Agro-Waste Bean Fibers as Reinforce Materials for Polycaprolactone Composites
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Fiber Fractionation
- Wax extraction;
- Pectin extraction;
- Lignin extraction;
- Cellulose and Hemicellulose extraction.
2.3. PCL Composite Preparation
2.4. Characterization Methods
3. Results and Discussion
3.1. Analyses of Fibers: Chemical Fractionation and Characterizations
3.2. Preparation of Composites
3.2.1. Morphological Properties of Composites
3.2.2. Thermal Properties of Composites
- Hindering crystallization by reducing chain mobility makes reorganization into ordered structures harder [34].
3.2.3. Mechanical Analyses
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Component | Borlotti Beans (% wt) * | Green Beans (% wt) * |
---|---|---|
Waxes | 5 | 8 |
Pectin | 11 | 27 |
Lignin | 9 | 6 |
Hemicellulose | 68 | 7 |
Cellulose | 7 | 52 |
From TGA | From DTG | ||||
---|---|---|---|---|---|
Samples | Water Loss % | Tonset (°C) | Residue % | Tmax1 (°C) | Tmax2 (°C) |
G1 | 8.0 | 235.4 | 27.9 | 252.8 | 310.1 |
G1-Soap | 10.4 | 233.0 | 23.5 | 252.3 | 308.8 |
G1-Tol-EtOH | 8.0 | 232.6 | 22.6 | 252.1 | 309.4 |
G1-Oxa | 7.4 | 284.2 | 16.7 | - | 346.2 |
G1-Buffer | 7.0 | 284.0 | 18.1 | - | 349.3 |
G1-KOH | 8.0 | 266.9 | 23.6 | - | 326.7 |
From TGA | From DTG | ||||||
---|---|---|---|---|---|---|---|
Samples | Water Loss % | Tonset (°C) | Residue % | Tmax1 (°C) | Tmax2 (°C) | Tmax3 (°C) | Tmax4 (°C) |
B1 | 5.2 | 267.3 | 26.6 | 261.2 | 286.4 | - | 325.7 |
B1-Soap | 12.0 | 276.2 | 17.9 | 244.3 | - | 308.2 | 341.2 |
B1-Tol-EtOH | 9.7 | 280.6 | 16.5 | 243.1 | 303.4 | 309.6 | 340.8 |
B1-Oxa | 10.7 | 226.0 | 24.7 | 226.0 | 293.2 | - | 345.9 |
B1-Buffer | 9.7 | 273.1 | 21.3 | 277.8 | 292.9 | - | - |
From 1° Cooling | From 2° Heating | ||||||
---|---|---|---|---|---|---|---|
Samples | Tc (°C) | ΔHc (J/g) | Tg (°C) | ΔCp (J/g °C) | Tm (°C) | ΔHm (J/g) | χ% * |
PCL | 32.6 | −63.4 | −64.0 | 0.085 | 57.4 | 66.7 | 49.4 |
PCL5B1 | 28.4 | −78.3 | −64.7 | 0.14 | 56.9 | 92.2 | 71.9 |
PCL40B1 | 29.4 | −48.9 | −64.5 | 0.10 | 56.3 | 58.0 | 71.6 |
PCL5G1 | 29.0 | −76.5 | −64.6 | 0.11 | 56.6 | 84.3 | 65.7 |
PCL40G1 | 32.3 | −44.7 | −65.0 | 0.12 | 56.7 | 51.5 | 63.6 |
From TGA | From DTG | |||||||
---|---|---|---|---|---|---|---|---|
Samples | Tonset (°C) | T5% (°C) | T30% (°C) | T50% (°C) | T80% (°C) | Residue % | Tmax (°C) * | Other Peak (°C) |
PCL ** | 395.3 | 386.5 | 408.1 | 417.1 | 431.2 | 1.1 | 418.0 | - |
PCL5B1 | 264.2 | 355.6 | 403.4 | 413.0 | 426.8 | 2.1 | 417.1 | - |
PCL40B1 | 263.6 | 233.9 | 367.3 | 397.0 | 418.0 | 9.9 | 410.0 | 287.5 |
PCL5G1 | 239.2 | 340.9 | 397.2 | 407.3 | 420.9 | 1.2 | 411.6 | - |
PCL40G1 | 239.2 | 237.2 | 362.8 | 386.1 | 409.2 | 11.4 | 395.1 | 256.0 308.0 |
Samples | Young’s Modulus (MPa) | Elongation at Break (%) | Tensile Strength (MPa) |
---|---|---|---|
PCL | 600 ± 20 | 590 ± 90 | 47 ± 8 |
PCL5B1 | 600 ± 30 | 140 ± 90 | 15 ± 3 |
PCL40B1 | 1010 ± 40 | 25 ± 8 | 2.1 ± 0.8 |
PCL5G1 | 650 ± 70 | 30 ± 10 | 12 ± 4 |
PCL40G1 | 1050 ± 50 | 4.2 ± 0.9 | 5.1 ± 0.6 |
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De Monte, C.; Arrighetti, L.; Ricci, L.; Civello, A.; Bronco, S. Agro-Waste Bean Fibers as Reinforce Materials for Polycaprolactone Composites. Compounds 2023, 3, 504-520. https://doi.org/10.3390/compounds3030036
De Monte C, Arrighetti L, Ricci L, Civello A, Bronco S. Agro-Waste Bean Fibers as Reinforce Materials for Polycaprolactone Composites. Compounds. 2023; 3(3):504-520. https://doi.org/10.3390/compounds3030036
Chicago/Turabian StyleDe Monte, Cristina, Leonardo Arrighetti, Lucia Ricci, Alessandra Civello, and Simona Bronco. 2023. "Agro-Waste Bean Fibers as Reinforce Materials for Polycaprolactone Composites" Compounds 3, no. 3: 504-520. https://doi.org/10.3390/compounds3030036