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Molecular Characterization of Biopolymers and Biobased Bioplastics

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Materials Chemistry".

Deadline for manuscript submissions: closed (20 May 2021) | Viewed by 5539

Special Issue Editor


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Guest Editor
MOSS Group, Instituto de Recursos Naturales y Agrobiologia de Sevilla (IRNAS-CSIC), 41012 Sevilla, Spain
Interests: environmental organic geochemistry, including organic matter and soil health; organic contaminants in nature; refractory C forms in nature; molecular characterization of soil organic matter and its agronomic and environmental implications; biogeochemical markers in soils and sediments; the use of advanced techniques for organic matter and biopolymer characterization (GC/MS, Py-GC/MS, FT-IR, ED-XRF, IRMS, CSIA, 13C-MAS-NMR; high resolution MS, GC/Q-TOF)
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Special Issue Information

Dear Colleagues,

Biopolymers synthesized by living organisms are amazing materials, enormously abundant in nature with diverse properties and biological functions. Today, biobased bioplastics, which encompass a whole family of materials usually based in biopolymers, are considered the natural evolution of conventional petroleum-based plastics and envisaged as a solution and an environmentally acceptable alternative for the many uses of these synthetic materials. Apart from saving fossil resources by using renewable materials (biomass), bioplastics are usually biodegradable, offering means of recovery at the end of the product’s life. This may help to solve some of the most urgent problems caused by the overuse of conventional synthetic petroleum-based polymers such as water and soil pollution, the deleterious influence to human and animal health, and the varied problems derived from the increasing ammount of microplastics in the environment.
An accurate molecular characterization of biopolymers and bio-based bioplastics is important, among many other reasons to infer and discover functionalities and properties, to trace organic matter in soils and sediments, for the design of new uses and applications, for quality control and forensic purpose and to foresee its fate in the environment and the design of appropriate recovery strategies. This Special Issue on “Molecular Characterization of Biopolymers and Bio-Based Bioplastics” intends to compile the latest analytical developments applied towards a better structural knowledge of these valuable materials, from natural polymers in biomass (biopolyesters, celluloses, lignins, suberins and cutins, chitins, proteins, polypeptides and polynucleotides) to the new polymers derived from renewable biomass sources (starch, cellulose, protein, lipid derived polymers, aliphatic polyesters, etc.). Manuscripts including multidisciplinary approaches and the use of complementary techniques for the molecular characterization and traceability of biopolymers in the environment (biomarkers) will be particularly welcome.

Dr. José A. González-Pérez
Guest Editor

Manuscript Submission Information

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Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • Biomass
  • Biopolymers
  • Bioplastics
  • Structural characterization
  • Chromatography
  • Spectroscopy
  • Spectrometry
  • Stable isotopes
  • Pyrolysis
  • Recycling
  • Biomarker

Published Papers (2 papers)

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Research

13 pages, 3615 KiB  
Article
Bio-Based Hydrogels Composed of Humic Matter and Pectins of Different Degree of Methyl-Esterification
by Assunta Nuzzo, Pierluigi Mazzei, Davide Savy, Vincenzo Di Meo and Alessandro Piccolo
Molecules 2020, 25(12), 2936; https://doi.org/10.3390/molecules25122936 - 25 Jun 2020
Cited by 6 | Viewed by 2298
Abstract
We prepared humo-pectic hydrogels through ionotropic gelation by crosslinking natural pectins of different degree of methyl-esterification with either humic substances (HS) extracted from cow manure compost or humic-like substances (HULIS) from depolymerized lignocellulose biorefinery waste. The hydrogels were characterized by solid-state 13C-NMR [...] Read more.
We prepared humo-pectic hydrogels through ionotropic gelation by crosslinking natural pectins of different degree of methyl-esterification with either humic substances (HS) extracted from cow manure compost or humic-like substances (HULIS) from depolymerized lignocellulose biorefinery waste. The hydrogels were characterized by solid-state 13C-NMR spectroscopy, scanning electron microscopy, spectroscopic magnetic resonance imaging and rheological analyses. Their ability to work as controlled release systems was tested by following the release kinetics of a previously incorporated model phenolic compound, like phloroglucinol. Our results indicated that the release properties of hydrogels were influenced by the molecular composition of HS and HULIS and by the different degrees of methyl-esterification of pectins. The hydrogel made by the high methoxyl pectin and HS showed the fastest rate of phloroglucinol release, and this was attributed not only to its morphological structure and crosslinking density but also to the least formation of ionic interactions between phloroglucinol and the polysaccharidic chains. Our study suggests that the efficiency of novel humo-pectic hydrogels as sustainable carriers of agroproducts to crops is related to a careful choice of the characteristics of their components. Full article
(This article belongs to the Special Issue Molecular Characterization of Biopolymers and Biobased Bioplastics)
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14 pages, 3994 KiB  
Article
Structure and Properties of Biodegradable Poly (Xylitol Sebacate-Co-Butylene Sebacate) Copolyester
by Marta Piątek-Hnat, Kuba Bomba and Jakub Pęksiński
Molecules 2020, 25(7), 1541; https://doi.org/10.3390/molecules25071541 - 28 Mar 2020
Cited by 7 | Viewed by 2688
Abstract
In this work, a bio-based copolyester with good mechanical properties was synthesized and characterized in terms of structure, main properties and biodegradability Determining the chemical structure of such materials is important to understand their behavior and properties. Performing an extraction of insoluble cross-linked [...] Read more.
In this work, a bio-based copolyester with good mechanical properties was synthesized and characterized in terms of structure, main properties and biodegradability Determining the chemical structure of such materials is important to understand their behavior and properties. Performing an extraction of insoluble cross-linked polymer using different solvents allowed us to analyze how the polymer behaves when subjected to different chemical environments, and to obtain soluble samples suitable for more in-depth analysis. Chemical structure of poly (xylitol sebacate-co-butylene sebacate) was determined by a 1H NMR and FTIR analysis of both prepolymer gel sample and samples obtained by extraction of cross-linked polymer using different solvents. Block structure of the copolymer was confirmed by both NMR and DSC. Gel fraction, swelling value, water contact angle, and mechanical properties were also analyzed. Biodegradability of this material was confirmed by performing enzymatic and hydrolytic degradation. Synthesizing sugar-alcohol based copolyester using three monomers leads to obtaining a material with interesting chemical structure and desirable mechanical properties comparable to conventional elastomers. Full article
(This article belongs to the Special Issue Molecular Characterization of Biopolymers and Biobased Bioplastics)
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