Effects of Laser Treatment on Surface Characterization and Mechanical Properties of Alloys

A special issue of Coatings (ISSN 2079-6412). This special issue belongs to the section "Surface Characterization, Deposition and Modification".

Deadline for manuscript submissions: 20 November 2024 | Viewed by 8652

Special Issue Editor


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Guest Editor
Applied Materials & Manufacturing, Energy and Environment Directorate, Pacific Northwest National Laboratory (PNNL), Richland, WA, USA
Interests: laser material processing; laser-based wettability modification (superhydrophobicity, superhydrophilicity, superwicking); laser shock processing; laser-based additive manufacturing; laser-assisted machining; ultrasonic welding; friction stir processing; related applications
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Special Issue Information

Dear Colleagues,

We have the pleasure to invite you to submit your research works to our Special Issue “Effects of Laser Treatment on Surface Characterization and Mechanical Properties of Alloys”. Laser-based material processing and surface engineering techniques are useful to enhance material properties and surface characteristics of metals and alloys. Remarkable progress has been achieved on both the fundamental knowledge and material processing front. Controlled and selective laser processing is an active area of research to prepare surfaces for various applications. Laser processing can enhance surface wetting characteristics, activate a surface for multifunctionality, improve residual stress behavior, corrosion resistance, tribological characteristics, etc. Laser-induced deposition, alloying, and shock processing add another dimension to the surface treatment processing window.

This Special Issue of Coatings is devoted to advances in laser-based material processing with an emphasis on surface characterization and enhancement of mechanical properties of metals and alloys. Submission of original research articles and reviews is welcome. Research areas may include (but are not limited to) the following:

  • Recent developments in laser processing related to surface engineering, such as shock processing, ablation, texturing, re-melting, polishing, etc.;
  • Effect of laser processing on surface roughness, hardness, surface residual stress, fracture toughness, fatigue behavior, and other related properties of metal alloys;
  • Effect of laser processing on strength and ductility of metal alloys and high entropy alloys;
  • Nanosecond, picosecond, and femtosecond pulsed laser processing of metal alloys and surface wetting enhancement;
  • Laser surface engineering for tribology;
  • Theoretical research, processing mechanism, and new ideas in laser treatment.

We look forward to receiving your contributions.

Dr. Avik Samanta
Guest Editor

Manuscript Submission Information

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Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Coatings is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2600 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • laser-based surface engineering
  • laser surface functionalization
  • laser shock processing
  • laser texturing
  • laser polishing
  • laser ablation
  • laser-processed multifunctional material

Published Papers (9 papers)

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Research

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21 pages, 11013 KiB  
Article
Macroscopic Characteristic and Properties of Inconel 625 Cladding Layers on a Cylinder Liner Based on Laser Cladding Assisted by a Steady-State Magnetic Field
by Xinlin Wang, Jing Zhu, Yongchang Tian, Jinkun Jiang and Tianmin Guan
Coatings 2024, 14(4), 438; https://doi.org/10.3390/coatings14040438 - 07 Apr 2024
Viewed by 456
Abstract
Cylinder liners, which are an vital part of marine diesel engines, are prone to damage owing to the pool working conditions of reciprocating friction and electrochemical corrosion. As a burgeoning manufacturing technology, laser cladding has a prospective application on repairing and performance enhancement [...] Read more.
Cylinder liners, which are an vital part of marine diesel engines, are prone to damage owing to the pool working conditions of reciprocating friction and electrochemical corrosion. As a burgeoning manufacturing technology, laser cladding has a prospective application on repairing and performance enhancement of cylinder liners. The performance of cladding layers on cylinder liners reported by current studies is not satisfactory. The laser cladding, assisted by the steady state magnetic field on the cylinder liner, is an effectual method to cover the shortage. However, there are few studies about that. In this study, single-track Inconel 625 cladding layers were carried out on a cylinder liner, assisted by a steady-state magnetic field. The effects of the magnetic field intensity and direction on the geometrical characteristics (width, height, penetration, and dilution ratio), microstructure, phase composition, microhardness, wear resistance, and corrosion resistance were investigated. According to the results obtained, adding a magnetic field with a small magnetic field intensity can significantly enhance the flatness, hardness, friction, wear resistance, and corrosion resistance of the cladding layer. Applying a magnetic field in the horizontal direction was conducive to improving the corrosion resistance of the sample. With the application of a vertical magnetic field, the microhardness increased, and wear resistance, as well as the flatness of the cladding layer, were improved. Full article
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22 pages, 3879 KiB  
Article
Influence of Scanning Strategy and Post-Treatment on Cracks and Mechanical Properties of Selective-Laser-Melted K438 Superalloy
by Bin Zhang, Hua Yan, Zhisheng Xia, Peilei Zhang, Haichuan Shi and Qinghua Lu
Coatings 2024, 14(4), 414; https://doi.org/10.3390/coatings14040414 - 30 Mar 2024
Viewed by 514
Abstract
The feasibility of manufacturing high-performance components with complex structures is limited due to cracks in some superalloys fabricated by selective laser melting (SLM). By controlling the main process parameters such as scanning strategy, the adverse effects of cracks can be effectively reduced. In [...] Read more.
The feasibility of manufacturing high-performance components with complex structures is limited due to cracks in some superalloys fabricated by selective laser melting (SLM). By controlling the main process parameters such as scanning strategy, the adverse effects of cracks can be effectively reduced. In this paper, the effects of two different SLM scanning strategies with island and ‘back-and-forth’ and post-heat treatment on the cracks and mechanical properties of selective-laser-melted (SLMed) K438 alloy were investigated. The results show that the SLM method of the ‘back-and-forth’ scanning strategy had better lap and interlayer rotation angles and a more uniform distribution of laser energy compared with the island scanning strategy. The residual stress accumulation was reduced and crack formation was inhibited under this scanning strategy owing to the cooling and shrinkage process. In addition, the dislocation motion was hindered by the formation of uniformly dispersed MC carbides and γ’ phases during the SLM K438 alloy process, which resulted in the density of the as-built SLMed K438 alloy being up to 99.34%, the hardness up to 9.6 Gpa, and the tensile strength up to 1309 MPa. After post-heat treatment, the fine secondary γ’ phases were precipitated and dispersed uniformly in the Ni matrix, which effectively improved the Young’s modulus and tensile strength of the alloy by dispersing the stress-concentrated area. Full article
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18 pages, 5945 KiB  
Article
Microstructure and Impact Toughness of Laser-Arc Hybrid Welded Joint of Medium-Thick TC4 Titanium Alloy
by Peng Luo, Wanxi Feng, Gang Zu, Linyin Luo and Jun Xiao
Coatings 2024, 14(4), 395; https://doi.org/10.3390/coatings14040395 - 27 Mar 2024
Viewed by 703
Abstract
This study delves into the impact toughness of medium-thick (12 mm thick) titanium alloy joints crafted through a multi-layer, multi-pass welding technique that blends laser-arc (MIG) hybrid welding technology. Microstructural scrutiny, employing optical microscopy, SEM and TEM, unveils a consistent composition across weld [...] Read more.
This study delves into the impact toughness of medium-thick (12 mm thick) titanium alloy joints crafted through a multi-layer, multi-pass welding technique that blends laser-arc (MIG) hybrid welding technology. Microstructural scrutiny, employing optical microscopy, SEM and TEM, unveils a consistent composition across weld passes, with prevailing α/α′ phases interspersed with some β phase, resulting in basket-weave structures primarily dominated by acicular α′ martensite. However, upper regions exhibit Widmanstatten microstructures, potentially undermining joint toughness. Hardness testing indicates higher values in cosmetic layers (~420 HV) compared to backing layers and bending tests manifest superior toughness in lower joint regions, attributed to smaller grain sizes induced by repetitive welding thermal cycles. Impact toughness assessment unveils diminished values in the weld metal (WM) compared to the heat-affected zone (HAZ) and base material (BM), amounting to 91.3% of the base metal’s absorption energy. This decrement is ascribed to heightened porosity in upper regions and variations in grain size and phase composition due to multi-layer, multi-pass welding. Microstructural analysis proximal to failure sites suggests one mechanism wherein crack propagation is impeded by the β phase at acute crack angles. In essence, this study not only underscores the practicality of laser-MIG hybrid welding for medium-thick TC4 alloy plates but also underscores the reliability of joint mechanical properties. Full article
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21 pages, 6716 KiB  
Article
Post-Wear Surface Morphology Assessment of Selective Laser Melting (SLM) AlSi10Mg Specimens after Heat Exposure to Different Gas Flames
by Maaz Akhtar, Muhammad Muzamil, Muhammad Samiuddin, Naser Alsaleh, Rashid Khan, Mahad Ali Khan, Joy Djuansjah, Ali Khursheed Siddiqui and Arfan Majeed
Coatings 2024, 14(3), 252; https://doi.org/10.3390/coatings14030252 - 20 Feb 2024
Cited by 1 | Viewed by 746
Abstract
The wear surface morphology of AlSi10Mg specimens, originally manufactured using selective laser melting (SLM), has been analyzed in the context of exposure to heat from gas flames. The first stage of the experimental work included the performance of surface heat-exposure on SLM-prepared specimens [...] Read more.
The wear surface morphology of AlSi10Mg specimens, originally manufactured using selective laser melting (SLM), has been analyzed in the context of exposure to heat from gas flames. The first stage of the experimental work included the performance of surface heat-exposure on SLM-prepared specimens through oxyacetylene gas welding. Gas welding was utilized with three different flames, namely; reducing, neutral, and oxidizing on the as-built specimens of SLM. The post-surface-treated specimens were subjected to pin-on-disk wear testing against fixed parameters. After the performance of wear testing at two different radii, the mass loss of each of the four types of specimens was calculated including the three specimens exposed to heat along with the as-built specimens. The results showed that the maximum amount of mass losses at 24 mm and 30 mm radii belongs to the neutral flame specimens and the least was for the as-built condition specimens. Upon analysis, the heat-exposure specimens through all three types of gas flames resulted in an increase in the amount of mass in contrast to the as-built specimens. Moreover, the morphologies of the developed wear tracks at surfaces were examined using the scanning electron microscope (SEM) for the understating of the mechanism. Full article
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12 pages, 10954 KiB  
Article
Adhesion Strength and Anti-Corrosion Performance of Ceramic Coating on Laser-Textured Aluminum Alloy
by Changfeng Fan, Xue Wang, Xiaoli Yin, Wei Huang, Yujie Da, Hao Jiang, Jingfeng Cao, Yongchao Gai and Wangwang Zhang
Coatings 2023, 13(12), 2098; https://doi.org/10.3390/coatings13122098 - 17 Dec 2023
Viewed by 951
Abstract
Laser surface texturing and micro-arc oxidation provide excellent approaches to enhance the adhesion strength and anti-corrosion performance of adhesive bonding interfaces in aluminum alloys, which can be applied in the field of automotive light weighting. Herein, micro-arc oxidation coatings were fabricated on the [...] Read more.
Laser surface texturing and micro-arc oxidation provide excellent approaches to enhance the adhesion strength and anti-corrosion performance of adhesive bonding interfaces in aluminum alloys, which can be applied in the field of automotive light weighting. Herein, micro-arc oxidation coatings were fabricated on the laser-textured aluminum surface under the voltage of 500 V for various treatment times (5 min, 15 min, 30 min, 60 min). The anti-corrosion performance of ceramic coatings on the laser-textured surface was analyzed using electrochemical measurements. The results of electrochemical measurement indicate that the coating on the sample surface presents two time constants corresponding to a dual-layer structure. The sample grown under 500 V for 60 min exhibits excellent protective performance with a value of 1.3 × 107 ohm·cm2. The adhesion strength of laser-textured ceramic coating is improved compared with the as-received substrate. The sample treated with 500 V for 30 min exhibits the highest bonding strength with a value of 52 MPa. The wider pores and bulges for the sample grown in 60 min would introduce microcracks and consequently reduce the adhesion strength. Full article
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11 pages, 7406 KiB  
Article
An Analysis of the Morphology Evolution of YG8 Cemented Carbide by Laser Ablation in the Liquid Phase
by Yujie Fan, Kang Zhao, Mengjie Hao, Jing Xia, Xiaoyan Guan and Fanghua Liu
Coatings 2023, 13(12), 2061; https://doi.org/10.3390/coatings13122061 - 09 Dec 2023
Viewed by 631
Abstract
To explore the influence of the number of laser ablations on the shape, geometry, and taper of the pitting structure by laser ablation in the liquid phase, three-dimensional confocal microscopy was used to quantitatively characterize the shape of the surface dotting texture of [...] Read more.
To explore the influence of the number of laser ablations on the shape, geometry, and taper of the pitting structure by laser ablation in the liquid phase, three-dimensional confocal microscopy was used to quantitatively characterize the shape of the surface dotting texture of YG8 cemented carbide and analyze the evolution of the morphology based on the liquid-assisted laser ablation test. The results show that the surface pitting structure of YG8 cemented carbide evolves from a micro-convexity to a crater with the increase in the number of laser ablations, and the bottom of the crater produces a convexity after 7 ablations, the shape of the crater evolves to a trapezoidal shape after 13 ablations, and the shape is stable. The size of the dot texture increases with the number of laser ablations and reaches a maximum value of 396 μm in diameter and 149 μm in depth at the 10th and 12th ablations, respectively. The taper of the dot texture showed a trend of decreasing, increasing, and then decreasing with the increase in the number of laser ablations, and the taper was stable with more than seven ablations. This study lays a theoretical foundation for the control of the dot texture morphology on the surface of YG8 cemented carbide by laser ablation in a liquid-phase environment. Full article
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10 pages, 3454 KiB  
Article
Effects of Nanosecond-Pulsed Laser Milling on the Surface Properties of Al2O3 Ceramics
by Zhaomei Xu, Zhengye Zhang, Qi Sun, Jiale Xu, Zhao Meng, Yizhi Liu and Xiankai Meng
Coatings 2022, 12(11), 1687; https://doi.org/10.3390/coatings12111687 - 06 Nov 2022
Cited by 1 | Viewed by 975
Abstract
The effect of nanosecond-pulsed laser milling on the surficial microstructure of Al2O3 ceramics is studied in this work. The macrostructure, microstructure, surface roughness, and milling depth of the ceramics are analyzed via scanning electron microscopy and confocal laser scanning microscopy. [...] Read more.
The effect of nanosecond-pulsed laser milling on the surficial microstructure of Al2O3 ceramics is studied in this work. The macrostructure, microstructure, surface roughness, and milling depth of the ceramics are analyzed via scanning electron microscopy and confocal laser scanning microscopy. The results reveal that the surface roughness and the milling depth of Al2O3 ceramics increase with increasing laser power, laser repetition rate, and scanning times. After nanosecond-pulsed laser milling, cavities as well as molten and granular solidified structures are observed on the Al2O3 ceramic surface, which indicate that the main mechanism of nanolaser milling is the melting and gasification caused by the interaction between the laser and the material. Full article
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Review

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20 pages, 3582 KiB  
Review
Progress on the Properties of Ceramic Phase-Reinforced High-Entropy Alloy Composite Coatings Produced via Laser Cladding
by Haoran Zhang, Yaowei Yong, Fuwei Wang, Yuan Liang, Lin Liu, Hong Liu and Yang Gao
Coatings 2024, 14(1), 127; https://doi.org/10.3390/coatings14010127 - 18 Jan 2024
Viewed by 1381
Abstract
The production of ceramic phase-reinforced high-entropy alloy composite coatings with excellent mechanical properties, high-temperature oxidation resistance, and corrosion resistance via laser cladding is a new hotspot in the field of surface engineering. However, as high-entropy alloys have a wide range of constituent systems [...] Read more.
The production of ceramic phase-reinforced high-entropy alloy composite coatings with excellent mechanical properties, high-temperature oxidation resistance, and corrosion resistance via laser cladding is a new hotspot in the field of surface engineering. However, as high-entropy alloys have a wide range of constituent systems and different kinds of ceramic particles are introduced in different ways that give the coatings unique microscopic organization, structure, and synthesized performance, it is necessary to review the methods of preparing ceramic phase-reinforced high-entropy alloys composite coatings via laser cladding. In this paper, the latest research progress on laser cladding technology in the preparation of ceramic phase-reinforced high-entropy alloy composite coatings is first reviewed. On this basis, the effects of ceramic particles, alloying elements, process parameters, and the microstructure and properties of the coatings are analyzed with the examples of the in situ generation method and the externally added method. Finally, research gaps and future trends are pointed out, serving as a reference for the subsequent research, application, and development of the preparation of ceramic phase-reinforced high-entropy alloy composite coatings. Full article
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23 pages, 4370 KiB  
Review
Macroscopic and Microstructural Features of Metal Thin-Wall Fabricated by Laser Material Deposition: A Review
by Xinlin Wang, Jinkun Jiang, Chengui Xia and Yang Yu
Coatings 2022, 12(8), 1104; https://doi.org/10.3390/coatings12081104 - 03 Aug 2022
Cited by 2 | Viewed by 1517
Abstract
Owing to the versatility without expanding the machine’s size, thin-wall has been widely used in high-value parts. The investigation of laser additive manufacturing (LAM), which has advantages such as high powder density, easy controllability, and excellent stability, on the fabrication of thin-wall has [...] Read more.
Owing to the versatility without expanding the machine’s size, thin-wall has been widely used in high-value parts. The investigation of laser additive manufacturing (LAM), which has advantages such as high powder density, easy controllability, and excellent stability, on the fabrication of thin-wall has drawn much attention. In this paper, the research status of macroscopic and microstructural features of metal thin-wall fabricated by LAM has been reviewed. The deposition quality was mainly focused on the effect of process parameters and especially the matching of z-increment and single deposition height. Based on the grain size and growth of columnar, the characteristics of microstructures were analyzed. Considering the structural feature of thin-wall, the effect of grain size and phases on the hardness and distribution of hardness were discussed. The effect of grain size, phases and loading direction on the tensile properties were reviewed. The distribution and modification of thermal stress were presented. Full article
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