Janus Particles

A special issue of Crystals (ISSN 2073-4352). This special issue belongs to the section "Hybrid and Composite Crystalline Materials".

Deadline for manuscript submissions: closed (30 June 2023) | Viewed by 1543

Special Issue Editors

Materials Science & Engineering, Iowa State University, Ames, IA 50011, USA
Interests: Janus nanoparticles; polymer synthesis; polymeric materials; antibacterial coating; UV-block coating; tissue engineering

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Guest Editor
The Dow Chemical Company, Collegeville, PA 19426, USA
Interests: polymer science; material science; polymer coating; thin films; chemical vapor deposition; surface science; colloid assembly; nanocomposites; paint additives

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Guest Editor
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA
Interests: polymer; simulation; colloid; molecular dynamics; gels; soft matter
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Special Issue Information

Dear Colleagues,

Janus particles, named after the ancient Roman god Janus who has two faces on his head, were used to describe a unique class of colloidal particles with more than a single type of surface chemistry, composition, or physical functionalities, ranging in size from hundreds of nanometers to a few micrometers. The idea of Janus particles was first popularized by Pierre-Gilles de Gennes in his 1991 Nobel Prize lecture. It did not attract much notice until around 15 years later, but, since then, interest in the topic has grown more and more every year. Because of their asymmetry, Janus particles can self-assemble into complex materials and structures that are not attainable for their homogeneous counterparts. Their intriguing and practical features of multidirectional interaction open up new avenues for research in the realms of soft matter, fundamental materials, as well as applications in other fields and technologies, such as solid surfactants, interfacial catalyst, electronic paper, microprobes, micromotors, and other building blocks for functional materials.

Technological advances in manufacturing novel particles would dramatically improve our ability to build sustainable infrastructure, develop personalized medicine, elevate cost efficiency, and reduce energy consumption. One critical factor in determining the product properties is the particle morphology. It has been a longstanding goal to create novel particle morphologies that can help to improve the coating formulation and impart new functionalities. One promising example is the Janus morphology. They can serve as a better stabilizer for emulsions, offer new drug delivery capabilities, and create a multi-functional coating matrix. However, the ability to create and control particle morphologies in large-scale manufacture remains extremely limited. Meanwhile, with the fast-expanding study of functional Janus particles, it becomes urgent to explore more industrial-related applications for these intriguing materials.

We invite contributions on the synthesis of the Janus particles (block polymer self-assembly, direct seeded growth, surface selective modification, emulsion-based phase separation, etc.). While contributions reporting their properties (emulsification, self-assembly, environmental responsiveness, etc.) and potential applications are highly encouraged, studies reporting Janus particles because of their intriguing morphologies are also welcome. We particularly encourage practical application studies utilizing Janus particles, such as smart coating additives, targeted delivery, and building blocks for hierarchical structures.

Dr. Yifan Li
Dr. Xiaoshuang Wei
Dr. Shensheng Chen
Guest Editors

Manuscript Submission Information

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Keywords

  • janus particles
  • emulsion polymerization
  • microfluidic synthesis
  • amphiphilicity
  • catalysis
  • dipolar
  • nanoparticles
  • asymmetric properties
  • multicompartment particles
  • microprobes, reconfigurable materials and micromotors
  • solid surfactants
  • block copolymers
  • surface modification and compartmentalization
  • smart materials
  • multifunctional coatings
  • active surfaces and interfaces
  • coating additives

Published Papers (1 paper)

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Research

13 pages, 7833 KiB  
Article
Enhancement of Intrinsic Temperature Reduction for Plasma Surface-Modified Nanoparticle-Doped Low-Density Polyethylene Films
by Chenlei Qiu, Yiping Qiu, Yinjia Zhang and Lina Cui
Crystals 2023, 13(4), 707; https://doi.org/10.3390/cryst13040707 - 21 Apr 2023
Viewed by 1175
Abstract
The cooling performance of nanoparticle (NP)-doped radiative cooling materials depends on the dispersion of the NPs in the polymer matrix. However, it is a technical challenge to suppress agglomeration of NPs due to their high surface energy, resulting in poor dispersion of the [...] Read more.
The cooling performance of nanoparticle (NP)-doped radiative cooling materials depends on the dispersion of the NPs in the polymer matrix. However, it is a technical challenge to suppress agglomeration of NPs due to their high surface energy, resulting in poor dispersion of the NPs in the polymer matrix. In order to optimize the dispersion of zinc oxide (ZnO) NPs in low-density polyethylene (LDPE), NPs were treated with atmospheric pressure plasmas for 30, 60 and 90 s. The ZnO NPs were dispersed in LDPE using a xylene solution method. The dispersion of the NPs was progressively improved as the plasma-treatment time increased, likely due to the roughened and perhaps also activated NP surfaces by the plasma treatment. This made the transmittances of the films decrease in the solar-radiation band and absorptivity increased monotonically in the high-energy band as the plasma-treatment time increased, while in the mid-infrared band, the films maintained a similar high transmittance to the untreated sample. The differential scanning colorimetry analysis revealed that the crystallinities of the plasma-treated NP-doped samples were similar to those of the untreated sample. The cooling-performance tests showed that the maximum temperature reductions of the films with NP plasma-treated for 0 s, 30 s, 60 s and 90 s were 6.82, 7.90, 9.34 and 10.34 °C, respectively, corresponded to the intrinsic temperature reductions of 7.27, 8.23, 10.54, and 11.40 °C, respectively, when calculated using Cui’s Model. The results of the current study show that a simple one-step atmospheric pressure plasma treatment to the ZnO NPs can indeed improve dispersion of the NPs in LDPE and lead to the greatly improved passive-cooling performance of the film. Full article
(This article belongs to the Special Issue Janus Particles)
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