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Molecules
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Design and Application of Periodic Frameworks
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Design and Application of Periodic Frameworks

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Materials Chemistry".

Deadline for manuscript submissions: 31 May 2024 | Viewed by 983

Special Issue Editor

Dr. Jiafei Lyu

E-Mail Website
Guest Editor
Department of Pharmaceutical Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
Interests: novel porous materials for adsorption and catalysis

Special Issue Information

Dear Colleagues,

The past two decades have witnessed the progress of new-generation periodic frameworks including metal–organic frameworks (MOFs), covalent organic frameworks (COFs), and hydrogen-bonded organic frameworks (HOFs). Given tailorable structures with high internal surfaces and specific pore sizes, significant attention has been gained for their structural design and potential development.

We are pleased to invite you to contribute to the Special Issue “Design and Application of Periodic Frameworks”. The following type of manuscripts will be considered for publication: full research articles, short communications and reviews. This Special Issue includes but is not limited to the design, synthesis, modification, characterization, and applications of novel periodic materials.

Dr. Jiafei Lyu
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Molecules is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • metal–organic frameworks (MOFs)
  • covalent organic frameworks (COFs)
  • hydrogen-bonded organic frameworks (HOFs)
  • structure-assembling of periodic frameworks
  • modification of periodic frameworks
  • chemical separation by periodic frameworks
  • catalysis involving periodic frameworks
  • facile preparation of periodic frameworks
  • composite materials deviated from periodic frameworks

Published Papers (1 paper)

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Research

15 pages, 6229 KiB  
Article
Cu(II) Coordination Polymers Containing Mixed Ligands with Different Flexibilities: Structural Diversity and Iodine Adsorption
by Shu-Yu Lin, Yi-Lin Shen, Wei-Hao Chen, Manivannan Govindaraj and Jhy-Der Chen
Molecules 2024, 29(2), 311; https://doi.org/10.3390/molecules29020311 - 08 Jan 2024
Viewed by 719
Abstract
Reactions of N,N′-bis(3-methylpyridyl)oxalamide (L1), N,N’-bis(3-methylpyridyl)adipoamide (L2) and N,N’-bis(3-methylpyridyl)sebacoamide (L3) with tricarboxylic acids and Cu(II) salts afforded {[Cu(L1)(1,3,5-HBTC)]·H2 [...] Read more.
Reactions of N,N′-bis(3-methylpyridyl)oxalamide (L1), N,N’-bis(3-methylpyridyl)adipoamide (L2) and N,N’-bis(3-methylpyridyl)sebacoamide (L3) with tricarboxylic acids and Cu(II) salts afforded {[Cu(L1)(1,3,5-HBTC)]·H2O}n (1,3,5-H3BTC = 1,3,5-benzenetricarboxylic acid), 1, {[Cu1.5(L2)1.5(1,3,5-BTC)(H2O)2]·6.5H2O}n, 2, [Cu(L2)0.5(1,3,5-HBTB)]n (1,3,5-H3BTB = 1,3,5-tri(4-carboxyphenyl)benzene), 3, [Cu4(L3)(OH)2(1,3,5-BTC)2]n, 4, {[Cu3(L3)2(1,3,5-BTB)2]·2.5MeOH·2H2O}n, 5, and {[Cu3(L3)2(1,3,5-BTB)2 ]·DMF·2H2O}n, 6, which have been structurally characterized by using single crystal X-ray crystallography. Complexes 1–4 form a 2D layer with the {44.62}-sql topology, a 2D layer with the (4.62)2(42.62.82)-bex topology, a three-fold interpenetrated 3D net with the (412·63)-pcu topology and a 3D framework with the (410·632·83)(42·6)2(43·63) topology, respectively, whereas 5 and 6 are 3D frameworks with the (63)2(64·82)(68·85·102) topology. Complex 5 shows a better iodine adsorption factor of 290.0 mg g−1 at 60 °C for 360 min than the other ones, revealing that the flexibility of the spacer ligand governs the structural diversity and the adsorption capacity. Full article
(This article belongs to the Special Issue Design and Application of Periodic Frameworks)
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