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24 pages, 5728 KiB

Open AccessArticle

Study on Rheological Properties and Modification Mechanism of Budun Rock Asphalt/Nano-Silica Composite Modified Asphalt

by Chaojie Li, Zhenxia Li, Tengteng Guo, Yuanzhao Chen, Shangwei Jing, Jing Wang and Lihui Jin

Coatings 2024, 14(2), 226; https://doi.org/10.3390/coatings14020226 - 14 Feb 2024

Viewed by 665

Abstract

To enhance the high and low-temperature performance of asphalt materials and extend the service life of asphalt pavement, two types of external admixtures, Butonite rock asphalt, and nano-silica are added to the asphalt. By conducting dynamic shear rheological tests and bending creep stiffness [...] Read more.

To enhance the high and low-temperature performance of asphalt materials and extend the service life of asphalt pavement, two types of external admixtures, Butonite rock asphalt, and nano-silica are added to the asphalt. By conducting dynamic shear rheological tests and bending creep stiffness tests, the high and low-temperature rheological properties of Budun rock asphalt/nano-silica composite-modified asphalt were evaluated. The distribution of Budun rock asphalt and nano-silica in asphalt was studied using scanning electron microscopy and infrared spectroscopy tests, revealing the synergistic modification mechanism of Budun rock asphalt and nano-silica. The results show that the optimal dosage of Butonite rock asphalt and nano-silica composite-modified asphalt is 25% and 5%, respectively. At this dosage, the rutting factor G*/sinδ of composite-modified asphalt at 82 °C Compared with the matrix asphalt, the frequency main curve of Budun rock asphalt/nano-silica composite-modified asphalt is higher than that of the matrix asphalt and nano-silica-modified asphalt by 4 kPa. The creep modulus S at −18 °C decreases by 117.2 MPa, indicating that the high-temperature performance, low-temperature performance, and temperature sensitivity of Budun rock asphalt/nano-silica composite-modified asphalt are significantly improved compared to the matrix asphalt; The distribution of nano-silica particles in Budun rock asphalt/nano-silica composite-modified asphalt is uniform, and together with Budun rock asphalt, it forms a stable three-dimensional network skeleton structure; Budun rock asphalt/nano-silica composite-modified asphalt has generated new functional groups, and the blending process is mainly based on physical reactions, supplemented by weak chemical reactions. Full article

(This article belongs to the Special Issue Recent Development in Novel Green Asphalt Materials for Pavement)

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19 pages, 10051 KiB

Open AccessArticle

Study on the Performance of SBS/Polyphosphoric Acid Composite Modified Asphalt

by Chaojie Li, Zhenxia Li, Tengteng Guo, Yuanzhao Chen, Qi Liu, Jing Wang and Lihui Jin

Coatings 2024, 14(1), 72; https://doi.org/10.3390/coatings14010072 - 04 Jan 2024

Viewed by 760

Abstract

To address the issue of bad compatibility between a single polymer modifier and asphalt and high preparation cost, the composite modified asphalt with polyphosphoric acid (PPA) and SBS as a modifier was prepared. Basic properties, viscosity characteristics, high-temperature and low-temperature rheological performance, and [...] Read more.

To address the issue of bad compatibility between a single polymer modifier and asphalt and high preparation cost, the composite modified asphalt with polyphosphoric acid (PPA) and SBS as a modifier was prepared. Basic properties, viscosity characteristics, high-temperature and low-temperature rheological performance, and aging-resistant performance of SBS/PPA composite modified asphalt were comprehensively evaluated, and the best content of PPA was obtained through the experimental results below. By performing an infrared spectrum test and a scanning electron microscope test, structural changes and modifying mechanisms of composite modified asphalt were analyzed. The results indicate the optimal PPA content is 0.75%. After adding PPA, the penetration and ductility of composite modified asphalt were reduced, while the softening point increased. At 135 °C, the viscosity was 1.2 times that of SBS modified asphalt. The average weight loss ratio was 0.163%. When the content of PPA was 0.75% and 1%, the rutting factor increased significantly. Therefore, PPA can not only improve the thermal oxidation aging resistance of asphalt, it can also improve the shear resistance, high-temperature performance, and temperature sensitivity of asphalt. Between 1027 and 1150 cm⁻¹, the composite modified asphalt forms a new absorption peak, and from 1610 cm⁻¹, the absorption peak presents an upward trend, suggesting that PPA reacts chemically with asphalt, produces the new substance, and also increases a large number of hydrocarbon components with chain structure. The surface appearance of the compound modified asphalt gradually presents a smooth wrinkle state due to the increase of PPA, so the issue of easy segregation of SBS in asphalt is improved. Full article

(This article belongs to the Special Issue Recent Development in Novel Green Asphalt Materials for Pavement)

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17 pages, 4127 KiB

Open AccessArticle

Enhancing the Efficiency of Ice-Resistant Materials in Asphalt Road Surfaces: A Comprehensive Performance Analysis

by Xijuan Zhao, Yemao Zhang and Mulian Zheng

Coatings 2024, 14(1), 37; https://doi.org/10.3390/coatings14010037 - 27 Dec 2023

Viewed by 683

Abstract

This study addresses the critical issue of traffic safety in winter, particularly focusing on the challenges posed by ice and snow on roads. Traditional methods of snow and ice removal are often labor-intensive, inefficient, and environmentally harmful. The objective is to develop a [...] Read more.

This study addresses the critical issue of traffic safety in winter, particularly focusing on the challenges posed by ice and snow on roads. Traditional methods of snow and ice removal are often labor-intensive, inefficient, and environmentally harmful. The objective is to develop a more effective solution for asphalt pavement deicing. Inspired by the anti-icing coating technology used in high-voltage conductors, this research develops an ice-suppressing material designed to reduce the adhesion between snow, ice, and pavement surfaces. The material’s performance is evaluated in terms of deicing efficiency, durability, adhesive properties, and its impact on pavement performance. Test results demonstrate that the developed ice-suppressing material significantly reduces the adhesion between the ice layer and the pavement, facilitating easier removal. This study concludes that the developed ice-suppressing material significantly enhances deicing efficiency on asphalt pavements. It exhibits strong hydrophobic properties, as evidenced by increased water droplet contact angles on coated surfaces (99.5° to 83.3°) compared to clean glass slides (39.2° to 29°). This hydrophobicity effectively reduces ice adhesion, decreasing tensile and shear strength of the ice layer by 38.2% and 63.6%, respectively. Additionally, the material demonstrates superior ice-melting capabilities in sub-zero temperatures, with coated ice cubes showing a higher mass reduction rate than uncoated ones. Importantly, its slow-release nature ensures sustained deicing performance over multiple cycles, maintaining effectiveness after seven test cycles. This study introduces an innovative ice-suppressing material that not only improves the efficiency and environmental impact of deicing methods but also contributes to enhancing road safety in winter conditions. The material’s novel composition and sustained effectiveness present a significant advancement in the field of winter road maintenance. Full article

(This article belongs to the Special Issue Recent Development in Novel Green Asphalt Materials for Pavement)

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19 pages, 10726 KiB

Open AccessArticle

Study on the Performance of Nano-Zinc Oxide/Basalt Fiber Composite Modified Asphalt and Mixture

by Chaojie Li, Zhenxia Li, Tengteng Guo, Yuanzhao Chen, Junying Ma, Jing Wang and Lihui Jin

Coatings 2024, 14(1), 23; https://doi.org/10.3390/coatings14010023 - 25 Dec 2023

Viewed by 637

Abstract

In order to improve the service quality of roads and resolve the problem of defects in the conventional asphalt pavement in service, this paper uses a 5.3% aluminate coupling agent to modify the surface of nano-ZnO and prepares a composite-modified asphalt with nano-ZnO [...] Read more.

In order to improve the service quality of roads and resolve the problem of defects in the conventional asphalt pavement in service, this paper uses a 5.3% aluminate coupling agent to modify the surface of nano-ZnO and prepares a composite-modified asphalt with nano-ZnO and basalt fiber (BF) as modifiers. First, the basic performance of different types of asphalt was investigated by means of a rotary film oven experiment. Then, a dynamic shear rheology experiment was carried out to analyze the high-temperature anti-rutting performance of the composite-modified asphalt at different temperatures and frequencies. Then, using a bending creep stiffness test, the low-temperature properties of the composite-modified asphalt were investigated. Finally, the microstructure and modification mechanisms of the composite-modified asphalt were analyzed with scanning electron microscopy and infrared spectroscopy. The results indicate that the anti-aging performance of the nano-ZnO/BF composite-modified asphalt is significantly improved after adding fibers to the modified asphalt. The average mass loss ratio is only 0.192%. At 46 °C, the rutting coefficient of the composite-modified asphalt was increased by 62.3%. The frequency master curve is always at the highest position and continues to rise, indicating a significant improvement in the high-temperature anti-rutting performance of the composite-modified asphalt. At 24 °C, the creep stiffness modulus S value of the composite-modified asphalt increased by 24.9%; moreover, there is no obvious effect of improving low temperature, but the variation range of creep tangent slope m of the modified asphalt after aging is decreased, which further shows that the addition of a modifier can decrease the influence of aging on asphalt. Nanoparticles are uniformly dispersed in the asphalt and form a three-dimensional interconnected structure with BF, which effectively improves the overall performance of the asphalt. Nano-ZnO and fibers have weak chemical reactions in matrix asphalt, but they are physically dispersed and compatible. Full article

(This article belongs to the Special Issue Recent Development in Novel Green Asphalt Materials for Pavement)

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17 pages, 4769 KiB

Open AccessArticle

Analyzing Pore Evolution Characteristics in Cementitious Materials Using a Plane Distribution Model

by Yezhen Yuan, Zhe He, Kaimin Niu, Bo Tian, Liangliang Chen, Wei Bai, Shaopeng Zheng and Guoman Yu

Coatings 2023, 13(12), 2023; https://doi.org/10.3390/coatings13122023 - 29 Nov 2023

Viewed by 706

Abstract

This research aims to analyze the distribution and evolution of pores within the planar structure of cement-based materials. Utilizing digital imaging methods, a model for pore plane distribution was established, and the evolutionary patterns of both total pore numbers and varying pore sizes [...] Read more.

This research aims to analyze the distribution and evolution of pores within the planar structure of cement-based materials. Utilizing digital imaging methods, a model for pore plane distribution was established, and the evolutionary patterns of both total pore numbers and varying pore sizes in cement-based materials were investigated. The research introduced an innovative experimental method for analyzing pore distribution within cement-based planar structures. Additionally, a hybrid method was proposed, combining automated image binarization thresholding with manual comparative analysis, thereby enhancing the feasibility of comparative research. Pores were categorized into four distinct sizes: tiny pores (5–200 μm), small pores (200–500 μm), medium pores (500–1000 μm), and large pores (>1000 μm). Areas with apertures <5 μm were classified as dense areas. The findings indicated that the overall number of pores in cement-based materials increased due to the influence of styrene butadiene latex additives. However, at a 15% dosage, the rate of pore formation reached an inflection point, confirming that various factors, such as styrene butadiene latex, air bubbles, and the cement-based material itself, collectively influenced pore formation. The research also demonstrated that styrene butadiene latex affected the four categorized pore sizes differently. Importantly, a higher latex dosage did not necessarily lead to a proportional increase in pore content. Pore content was influenced by multiple factors and exhibited different distribution patterns. The number of micropores, although relatively small, gradually increased with higher latex dosages, while small and medium pores generally showed an upward trend. At a 10% latex dosage, both small and medium pores reached a turning point in their rate of increase. Large pores also exhibited a general increase, peaking at a latex dosage of 10%. It was confirmed that both the total pore volume and the content of micropores were critical factors in determining the mechanical properties of cementitious materials. Higher porosity and micropore content generally weakened mechanical performance. However, at a small latex dosage, there was an improvement in flexural strength. When the latex dosage reached 15%, the total pore and micropore content declined, resulting in a balanced increase in flexural strength and a mitigated decline in compressive strength. This study offers valuable insights into the evolution of total pore volume and the content of pores of various sizes, providing a theoretical basis for the meticulous selection of additive types and dosages from a microscopic perspective. Full article

(This article belongs to the Special Issue Recent Development in Novel Green Asphalt Materials for Pavement)

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21 pages, 5546 KiB

Open AccessArticle

Study on the Performance and Modification Mechanism of Polyphosphoric Acid (PPA)/Styrene–Butadiene–Styrene (SBS) Composite Modified Asphalt

by Xiangjie Niu, Yuanzhao Chen, Zhenxia Li, Tengteng Guo, Jing Wang and Lihui Jin

Coatings 2023, 13(12), 2003; https://doi.org/10.3390/coatings13122003 - 25 Nov 2023

Viewed by 690

Abstract

In order to address the high preparation cost of styrene–butadiene–styrene block copolymer (SBS) modified asphalt, four kinds of polyphosphoric acid (PPA) content (0%, 0.5%, 0.75%, and 1% PPA by weight of the matrix asphalt) were selected to prepare composite modified asphalt with better [...] Read more.

In order to address the high preparation cost of styrene–butadiene–styrene block copolymer (SBS) modified asphalt, four kinds of polyphosphoric acid (PPA) content (0%, 0.5%, 0.75%, and 1% PPA by weight of the matrix asphalt) were selected to prepare composite modified asphalt with better high-temperature performance. The physical properties of composite modified asphalt were evaluated by conventional performance tests. The rheological properties of composite modified asphalt were evaluated by dynamic shear rheometer (DSR) test and bending beam rheometer (BBR) test. The synergistic modification mechanism of PPA and SBS was revealed by the Fourier transform infrared spectroscopy test. The results show that with the increase of PPA content, the penetration of PPA/SBS composite modified asphalt is reduced by 20.92%, 25.07% and 28.94%, respectively, compared with matrix asphalt, and the softening point is increased by 5.46%, 22.69% and 34.03%, respectively. In addition, PPA can improve the thermal oxidative aging resistance of asphalt. PPA can improve the shear resistance, high-temperature performance and temperature sensitivity of asphalt. At 82 °C, compared with SBS modified asphalt, the phase angle of PPA/SBS composite modified asphalt can be decreased by 8.63%, 13.23% and 19.24%, respectively, and G*/sinδ can be increased by 41.97%, 67.62% and 70.97%, respectively. SBS mainly exists in asphalt in the form of physical blending, and PPA has a new chemical reaction with asphalt, which increases the macromolecules and chain hydrocarbon components in asphalt, and the macroscopic performance is the improvement of high-temperature performance of asphalt. However, PPA has a negative effect on the low-temperature performance of the SBS modified asphalt. Full article

(This article belongs to the Special Issue Recent Development in Novel Green Asphalt Materials for Pavement)

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20 pages, 6228 KiB

Open AccessArticle

Evaluation of Fume Suppression, Viscosity-Retarding, and Rheological Properties of Eco-Friendly High-Viscosity Modified Asphalt

by Weidong Ning, Guoqiang Sun, Kexin Qiu, Xulai Jiang, Chunze Wang and Ruiqi Zhao

Coatings 2023, 13(9), 1497; https://doi.org/10.3390/coatings13091497 - 24 Aug 2023

Cited by 1 | Viewed by 796

Abstract

In order to address the issues of high viscosity and excessive fume exhaust associated with high-viscosity modified asphalt (HVMA), the objective of this study was to develop an eco-friendly HVMA by incorporating fume suppressants and viscosity-retarding agents (VRAs). To begin with, desulfurization rubber [...] Read more.

In order to address the issues of high viscosity and excessive fume exhaust associated with high-viscosity modified asphalt (HVMA), the objective of this study was to develop an eco-friendly HVMA by incorporating fume suppressants and viscosity-retarding agents (VRAs). To begin with, desulfurization rubber powder (DRP) was utilized as a modifier, and fume suppressants, including activated carbon, a chemical reaction fume suppressant, and a composite fume suppressant combining activated carbon and chemical reaction fume suppressant were added to the HVMA separately. The fume suppression effect and odor level were observed to determine the optimal fume suppressant composition for this study. Based on these observations, an area integration method was proposed, utilizing rotational viscosity testing and temperature sweeping experiments, evaluating the viscosity-retarding effect and mixing temperature when different amounts of Sasobit VRA, Evotherm3G VRA, and a composite VRA of Sasobit and Evotherm3G were added to the HVMA. This approach aimed to identify the eco-friendly HVMA with the most effective fume suppression and viscosity-retarding abilities. Furthermore, the morphology and rheological properties of the eco-friendly HVMA were examined through fluorescence microscopy, zero shear viscosity test, multiple stress creep recovery analysis, liner amplitude sweep test, and frequency sweep test. The results demonstrated that the HVMA formulation consisting of 15% DRP and 1% composite fume suppressant exhibited a satisfactory fume suppression effect and odor level. Based on this, the HVMA formulation containing 0.6% Evotherm3G and 3% Sasobit VRAs displayed the best viscosity-retarding effect while reducing the mixing temperature. Moreover, when compared to common HVMA, the eco-friendly HVMA exhibited excellent high-temperature resistance, successfully accomplishing the dual objectives of ecological friendliness and superior performance. Full article

(This article belongs to the Special Issue Recent Development in Novel Green Asphalt Materials for Pavement)

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14 pages, 3939 KiB

Open AccessArticle

Long-Term Performance Analysis of Epoxy Resin Ultra-Thin Wearing Course Overlay on Cement Concrete Pavement

by Xiaoguang Zheng, Yajie Chen, Wanwan Xu, Zhen Zhang, Guoqiang Sun and Tao Wang

Coatings 2023, 13(8), 1455; https://doi.org/10.3390/coatings13081455 - 18 Aug 2023

Cited by 1 | Viewed by 1058

Abstract

The overall rigidity of the cement concrete pavement is high, but there are defects such as easy cracking and insufficient anti-slip performance. The epoxy resin ultra-thin wearing course overlay can effectively solve these issues. However, there is still a lack of knowledge about [...] Read more.

The overall rigidity of the cement concrete pavement is high, but there are defects such as easy cracking and insufficient anti-slip performance. The epoxy resin ultra-thin wearing course overlay can effectively solve these issues. However, there is still a lack of knowledge about the long-term performance of epoxy resin ultra-thin wearing course overlay on cement concrete pavement. Therefore, this article analyzed the interlayer adhesion and durability of epoxy resin ultra-thin wearing course overlay through the Hamburg rutting test and a series of shear tests under damp heat, thermal oxygen aging, and ultraviolet (UV) aging conditions. Shear test results indicated that the shear performance of epoxy resin overlay grew with the increase in epoxy resin content and was severely affected by high temperature, and the optimal content was set as 3.4 kg/m². The Hamburg rutting test results showed that the epoxy resin overlay exhibited satisfactory high-temperature performance and water resistance. For the damp heat effect, it was revealed that damp heat led to more significant shear strength loss compared with the overlay specimens without damp heat. The water immersion caused the shear strength decline due to the water damage to the overlay interface. As for the thermal oxygen aging effect, it was reflected that the short-term thermal oxygen aging had a minor impact on the shear performance of the epoxy resin overlay. However, with the increase in thermal oxygen aging duration, the shear strength of the epoxy resin overlay significantly decreased due to the aging of epoxy resin binders. Regarding the UV aging impact, it was also found that the shear performance of the epoxy resin overlay rapidly decreased as the UV aging duration grew whether at 20 °C or 60 °C. Moreover, UV aging led to a more significant impact on the shear performance of the epoxy resin overlay than thermal oxygen aging. Full article

(This article belongs to the Special Issue Recent Development in Novel Green Asphalt Materials for Pavement)

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15 pages, 3092 KiB

Open AccessArticle

A Comparative Study for Creep and Recovery Behavior Characterization of Modified Bitumens Using the MSCR Test

by Guodong Zeng, Jianjing Zhang, Hongming Huang, Xin Xiao and Chuanqi Yan

Coatings 2023, 13(8), 1445; https://doi.org/10.3390/coatings13081445 - 16 Aug 2023

Viewed by 779

Abstract

In recent decades, the application of modified bitumens has experienced tremendous growth. However, due to the varying modification mechanism of different modifiers, the creep and recovery properties of modified bitumen have not been comprehensively understood. This study aims to evaluate the creep and [...] Read more.

In recent decades, the application of modified bitumens has experienced tremendous growth. However, due to the varying modification mechanism of different modifiers, the creep and recovery properties of modified bitumen have not been comprehensively understood. This study aims to evaluate the creep and recovery properties of several representative modified bitumens using the multi-stress creep recovery (MSCR) test. The MSCR test can highlight the unique delayed elasticity of modified bitumen and it uses a high stress level, which is more comparable to the field. In particular, this test also aims to identify the effects of different aging conditions. To do so, a total of 15 bitumens, including 7 elastomeric-modified bitumens, 5 non-elastomeric-modified bitumens, and 3 plain bitumens, were prepared and examined. Furthermore, 10 different aging conditions were considered. The results suggest that the generation mechanism of elasticity varies for different modified bitumens. There are two types of elasticities, which are energy elasticity and entropy elasticity, and their differences need more attention in the road bitumen material community. Aging changes the percentages of contributions from energy elasticity and entropy elasticity to the bitumen’s overall recovery performance. The increase in “bad” energy elasticity may compensate for part of the “good” entropy elasticity loss, but overall, the bitumen’s recovery rate is decreasing and the ratio of energy elasticity is increasing, which might hinder the bitumen’s road performance. Full article

(This article belongs to the Special Issue Recent Development in Novel Green Asphalt Materials for Pavement)

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20 pages, 8698 KiB

Open AccessArticle

Rheological Properties of Composite Inorganic Micropowder Asphalt Mastic

by Tengteng Guo, Haijun Chen, Deqing Tang, Shengquan Ding, Chaohui Wang, Decai Wang, Yuanzhao Chen and Zhenxia Li

Coatings 2023, 13(6), 1068; https://doi.org/10.3390/coatings13061068 - 08 Jun 2023

Viewed by 890

Abstract

Graphene Tourmaline Composite Micropowder (hereinafter referred to as GTCM) modified asphalt was prepared by the ball milling method. The effects of different temperatures and different frequencies on the high-temperature performance of composite-modified asphalt were evaluated by dynamic shear rheological test, and the viscoelastic [...] Read more.

Graphene Tourmaline Composite Micropowder (hereinafter referred to as GTCM) modified asphalt was prepared by the ball milling method. The effects of different temperatures and different frequencies on the high-temperature performance of composite-modified asphalt were evaluated by dynamic shear rheological test, and the viscoelastic properties of composite-modified asphalt under different stresses and different temperatures were analyzed. The low-temperature rheological properties of GTCM-modified asphalt were analyzed by bending beam rheological test, and its mechanism was analyzed by Fourier transform infrared spectroscopy (FTIR) test. The results show that the temperature sensitivity and anti-aging resistance of GTCM-modified asphalt are significantly higher than that of tourmaline-modified asphalt. The improvement effect gradually increases with the increase in graphene powder content, and its addition does not change the viscoelastic properties of asphalt. The complex shear modulus and phase angle of GTCM-modified asphalt at appropriate temperatures are more conducive to tourmaline-modified asphalt and matrix asphalt, which can improve the rutting resistance of asphalt. In the same type, with the increase in composite modified micropowder content, the rutting resistance of modified asphalt is better. The improvement of rutting resistance of GTCM-0.5, GTCM-1.0 and GTCM-1.5-modified asphalt can reach 12.95%, 10.12% and 24.25%, respectively; the improvement range is more complicated due to temperature and frequency changes. The GTCM-modified asphalt has good low-temperature crack resistance. The creep stiffness modulus of GTCM-modified asphalt decreases with the increase in load time under different types and dosages, and its stiffness modulus is smaller than that of tourmaline-modified asphalt and mineral powder asphalt mastic. The creep rate increases with the extension of load time, which is greater than that of tourmaline-modified asphalt and mineral powder asphalt mastic. When the load was 60 s, the creep stiffness modulus of GTCM-0.5, GTCM-1.0 and GTCM-1.5-modified asphalt decreased by 5.75%, 6.97% and 13.73%, respectively, and the creep rate increased by 1.37%, 2.52% and 4.35%, respectively. After adding GTCM or tourmaline to the matrix asphalt, no new functional groups were produced due to the chemical reaction with the asphalt. Full article

(This article belongs to the Special Issue Recent Development in Novel Green Asphalt Materials for Pavement)

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16 pages, 16236 KiB

Open AccessArticle

Mechanism of Sodium Dodecyl Diphenyl Ether Disulfonate Filled Hydrotalcite Inhibiting the Photo-Degradation of Polyvinyl Chloride under Different Ranges of Ultraviolet Wavelength Irradiation

by Enguo Zhou, Yuan Liu, Huajin Yuan, Xiaoling Cheng, Yuanhong Zhong, Jiebing He and Xi Lu

Coatings 2023, 13(6), 985; https://doi.org/10.3390/coatings13060985 - 25 May 2023

Cited by 1 | Viewed by 1001

Abstract

This content introduces a novel Ultraviolet (UV)-shielding material, Zn₂Al-MADS-LDH (MADS-LDH), which was synthesized through co-precipitation method to insert sodium dodecyl diphenyl ether disulfonate (MADS) into the interlayer of Zn₂Al-LDH layered double hydroxide (LDH), to improve the photoaging resistance of [...] Read more.

This content introduces a novel Ultraviolet (UV)-shielding material, Zn₂Al-MADS-LDH (MADS-LDH), which was synthesized through co-precipitation method to insert sodium dodecyl diphenyl ether disulfonate (MADS) into the interlayer of Zn₂Al-LDH layered double hydroxide (LDH), to improve the photoaging resistance of polyvinyl chloride (PVC). The characterization results indicated that MADS-LDH had a host-guest interaction between the LDH host layer and MADS guest anion, and it exhibited superior UV absorption capabilities than Zn₂Al-CO₃-LDH (CO₃-LDH) and a broader absorption spectrum compared to MADS. A series of LDHs/PVC film composite materials containing LDHs nanosheets were prepared by incorporating the prepared LDHs into a PVC matrix via a solvent casting method. As expected, the MADS-LDH/PVC film composite materials exhibited enhanced photoaging resistance. The results of photoaging tests indicated that MADS-LDH inhibits the rate of carbonyl generation during photoaging of MADS-LDH/PVC film composite materials, resulting in a decrease in the carbonyl index (ΔCl) and relative degradation rate (RDR) compared to pristine PVC film and CO₃-LDH/PVC film composite materials. Furthermore, the study evaluated the influence of different UV light wavelength ranges, such as UVB (280~315 nm), UVC (200~280 nm), and UV (200~400 nm), on the aging performance of PVC film and LDHs/PVC film composite materials. The results demonstrated that UV had the highest aging effect on PVC composite films, followed by UVC and UVB. Therefore, the MADS-LDH is a highly efficient and promising UV-shielding material with excellent potential for wide applications in the field of PVC. Full article

(This article belongs to the Special Issue Recent Development in Novel Green Asphalt Materials for Pavement)

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28 pages, 9001 KiB

Open AccessArticle

Sprayed-Polyurea-Modified Asphalt: Optimal Preparation Parameters, Rheological Properties and Thermal Properties

by Qinyuan Peng, Xiaolong Sun, Zhisheng Liu, Jiao Jin, Huayang Yu and Yingmei Yin

Coatings 2023, 13(3), 544; https://doi.org/10.3390/coatings13030544 - 02 Mar 2023

Cited by 4 | Viewed by 1314

Abstract

For promoting modifying application of sprayed polyurea (SPUA) in asphalt pavement materials, the effects of sprayed polyurea materials on high-temperature and fatigue performance of asphalt binders were investigated from different aspects. First, the optimal preparation parameters of sprayed-polyurea-modified asphalt binders (SPMAs) were determined [...] Read more.

For promoting modifying application of sprayed polyurea (SPUA) in asphalt pavement materials, the effects of sprayed polyurea materials on high-temperature and fatigue performance of asphalt binders were investigated from different aspects. First, the optimal preparation parameters of sprayed-polyurea-modified asphalt binders (SPMAs) were determined by designing an orthogonal test. Then, the high-temperature and fatigue properties of sprayed-polyurea-modified asphalt binders with different contents were characterized by rheological testing methods, including Brookfield rotary viscosity (RV) test, performance grading (PG) test, multiple stress creep recover (MSCR) test, linear amplitude sweep (LAS) test and time sweeping (TS) test. Finally, the thermal properties of the asphalt binders were analyzed by differential scanning calorimetry (DSC) test. The results showed that the optimum preparation parameters were determined by the extreme difference analysis method and analysis of variance (ANOVA) method, and the shearing time was 40 min, the shearing rate was 6000 rpm and the shearing temperature was 150 °C. Sprayed polyurea positively affected high-temperature performance of asphalt binders and could improve fatigue resistance of asphalt binders. Moreover, the Brookfield rotary viscosity test, multiple stress creep recover test and linear amplitude sweep test had high sensitivity to the performance of sprayed-polyurea-modified asphalt binder, which could help to distinguish the effect of sprayed polyurea dosing on performance of asphalt binders accurately. The differential scanning calorimetry test showed that sprayed polyurea was beneficial to high-temperature stability of asphalt binders, which explains the reason why sprayed-polyurea-modified asphalt binders have excellent high-temperature performance from a microscopic perspective. Full article

(This article belongs to the Special Issue Recent Development in Novel Green Asphalt Materials for Pavement)

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21 pages, 2969 KiB

Open AccessArticle

Experimental Study on Mechanism, Aging and Fatigue Performance of Warm Mixing Speed Melting SBS Modified Asphalt Binders

by Yazhou Zhuang, Jinchao Yue, Bo Men, Guoqi Tang and Riran Wang

Coatings 2023, 13(2), 311; https://doi.org/10.3390/coatings13020311 - 30 Jan 2023

Cited by 4 | Viewed by 1320

Abstract

In this study, two kinds of quick melting modifier SBS-T and SBS-W, as well as the traditional SBS modifier, were used in the optimization design of asphalt binders. The changes in material structure and fatigue properties of three polymer-modified asphalt after adding 3% [...] Read more.

In this study, two kinds of quick melting modifier SBS-T and SBS-W, as well as the traditional SBS modifier, were used in the optimization design of asphalt binders. The changes in material structure and fatigue properties of three polymer-modified asphalt after adding 3% Sasobit to warm mix agent were investigated. The feasibility of SBS-T and SBS-W in asphalt binder was discussed from the modification mechanism and fatigue properties. In order to reveal the modification mechanism, the interaction mechanism between the fast-melting SBS modifier and the base asphalt was characterized by Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The temperature sensitivity and viscoelastic properties of SBS-T and SBS-W modified binders were determined by frequency scanning (FS). The fatigue properties of SBS-T and SBS-W modified binders were tested by linear amplitude scanning (LAS). The results of FTIR showed that there was no chemical reaction between the SBS-T and SBS-W and the base asphalt. XRD results showed that SBS-W-modified asphalt has stronger fluidity. The results of FS and LAS showed that the asphalt binder with Sasobit has good stiffness and elastic recovery ability, and the same SBS-T and SBS-W have better temperature sensitivity and deformation resistance. In addition, the fatigue life of asphalt binder under the linear viscoelastic continuous damage theory is increased 3.9 times by SBS-W. Full article

(This article belongs to the Special Issue Recent Development in Novel Green Asphalt Materials for Pavement)

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