, P.; Nunes, T.; Gomes, J.; Castro, A.; Oduber, F.; Coz, E.; Fraile, R. Aethalometer measurements in a road tunnel: A step forward in the characterization of black carbon emissions from traffic. Sci. Total Environ. 2019, 703, 135483. [Google Scholar] [CrossRef]
  8. Li, X.; Dallmann, T.R.; May, A.; Stanier, C.O.; Grieshop, A.P.; Lipsky, E.M.; Robinson, A.; Presto, A.A. Size distribution of vehicle emitted primary particles measured in a traffic tunnel. Atmos. Environ. 2018, 191, 9–18. [Google Scholar] [CrossRef]
  9. Luo, Y.; Chen, J.; Liu, W.; Ji, Z.; Ji, X.; Shi, Z.; Yuan, J.; Li, Y. Pollutant concentration measurement and emission factor analysis of highway tunnel with mainly HGVs in mountainous area. Tunn. Undergr. Space Technol. 2020, 106, 103591. [Google Scholar] [CrossRef]
  10. Li, X.; Dallmann, T.R.; May, A.A.; Presto, A.A. Seasonal and Long-Term Trend of on-Road Gasoline and Diesel Vehicle Emission Factors Measured in Traffic Tunnels. Appl. Sci. 2020, 10, 2458. [Google Scholar] [CrossRef]
  11. Pierson, W.R.; Gertler, A.W.; Robinson, N.F.; Sagebiel, J.C.; Zielinska, B.; Bishop, G.; Stedman, D.H.; Zweidinger, R.B.; Ray, W.D. Real-world automotive emissions—Summary of studies in the Fort McHenry and Tuscarora mountain tunnels. Atmos. Environ. 1996, 30, 2233–2256. [Google Scholar] [CrossRef]
  12. Mancilla, Y.; Araizaga, A.E.; Mendoza, A. A tunnel study to estimate emission factors from mobile sources in Monterrey, Mexico. J. Air Waste Manag. Assoc. 2012, 62, 1431–1442. [Google Scholar] [CrossRef] [Green Version]
  13. Pio, C.; Mirante, F.; Oliveira, C.; Matos, M.; Caseiro, A.; Oliveira, C.; Querol, X.; Alves, C.; Martins, N.; Cerqueira, M.; et al. Size-segregated chemical composition of aerosol emissions in an urban road tunnel in Portugal. Atmos. Environ. 2013, 71, 15–25. [Google Scholar] [CrossRef]
  14. Fang, X.; Wu, L.; Zhang, Q.; Zhang, J.; Wang, A.; Zhang, Y.; Zhao, J.; Mao, H. Characteristics, emissions and source identifications of particle polycyclic aromatic hydrocarbons from traffic emissions using tunnel measurement. Transp. Res. Part D Transp. Environ. 2018, 67, 674–684. [Google Scholar] [CrossRef]
  15. Marinello, S.; Lolli, F.; Gamberini, R. Roadway tunnels: A critical review of air pollutant concentrations and vehicular emissions. Transp. Res. Part D Transp. Environ. 2020, 86, 102478. [Google Scholar] [CrossRef]
  16. Abajo, L.L.-D.; Gálvez, J.C.; Alberti, M.G. Simulación del proceso de carbonatación del hormigón en túneles urbanos. In Proceedings of the XVIII Congreso de Control de Calidad en la Construcción, Brasilia, Brazil, 19–21 October 2021. [Google Scholar] [CrossRef]
  17. Liu, B.; Zimmerman, N. Fleet-Based Vehicle Emission Factors Using Low-Cost Sensors: Case Study in Parking Garages. In Transportation Research Part D: Transport and Environment; Elsevier: Amsterdam, The Netherlands, 2021; Volume 91, Available online: https://www.sciencedirect.com/science/article/pii/S1361920920308208 (accessed on 4 November 2022).
  18. Jin, B.; Zhu, R.; Mei, H.; Wang, M.; Zu, L.; Yu, S.; Zhang, R.; Li, S.; Bao, X. Volatile organic compounds from a mixed fleet with numerous E10-fuelled vehicles in a tunnel study in China: Emission characteristics, ozone formation and secondary organic aerosol formation. Environ. Res. 2021, 200, 111463. [Google Scholar] [CrossRef]
  19. MITECO, TEC/1146/2018 Madrid: Instrucción Técnica Complementaria 04.7.06. Control de Gases Tóxicos en la Atmósfera de las Actividades Subterráneas. 2018. Available online: https://www.boe.es/diario_boe/txt.php?id=BOE-A-2018-14894 (accessed on 22 July 2022).
  20. Zhang, Z.; Zhang, H.; Tan, Y.; Yang, H. Natural wind utilization in the vertical shaft of a super-long highway tunnel and its energy saving effect. Build. Environ. 2018, 145, 140–152. [Google Scholar] [CrossRef]
  21. Guo, C.; Wang, M.; Yang, L.; Sun, Z.; Zhang, Y.; Xu, J. A review of energy consumption and saving in extra-long tunnel operation ventilation in China. Renew. Sustain. Energy Rev. 2016, 53, 1558–1569. [Google Scholar] [CrossRef]
  22. Liu, R.; He, Y.; Zhao, Y.; Jiang, X.; Ren, S. Tunnel construction ventilation frequency-control based on radial basis function neural network. Autom. Constr. 2020, 118, 103293. [Google Scholar] [CrossRef]
  23. Al-Chalabi, H.S. Life cycle cost analysis of the ventilation system in Stockholm’s road tunnels. J. Qual. Maint. Eng. 2018, 24, 358–375. [Google Scholar] [CrossRef] [Green Version]
  24. Guo, C.; Xu, J.; Yang, L.; Guo, X.; Zhang, Y.; Wang, M. Energy-Saving Network Ventilation Technology of Extra-Long Tunnel in Climate Separation Zone. Appl. Sci. 2017, 7, 454. [Google Scholar] [CrossRef] [Green Version]
  25. Sohi, P.A.; Kahrizi, M. Low-Voltage Gas Field Ionization Tunneling Sensor Using Silicon Nanostructures. IEEE Sens. J. 2018, 18, 6092–6096. [Google Scholar] [CrossRef]
  26. Song, C.; Liu, Y.; Sun, L.; Zhang, Q.; Mao, H. Emissions of volatile organic compounds (VOCs) from gasoline- and liquified natural gas (LNG)-fueled vehicles in tunnel studies. Atmos. Environ. 2020, 234, 117626. [Google Scholar] [CrossRef]
  27. Gautam, Y.K.; Sharma, K.; Tyagi, S.; Ambedkar, A.K.; Chaudhary, M.; Singh, B.P. Nanostructured metal oxide semiconductor-based sensors for greenhouse gas detection: Progress and challenges. R. Soc. Open Sci. 2021, 8, 201324. [Google Scholar] [CrossRef]
  28. Kalyakin, A.; Volkov, A.; Dunyushkina, L. Solid-Electrolyte Amperometric Sensor for Simultaneous Measurement of CO and CO2 in Nitrogen. Appl. Sci. 2022, 12, 4515. [Google Scholar] [CrossRef]
  29. Mulmi, S.; Thangadurai, V. Editors’ Choice—Review—Solid-State Electrochemical Carbon Dioxide Sensors: Fundamentals, Materials and Applications. J. Electrochem. Soc. 2020, 167, 037567. [Google Scholar] [CrossRef]
  30. Müller, M.; Graf, P.; Meyer, J.; Pentina, A.; Brunner, D.; Perez-Cruz, F.; Hüglin, C.; Emmenegger, L. Integration and calibration of non-dispersive infrared (NDIR) CO2 low-cost sensors and their operation in a sensor network covering Switzerland. Atmos. Meas. Tech. 2020, 13, 3815–3834. [Google Scholar] [CrossRef]
  31. Carotenuto, F.; Gualtieri, G.; Miglietta, F.; Riccio, A.; Toscano, P.; Wohlfahrt, G.; Gioli, B. Industrial point source CO2 emission strength estimation with aircraft measurements and dispersion modelling. Environ. Monit. Assess. 2018, 190, 1–15. [Google Scholar] [CrossRef] [Green Version]
  32. You, Y.; Niu, C.; Zhou, J.; Liu, Y.; Bai, Z.; Zhang, J.; He, F.; Zhang, N. Measurement of air exchange rates in different indoor environments using continuous CO2 sensors. J. Environ. Sci. 2012, 24, 657–664. [Google Scholar] [CrossRef]
  33. Borodinecs, A.; Palcikovskis, A.; Jacnevs, V. Indoor Air CO2 Sensors and Possible Uncertainties of Measurements: A Review and an Example of Practical Measurements. Energies 2022, 15, 6961. [Google Scholar] [CrossRef]
  34. Operating Principle—MOS-Type Gas Sensor. Available online: https://www.figaro.co.jp/en/technicalinfo/principle/mos-type.html (accessed on 4 November 2022).
  35. Zosel, J.; Oelßner, W.; Decker, M.; Gerlach, G.; Guth, U. The measurement of dissolved and gaseous carbon dioxide concentration. Meas. Sci. Technol. 2011, 22, 072001. [Google Scholar] [CrossRef]
  36. Dinh, T.-V.; Choi, I.-Y.; Son, Y.-S.; Kim, J.-C. A review on non-dispersive infrared gas sensors: Improvement of sensor detection limit and interference correction. Sens. Actuators B Chem. 2016, 231, 529–538. [Google Scholar] [CrossRef]
  37. Tan, X.; Zhang, H.; Li, J.; Wan, H.; Guo, Q.; Zhu, H.; Liu, H.; Yi, F. Non-dispersive infrared multi-gas sensing via nanoantenna integrated narrowband detectors. Nat. Commun. 2020, 11, 5245. [Google Scholar] [CrossRef]
  38. Ng, D.K.T.; Ho, C.P.; Xu, L.; Chen, W.; Fu, Y.H.; Zhang, T.; Siow, L.Y.; Jaafar, N.; Ng, E.J.; Gao, Y.; et al. NDIR CO2 gas sensing using CMOS compatible MEMS ScAlN-based pyroelectric detector. Sens. Actuators B Chem. 2021, 346, 130437. [Google Scholar] [CrossRef]
  39. Jha, R.K. Non-Dispersive Infrared Gas Sensing Technology: A Review. IEEE Sens. J. 2021, 22, 6–15. [Google Scholar] [CrossRef]
  40. Ye, W.; Tu, Z.; Xiao, X.; Simeone, A.; Yan, J.; Wu, T.; Wu, F.; Zheng, C.; Tittel, F.K. A NDIR Mid-Infrared Methane Sensor with a Compact Pentahedron Gas-Cell. Sensors 2020, 20, 5461. [Google Scholar] [CrossRef]
  41. Hsu, K.-C.; Fang, T.-H.; Hsiao, Y.-J.; Chan, C.-A. Highly response CO2 gas sensor based on Au-La2O3 doped SnO2 nanofibers. Mater. Lett. 2020, 261, 127144. [Google Scholar] [CrossRef]
  42. Akram, M.M.; Nikfarjam, A.; Hajghassem, H.; Ramezannezhad, M.; Iraj, M. Low cost and miniaturized NDIR system for CO2 detection applications. Sens. Rev. 2020, 40, 637–646. [Google Scholar] [CrossRef]
  43. Vafaei, M.; Amini, A.; Siadatan, A. Breakthrough in CO2 Measurement With a Chamberless NDIR Optical Gas Sensor. IEEE Trans. Instrum. Meas. 2019, 69, 2258–2268. [Google Scholar] [CrossRef]
  44. Willa, C.; Schmid, A.; Briand, D.; Yuan, J.; Koziej, D. Lightweight, Room-Temperature CO2 Gas Sensor Based on Rare-Earth Metal-Free Composites—An Impedance Study. ACS Appl Mater Interfaces 2017, 9, 25553–25558. [Google Scholar] [CrossRef] [Green Version]
  45. Jia, X.; Roels, J.; Baets, R.; Roelkens, G. A Miniaturised, Fully Integrated NDIR CO2 Sensor On-Chip. Sensors 2021, 21, 5347. [Google Scholar] [CrossRef] [PubMed]
  46. Popa, D.; Udrea, F. Towards Integrated Mid-Infrared Gas Sensors. Sensors 2019, 19, 2076. [Google Scholar] [CrossRef] [PubMed] [Green Version]
  47. Zemitis, J.; Bogdanovics, R.; Bogdanovica, S. The Study of CO2 Concentration in A Classroom During The Covid-19 Safety Measures. E3S Web Conf. 2021, 246, 01004. [Google Scholar] [CrossRef]
  48. Arzoumanian, E.; Vogel, F.R.; Bastos, A.; Gaynullin, B.; Laurent, O.; Ramonet, M.; Ciais, P. Characterization of a commercial lower-cost medium-precision non-dispersive infrared sensor for atmospheric CO2 monitoring in urban areas. Atmos. Meas. Tech. 2019, 12, 2665–2677. [Google Scholar] [CrossRef] [Green Version]
  49. Almeida-Silva, M.; Canha, N.; Freitas, M.; Dung, H.; Dionísio, I. Air pollution at an urban traffic tunnel in Lisbon, Portugal—An INAA study. Appl. Radiat. Isot. 2011, 69, 1586–1591. [Google Scholar] [CrossRef]
  50. Molina, A.; Escobar-Barrios, V.; Oliva, J. A review on hybrid and flexible CO2 gas sensors. Synth. Met. 2020, 270, 116602. [Google Scholar] [CrossRef]
  51. Hammad, A.B.A.; Elnahrawy, A.M.; Youssef, A.M. Sol gel synthesis of hybrid chitosan/calcium aluminosilicate nanocomposite membranes and its application as support for CO2 sensor. Int. J. Biol. Macromol. 2018, 125, 503–509. [Google Scholar] [CrossRef]
  52. Fasching, R.; Kohl, F.; Urban, G. A miniaturized amperometric CO2 sensor based on dissociation of copper complexes. Sens. Actuators B Chem. 2003, 93, 197–204. [Google Scholar] [CrossRef]
  53. Decker, M.; Oelßner, W.; Zosel, J. Chapter 4—Electrochemical CO2 Sensors with Liquid or Pasty Electrolyte. In Carbon Dioxide Sensing: Fundamentals, Principles, and Applications; Wiley Online Library: Hoboken, NJ, USA, 2019; pp. 87–116. [Google Scholar] [CrossRef]
  54. Tebizi-Tighilt, F.-Z.; Zane, F.; Belhaneche-Bensemra, N.; Belhousse, S.; Sam, S.; Gabouze, N.-E. Electrochemical gas sensors based on polypyrrole-porous silicon. Appl. Surf. Sci. 2013, 269, 180–183. [Google Scholar] [CrossRef]
  55. Triana, Y.; Ogata, G.; Einaga, Y. Application of boron doped diamond electrodes to electrochemical gas sensor. Curr. Opin. Electrochem. 2022, 36, 101113. [Google Scholar] [CrossRef]
  56. Gómez, J.C.; Pelegri-Sebastia, J.; Lajara, R. Circuit Topologies for MOS-Type Gas Sensor. Electronics 2020, 9, 525. [Google Scholar] [CrossRef] [Green Version]
  57. Hayat, A.; Marty, J.L. Disposable Screen Printed Electrochemical Sensors: Tools for Environmental Monitoring. Sensors 2014, 14, 10432–10453. [Google Scholar] [CrossRef] [Green Version]
  58. Mahajan, S.; Jagtap, S. Metal-oxide semiconductors for carbon monoxide (CO) gas sensing: A review. Appl. Mater. Today 2020, 18, 100483. [Google Scholar] [CrossRef]
  59. Dwivedi, D.; Srivastava, S. Sensing properties of palladium-gate MOS (Pd-MOS) hydrogen sensor-based on plasma grown silicon dioxide. Sens. Actuators B Chem. 2000, 71, 161–168. [Google Scholar] [CrossRef]
  60. Gancarz, M.; Malaga-Toboła, U.; Oniszczuk, A.; Tabor, S.; Oniszczuk, T.; Gawrysiak-Witulska, M.; Rusinek, R. Detection and measurement of aroma compounds with the electronic nose and a novel method for MOS sensor signal analysis during the wheat bread making process. Food Bioprod. Process. 2021, 127, 90–98. [Google Scholar] [CrossRef]
  61. Nazemi, H.; Joseph, A.; Park, J.; Emadi, A. Advanced Micro- and Nano-Gas Sensor Technology: A Review. Sensors 2019, 19, 1285. [Google Scholar] [CrossRef] [Green Version]
  62. Wang, C.; Yin, L.; Zhang, L.; Xiang, D.; Gao, R. Metal Oxide Gas Sensors: Sensitivity and Influencing Factors. Sensors 2010, 10, 2088–2106. [Google Scholar] [CrossRef] [Green Version]
  63. Kanazawa, E.; Sakai, G.; Shimanoe, K.; Kanmura, Y.; Teraoka, Y.; Miura, N.; Yamazoe, N. Metal oxide semiconductor N2O sensor for medical use. Sens. Actuators B Chem. 2001, 77, 72–77. [Google Scholar] [CrossRef]
  64. Struzik, M.; Garbayo, I.; Pfenninger, R.; Rupp, J.L.M. A Simple and Fast Electrochemical CO2 Sensor Based on Li7La3Zr2O12for Environmental Monitoring. Adv. Mater. 2018, 30, e1804098. [Google Scholar] [CrossRef]
  65. Yoon, H.J.; Jun, D.H.; Yang, J.H.; Zhou, Z.; Yang, S.S.; Cheng, M.M.-C. Carbon dioxide gas sensor using a graphene sheet. Sens. Actuators B Chem. 2011, 157, 310–313. [Google Scholar] [CrossRef]
  66. Gheorghe, A.; Lugier, O.; Ye, B.; Tanase, S. Metal–organic framework based systems for CO2 sensing. J. Mater. Chem. C 2021, 9, 16132–16142. [Google Scholar] [CrossRef]
  67. Ye, B.; Gheorghe, A.; van Hal, R.; Zevenbergen, M.; Tanase, S. CO2 sensing under ambient conditions using metal–organic frameworks. Mol. Syst. Des. Eng. 2020, 5, 1071–1076. [Google Scholar] [CrossRef] [Green Version]
  68. Ding, Y.; Guo, X.; Du, B.; Hu, X.; Yang, X.; He, Y.; Zhou, Y.; Zang, Z. Low-operating temperature ammonia sensor based on Cu2O nanoparticles decorated with p-type MoS2 nanosheets. J. Mater. Chem. C 2021, 9, 4838–4846. [Google Scholar] [CrossRef]
  69. Zaporotskova, I.V.; Boroznina, N.P.; Parkhomenko, Y.N.; Kozhitov, L.V. Carbon nanotubes: Sensor properties. A review. Mod. Electron. Mater. 2016, 2, 95–105. [Google Scholar] [CrossRef]
  70. Chopra, S.; McGuire, K.; Gothard, N.; Rao, A.M.; Pham, A. Selective gas detection using a carbon nanotube sensor. Appl. Phys. Lett. 2003, 83, 2280–2282. [Google Scholar] [CrossRef]
  71. Tian, W.; Liu, X.; Yu, W. Research Progress of Gas Sensor Based on Graphene and Its Derivatives: A Review. Appl. Sci. 2018, 8, 1118. [Google Scholar] [CrossRef] [Green Version]
  72. Nag, A.; Mitra, A.; Mukhopadhyay, S.C. Graphene and its sensor-based applications: A review. Sens. Actuators A Phys. 2018, 270, 177–194. [Google Scholar] [CrossRef]
  73. Liu, L.; Zhou, Y.; Liu, S.; Xu, M. The Applications of Metal−Organic Frameworks in Electrochemical Sensors. Chemelectrochem 2017, 5, 6–19. [Google Scholar] [CrossRef]
  74. Yang, X.-L.; Ding, C.; Guan, R.-F.; Zhang, W.-H.; Feng, Y.; Xie, M.-H. Selective dual detection of H2S and Cu2+ by a post-modified MOF sensor following a tandem process. J. Hazard. Mater. 2020, 403, 123698. [Google Scholar] [CrossRef]
  75. Wang, Q.; Liu, Q.; Du, X.-M.; Zhao, B.; Li, Y.; Ruan, W.-J. A white-light-emitting single MOF sensor-based array for berberine homologue discrimination. J. Mater. Chem. C 2019, 8, 1433–1439. [Google Scholar] [CrossRef]
  76. Tanase, S.; Mittelmeijer-Hazeleger, M.C.; Rothenberg, G.; Mathonière, C.; Jubera, V.; Smits, J.M.M.; de Gelder, R. A facile building-block synthesis of multifunctional lanthanide MOFs. J. Mater. Chem. 2011, 21, 15544–15551. [Google Scholar] [CrossRef] [Green Version]
  77. Ma, Z.; Yuan, T.; Fan, Y.; Wang, L.; Duan, Z.; Du, W.; Zhang, D.; Xu, J. A benzene vapor sensor based on a metal-organic framework-modified quartz crystal microbalance. Sens. Actuators B Chem. 2020, 311, 127365. [Google Scholar] [CrossRef]
  78. Strauss, I.; Mundstock, A.; Treger, M.; Lange, K.; Hwang, S.; Chmelik, C.; Rusch, P.; Bigall, N.C.; Pichler, T.; Shiozawa, H.; et al. Metal–Organic Framework Co-MOF-74-Based Host–Guest Composites for Resistive Gas Sensing. ACS Appl. Mater. Interfaces 2019, 11, 14175–14181. [Google Scholar] [CrossRef] [Green Version]
  79. Chong, X.; Zhang, Y.; Li, E.; Kim, K.-J.; Ohodnicki, P.R.; Chang, C.-H.; Wang, A.X. Surface-Enhanced Infrared Absorption: Pushing the Frontier for On-Chip Gas Sensing. ACS Sens. 2018, 3, 230–238. [Google Scholar] [CrossRef]
  80. Kim, H.-T.; Hwang, W.; Liu, Y.; Yu, M. Ultracompact gas sensor with metal-organic-framework-based differential fiber-optic Fabry-Perot nanocavities. Opt. Express 2020, 28, 29937–29947. [Google Scholar] [CrossRef]
  81. Dmello, M.E.; Sundaram, N.G.; Kalidindi, S.B. Assembly of ZIF-67 Metal-Organic Framework over Tin Oxide Nanoparticles for Synergistic Chemiresistive CO2 Gas Sensing. Chem. Eur. J. 2018, 24, 9220–9223. [Google Scholar] [CrossRef]
  82. Yuan, H.; Tao, J.; Li, N.; Karmakar, A.; Tang, C.; Cai, H.; Pennycook, S.J.; Singh, N.; Zhao, D. On-Chip Tailorability of Capacitive Gas Sensors Integrated with Metal–Organic Framework Films. Angew. Chem. Int. Ed. 2019, 58, 14089–14094. [Google Scholar] [CrossRef]
  83. Gustafson, J.A.; Wilmer, C.E. Optimizing information content in MOF sensor arrays for analyzing methane-air mixtures. Sens. Actuators B Chem. 2018, 267, 483–493. [Google Scholar] [CrossRef]
  84. Gassensmith, J.J.; Kim, J.Y.; Holcroft, J.M.; Farha, O.K.; Stoddart, J.F.; Hupp, J.T.; Jeong, N.C. A Metal–Organic Framework-Based Material for Electrochemical Sensing of Carbon Dioxide. J. Am. Chem. Soc. 2014, 136, 8277–8282. [Google Scholar] [CrossRef]
  85. Zhan, Z.; Jia, Y.; Li, D.; Zhang, X.; Hu, M. A water-stable terbium-MOF sensor for the selective, sensitive, and recyclable detection of Al3+ and CO32− ions. Dalton Trans. 2019, 48, 15255–15262. [Google Scholar] [CrossRef]
  86. Allendorf, M.D.; Bauer, C.A.; Bhakta, R.K.; Houk, R.J.T. Luminescent metal–organic frameworks. Chem. Soc. Rev. 2009, 38, 1330–1352. [Google Scholar] [CrossRef] [PubMed]
  87. Jensen, S.; Tan, K.; Lustig, W.P.; Kilin, D.; Li, J.; Chabal, Y.J.; Thonhauser, T. Quenching of photoluminescence in a Zn-MOF sensor by nitroaromatic molecules. J. Mater. Chem. C 2019, 7, 2625–2632. [Google Scholar] [CrossRef]
  88. Chocarro-Ruiz, B.; Pérez-Carvajal, J.; Avci, C.; Calvo-Lozano, O.; Alonso, M.I.; Maspoch, D.; Lechuga, L.M. A CO2 optical sensor based on self-assembled metal–organic framework nanoparticles. J. Mater. Chem. A 2018, 6, 13171–13177. [Google Scholar] [CrossRef] [Green Version]
  89. Korotcenkov, G. Metal oxides for solid-state gas sensors: What determines our choice? Mater. Sci. Eng. B 2007, 139, 1–23. [Google Scholar] [CrossRef]
  90. Martin, C.R.; Zeng, N.; Karion, A.; Dickerson, R.R.; Ren, X.; Turpie, B.N.; Weber, K.J. Evaluation and environmental correction of ambient CO2 measurements from a low-cost NDIR sensor. Atmos. Meas. Tech. 2017, 10, 2383–2395. [Google Scholar] [CrossRef] [Green Version]
  91. Fisk, W.J.; Sullivan, D.P.; Faulkner, D.; Eliseeva, E. CO2 Monitoring for Demand Controlled Ventilation in Commercial Buildings; Lawrence Berkeley National Laboratory: Berkeley, CA, USA, 2010; Available online: https://escholarship.org/uc/item/4bk4x479 (accessed on 22 July 2022).
  92. Kamionka, M.; Breuil, P.; Pijolat, C. Calibration of a multivariate gas sensing device for atmospheric pollution measurement. Sens. Actuators B Chem. 2006, 118, 323–327. [Google Scholar] [CrossRef]
  93. Hasenfratz, D.; Saukh, O.; Thiele, L. On-the-fly calibration of low-cost gas sensors. In Lecture Notes in Computer Science (Including Subseries Lecture Notes in Artificial Intelligence and Lecture Notes in Bioinformatics); Springer: Berlin/Heidelberg, Germany, 2012; Volume 7158 LNCS, pp. 228–244. [Google Scholar] [CrossRef]
  94. Vafaei, M.; Amini, A. Chamberless NDIR CO2 Sensor Robust against Environmental Fluctuations. ACS Sens. 2021, 6, 1536–1542. [Google Scholar] [CrossRef]
  95. Ait-Helal, W.; Beeldens, A.; Boonen, E.; Borbon, A.; Boréave, A.; Cazaunau, M.; Chen, H.; Daële, V.; Dupart, Y.; Gaimoz, C.; et al. On-road measurements of NMVOCs and NOx: Determination of light-duty vehicles emission factors from tunnel studies in Brussels city center. Atmos. Environ. 2015, 122, 799–807. [Google Scholar] [CrossRef]
  96. Aldrin, M.; Haff, I.H.; Rosland, P. The effect of salting with magnesium chloride on the concentration of particular matter in a road tunnel. Atmos. Environ. 2008, 42, 1762–1776. [Google Scholar] [CrossRef]
  97. Allen, J.O.; Mayo, P.R.; Hughes, L.S.; Salmon, L.G.; Cass, G.R. Emissions of Size-Segregated Aerosols from On-Road Vehicles in the Caldecott Tunnel. Environ. Sci. Technol. 2001, 35, 4189–4197. [Google Scholar] [CrossRef]
  98. Alves, C.A.; Gomes, J.; Nunes, T.; Duarte, M.; Calvo, A.; Custódio, D.; Pio, C.; Karanasiou, A.; Querol, X. Size-segregated particulate matter and gaseous emissions from motor vehicles in a road tunnel. Atmos. Res. 2015, 153, 134–144. [Google Scholar] [CrossRef]
  99. Ameur-Bouddabbous, I.; Kasperek, J.; Barbier, A.; Harel, F.; Hannoyer, B. Transverse approach between real world concentrations of SO2, NO2, BTEX, aldehyde emissions and corrosion in the Grand Mare tunnel. J. Environ. Sci. 2012, 24, 1240–1250. [Google Scholar] [CrossRef]
  100. Barrefors, G.; Petersson, G. Volatile hazardous hydrocarbons in a Scandinavian urban road tunnel. Chemosphere 1992, 25, 691–696. [Google Scholar] [CrossRef] [Green Version]
  101. Bozlaker, A.; Spada, N.J.; Fraser, M.P.; Chellam, S. Elemental Characterization of PM2.5 and PM10 Emitted from Light Duty Vehicles in the Washburn Tunnel of Houston, Texas: Release of Rhodium, Palladium, And Platinum. Environ. Sci. Technol. 2013, 48, 54–62. [Google Scholar] [CrossRef]
  102. Chan, L.; Zeng, L.; Qin, Y.; Lee, S. CO concentration inside the Cross Harbor Tunnel in Hong Kong. Environ. Int. 1996, 22, 405–409. [Google Scholar] [CrossRef]
  103. Lin, Y.-C.; Tsai, C.-J.; Wu, Y.-C.; Zhang, R.; Chi, K.-H.; Huang, Y.-T.; Lin, S.-H.; Hsu, S.-C. Characteristics of trace metals in traffic-derived particles in Hsuehshan Tunnel, Taiwan: Size distribution, potential source, and fingerprinting metal ratio. Atmos. Meas. Tech. 2015, 15, 4117–4130. [Google Scholar] [CrossRef] [Green Version]
  104. Chirico, R.; Prevot, A.S.; DeCarlo, P.F.; Heringa, M.F.; Richter, R.; Weingartner, E.; Baltensperger, U. Aerosol and trace gas vehicle emission factors measured in a tunnel using an Aerosol Mass Spectrometer and other on-line instrumentation. Atmos. Environ. 2011, 45, 2182–2192. [Google Scholar] [CrossRef]
  105. Demir, T.; Yenisoy-Karakaş, S.; Karakaş, D. PAHs, elemental and organic carbons in a highway tunnel atmosphere and road dust: Discrimination of diesel and gasoline emissions. Build. Environ. 2019, 160, 106166. [Google Scholar] [CrossRef]
  106. De Fré, R.; Bruynseraede, P.; Kretzschmar, J.G. Air pollution measurements in traffic tunnels. Environ. Health Perspect. 1994, 102, 31–37. [Google Scholar] [CrossRef] [Green Version]
  107. Gaga, E.O.; Arı, A.; Akyol, N.; Üzmez, Ö.Ö.; Kara, M.; Chow, J.C.; Watson, J.G.; Özel, E.; Döğeroğlu, T.; Odabasi, M. Determination of real-world emission factors of trace metals, EC, OC, BTEX, and semivolatile organic compounds (PAHs, PCBs and PCNs) in a rural tunnel in Bilecik, Turkey. Sci. Total Environ. 2018, 643, 1285–1296. [Google Scholar] [CrossRef]
  108. Grieshop, A.P.; Lipsky, E.M.; Pekney, N.J.; Takahama, S.; Robinson, A.L. Fine particle emission factors from vehicles in a highway tunnel: Effects of fleet composition and season. Atmos. Environ. 2006, 40, 287–298. [Google Scholar] [CrossRef]
  109. Handler, M.; Puls, C.; Zbiral, J.; Marr, I.; Puxbaum, H.; Limbeck, A. Size and composition of particulate emissions from motor vehicles in the Kaisermühlen-Tunnel, Vienna. Atmos. Environ. 2008, 42, 2173–2186. [Google Scholar] [CrossRef]
  110. Kristensson, A.; Johansson, C.; Westerholm, R.; Swietlicki, E.; Gidhagen, L.; Wideqvist, U.; Vesely, V. Real-world traffic emission factors of gases and particles measured in a road tunnel in Stockholm, Sweden. Atmos. Environ. 2004, 38, 657–673. [Google Scholar] [CrossRef]
  111. Li, R.; Meng, Y.; Fu, H.; Zhang, L.; Ye, X.; Chen, J. Characteristics of the pollutant emissions in a tunnel of Shanghai on a weekday. J. Environ. Sci. 2018, 71, 136–149. [Google Scholar] [CrossRef]
  112. Liu, Y.; Gao, Y.; Yu, N.; Zhang, C.; Wang, S.; Ma, L.; Zhao, J.; Lohmann, R. Particulate matter, gaseous and particulate polycyclic aromatic hydrocarbons (PAHs) in an urban traffic tunnel of China: Emission from on-road vehicles and gas-particle partitioning. Chemosphere 2015, 134, 52–59. [Google Scholar] [CrossRef]
  113. Ma, C.-J.; Tohno, S.; Kasahara, M. A case study of the single and size-resolved particles in roadway tunnel in Seoul, Korea. Atmos. Environ. 2004, 38, 6673–6677. [Google Scholar] [CrossRef]
  114. Riccio, A.; Chianese, E.; Monaco, D.; Costagliola, M.; Perretta, G.; Prati, M.; Agrillo, G.; Esposito, A.; Gasbarra, D.; Shindler, L.; et al. Real-world automotive particulate matter and PAH emission factors and profile concentrations: Results from an urban tunnel experiment in Naples, Italy. Atmos. Environ. 2016, 141, 379–387. [Google Scholar] [CrossRef]
  115. Simmons, W.; Seakins, P. Estimations of primary nitrogen dioxide exhaust emissions from chemiluminescence NOx measurements in a UK road tunnel. Sci. Total Environ. 2012, 438, 248–259. [Google Scholar] [CrossRef]
  116. Song, C.; Ma, C.; Zhang, Y.; Wang, T.; Wu, L.; Wang, P.; Liu, Y.; Li, Q.; Zhang, J.; Dai, Q.; et al. Heavy-duty diesel vehicles dominate vehicle emissions in a tunnel study in northern China. Sci. Total Environ. 2018, 637–638, 431–442. [Google Scholar] [CrossRef]
  117. Sternbeck, J.; Sjödin, Å.; Andréasson, K. Metal emissions from road traffic and the influence of resuspension—Results from two tunnel studies. Atmos. Environ. 2002, 36, 4735–4744. [Google Scholar] [CrossRef]
  118. Touaty, M.; Bonsang, B. Hydrocarbon emissions in a highway tunnel in the Paris area. Atmos. Environ. 2000, 34, 985–996. [Google Scholar] [CrossRef]
  119. Vasconcellos, P.C.; Carvalho, L.R.F.; Pool, C.S. Volatile organic compounds inside urban tunnels of São Paulo City, Brazil. J. Braz. Chem. Soc. 2005, 16, 1210–1216. [Google Scholar] [CrossRef] [Green Version]
  120. Wang, M.; Wang, X.; Yu, L.; Deng, T. Field measurements of the environmental parameter and pollutant dispersion in urban undersea road tunnel. Build. Environ. 2019, 149, 100–108. [Google Scholar] [CrossRef]
  121. Zhang, Q.; Wu, L.; Fang, X.; Liu, M.; Zhang, J.; Shao, M.; Lu, S.; Mao, H. Emission factors of volatile organic compounds (VOCs) based on the detailed vehicle classification in a tunnel study. Sci. Total Environ. 2017, 624, 878–886. [Google Scholar] [CrossRef]
  122. Kurtenbach, R.; Becker, K.; Gomes, J.; Kleffmann, J.; Lörzer, J.; Spittler, M.; Wiesen, P.; Ackermann, R.; Geyer, A.; Platt, U. Investigations of emissions and heterogeneous formation of HONO in a road traffic tunnel. Atmos. Environ. 2001, 35, 3385–3394. [Google Scholar] [CrossRef]
  123. Bari, S.; Naser, J. Simulation of airflow and pollution levels caused by severe traffic jam in a road tunnel. Tunn. Undergr. Space Technol. 2010, 25, 70–77. [Google Scholar] [CrossRef]
  124. Pang, Z.; Hu, P.; Lu, X.; Wang, Q.; O’Neill, Z.; Bueno, B.; Sepúlveda, A.; Maurer, C.; Wacker, S.; Kuhn, T.E.; et al. A Smart CO2-Based Ventilation Control Framework to Minimize the Infection Risk of COVID-19 in Public Buildings. 2021. Available online: https://www.researchgate.net/profile/Zhihong-Pang/publication/349121056_A_Smart_CO2-Based_Ventilation_Control_Framework_to_Minimize_the_Infection_Risk_of_COVID-19_In_Public_Buildings/links/6021a8c4458515893990132f/A-Smart-CO2-Based-Ventilation-Control-Framework-to-Minimize-the-Infection-Risk-of-COVID-19-In-Public-Buildings.pdf (accessed on 19 August 2022).
  125. Blad, T.; Nijssen, J.; Broeren, F.; Boogaard, B.; Lampaert, S.; Toorn, S.V.D.; Dobbelsteen, J.V.D. A Rapidly Deployable Test Suite for Respiratory Protective Devices in the COVID-19 Pandemic. Appl. Biosaf. 2020, 25, 161–168. [Google Scholar] [CrossRef]
  126. Tipparaju, V.V.; Mora, S.J.; Yu, J.; Tsow, F.; Xian, X. Wearable Transcutaneous CO₂ Monitor Based on Miniaturized Nondispersive Infrared Sensor. IEEE Sens. J. 2021, 21, 17327–17334. [Google Scholar] [CrossRef]
  127. Chen, C.-Y.; Chen, P.-H.; Chen, J.-K.; Su, T.-C. Recommendations for ventilation of indoor spaces to reduce COVID-19 transmission. J. Formos. Med. Assoc. 2021, 120, 2055–2060. [Google Scholar] [CrossRef]
  128. Hou, D.; Katal, A.; Wang, L.; Professor, A. Bayesian Calibration of Using CO2 Sensors to Assess Ventilation Conditions and Associated COVID-19 Airborne Aerosol Transmission Risk in Schools. medRxiv 2021. [Google Scholar] [CrossRef]
  129. Virbulis, J.; Sjomkane, M.; Surovovs, M.; Jakovics, A. Numerical Model for Prediction of Indoor COVID-19 Infection Risk Based on Sensor Data. J. Phys. Conf. Ser. 2021, 2069, 12189. [Google Scholar] [CrossRef]
  130. Bazant, M.Z.; Kodio, O.; Cohen, A.E.; Khan, K.; Gu, Z.; Bush, J.W. Monitoring carbon dioxide to quantify the risk of indoor airborne transmission of COVID-19. Flow 2021, 1, E10. [Google Scholar] [CrossRef]
  131. Lee, Y.-K.; Kim, Y.I.; Lee, W.-S. Development of CO2 Concentration Prediction Tool for Improving Office Indoor Air Quality Considering Economic Cost. Energies 2022, 15, 3232. [Google Scholar] [CrossRef]
  132. Mumtaz, R.; Zaidi, S.; Shakir, M.; Shafi, U.; Malik, M.; Haque, A.; Mumtaz, S.; Zaidi, S. Internet of Things (IoT) Based Indoor Air Quality Sensing and Predictive Analytic—A COVID-19 Perspective. Electronics 2021, 10, 184. [Google Scholar] [CrossRef]
  133. Li, B.; Cai, W. A novel CO2-based demand-controlled ventilation strategy to limit the spread of COVID-19 in the indoor environment. Build. Environ. 2022, 219, 109232. [Google Scholar] [CrossRef]
  134. Bouguera, T.; Diouris, J.-F.; Chaillout, J.-J.; Jaouadi, R.; Andrieux, G. Energy Consumption Model for Sensor Nodes Based on LoRa and LoRaWAN. Sensors 2018, 18, 2104. [Google Scholar] [CrossRef]
Figure 1. Diagram of an NDIR-type sensor operation based on [36].
Figure 1. Diagram of an NDIR-type sensor operation based on [36].
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Figure 2. Midinfrared absorption spectra of selected molecules with their relative intensities. H2O water; CO2: carbon dioxide; CO: carbon monoxide; NO: nitric oxide; NO2: nitrogen dioxide; CH4: methane; O3: oxygen; NH3: ammonia [46].
Figure 2. Midinfrared absorption spectra of selected molecules with their relative intensities. H2O water; CO2: carbon dioxide; CO: carbon monoxide; NO: nitric oxide; NO2: nitrogen dioxide; CH4: methane; O3: oxygen; NH3: ammonia [46].
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Figure 3. Diagram of MOS-type sensor operation. Based on [34].
Figure 3. Diagram of MOS-type sensor operation. Based on [34].
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Figure 4. Schematic diagram of operation of MOF-type sensors. Based on: [66].
Figure 4. Schematic diagram of operation of MOF-type sensors. Based on: [66].
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Figure 5. Schematic diagram of a fully mixed box model. Cin, C and Cout are concentrations of the monitored gas in the inflow, indoor air and outflow, respectively, Qin, Qout are air flows into/out of the building/space V is room volume [32].
Figure 5. Schematic diagram of a fully mixed box model. Cin, C and Cout are concentrations of the monitored gas in the inflow, indoor air and outflow, respectively, Qin, Qout are air flows into/out of the building/space V is room volume [32].
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Figure 6. Error from single-concentration calibration checks and multi-concentration calibration challenges at 510 ppm plotted versus sensor age. The error bars represent one standard deviation in the error [91].
Figure 6. Error from single-concentration calibration checks and multi-concentration calibration challenges at 510 ppm plotted versus sensor age. The error bars represent one standard deviation in the error [91].
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Figure 7. Map indicating global air quality laws and geographical distribution of studies [15].
Figure 7. Map indicating global air quality laws and geographical distribution of studies [15].
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Table 1. Comparison of various types of gas sensors [29,89].
Table 1. Comparison of various types of gas sensors [29,89].
ParameterType of Gas Sensors
SemiconductorElectrochemicalInfrared Absorption
SensitivityEGE
AccuracyGGE
SelectivityPGE
Response timeEPP
StabilityGBG
DurabilityGPE
MaintenanceEGP
CostEGP
Portable instrumentEPB
E: excellent, G: good, P: poor, B: bad
Table 2. Compilation of tunnels in which research projects aimed at measuring gas concentration.
Table 2. Compilation of tunnels in which research projects aimed at measuring gas concentration.
Infrastructure NameRef.
Annie Cordy Tunnel. Tunnel in Brussels city centre, Belgium[95]
Strømsås Tunnel. Road tunnel in Drammen, Norway [96]
Caldecott Tunnel. Tunnel in San Francisco Bay, California[97]
Urban traffic tunnels in Lisbon, Portugal[98]
Liberdade Avenue Tunnel (Braga, Portugal)[46]
Grand Mare Tunnel. Road tunnel located in Rouen, France[99]
Tingstad Tunnel. City tunnel in Gothenburg, Sweden[100]
Washburn Tunnel. Urban tunnel in Houston, Texas[101]
Cross Harbour Tunnel. Underwater urban tunnel in Hong Kong, China[102]
Hsuehshan Tunnel. Road tunnel on the Taipei-Yilan Freeway, Taiwan[103]
Gubrist tunnel. Highway tunnel in Zurich, Switzerland[104]
Craeybeckx Tunnel. Highway tunnel in Antwerp, Belgium[105]
Mount Bolu Tunnel. Highway tunnel in Turkey[106]
Osmaganzi Tunnel. Highway tunnel located in Bilecik, Turkey[107]
Highway tunnel in Pittsburgh, Pennsylvania[108]
Kaisermühlen Tunnel. Urban tunnel in Vienna, Austria[109]
Söderleds Tunnel. Urban tunnel in Stockholm, Sweden[110]
Túneles de carretera en Pittsburgh, Pennsylvania[8]
Xiangyin Tunnel. Urban tunnel in Shanghai, China[111]
Yan’an East Road Tunnel. Urban tunnel in the centre of Shanghai, China[112]
Buk-Ak Tunnel. Highway tunnel in Seoul, Korea[113]
Loma Larga Tunnel. Highway tunnel located in Monterrey, Mexico[12]
Fort McHenry Tunnel. Highway tunnel in Maryland [11]
Tuscarora Tunnel. Highway tunnel in Pennsylvania[11]
Marquês de Pombal Tunnel. Urban tunnel in Lisbon, Portugal[13]
‘4 Giornate’ Tunnel. Urban tunnel in Naples, Italy[114]
Westgate Tunnel. Leeds urban tunnel, United Kingdom[115]
Wujinglu Tunnel. Urban tunnel in Tianjin, China[116]
Tingstad Tunnel and Lundby Tunnel. Urban tunnels in Gothenburg, Sweden[117]
Thiais Tunnel. Highway tunnel in Paris, Francia[118]
Urban tunnels in Sao Paulo, Brasil[119]
Xiamen XiangAn Tunnel. Undersea tunnel in China [120]
Mountain tunnel in Nanjing, China[121]
Kiesberg Tunnel. Highway tunnel located between Düsseldorf and Wuppertal[122]
Domain Tunnel and Burnley Tunnel. Urban tunnels en Melbourne, Australia[123]
Table 3. References classified according to application and sensor type.
Table 3. References classified according to application and sensor type.
IssueNDIR SensorsElectrochemical Sensors
review[29,33,35,36,37,38,39,44,46][29,35,50,56,58,60,61,62,65,69,71,72,73,76,86,89]
domestic applications[32,33,37,40,42,43,45,88,91,125,126,128,129,130,131,132,133][66,67,68,82,83,84,88]
industrial applications[4,35,41,91,94][25,28,41,51,52,53,54,55,59,63,64,70,74,75,77,78,79,80,81,85,87]
infrastructure[4,7,9,10,11,12,13,14,15,17,22,90,98,104,113,116,120,122][15,55]
environment[5,6,9,30,31,35,48,93,94][5,6,27,55,57,92]
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Cepa, J.J.; Pavón, R.M.; Caramés, P.; Alberti, M.G. A Review of Gas Measurement Practices and Sensors for Tunnels. Sensors 2023, 23, 1090. https://doi.org/10.3390/s23031090

AMA Style

Cepa JJ, Pavón RM, Caramés P, Alberti MG. A Review of Gas Measurement Practices and Sensors for Tunnels. Sensors. 2023; 23(3):1090. https://doi.org/10.3390/s23031090

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Cepa, Jorge J., Rubén M. Pavón, Paloma Caramés, and Marcos G. Alberti. 2023. "A Review of Gas Measurement Practices and Sensors for Tunnels" Sensors 23, no. 3: 1090. https://doi.org/10.3390/s23031090

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