Understanding and Mitigating the Dissolution and Delamination Issues Encountered with High-Voltage LiNi0.5Mn1.5O4
Abstract
:1. Introduction
2. Experimental
2.1. Electrolyte and Electrodes
2.2. Electrochemical Measurement
2.3. Soaking Test
2.3.1. Electrode Soaking Test
2.3.2. Powder Soaking Test
2.3.3. Additive Soaking Test
2.4. Characterizations of Electrode and Electrolyte
2.4.1. 1H and 19F Nuclear Magnetic Resonance (NMR) Spectroscopy
2.4.2. X-ray Photoelectron Spectra (XPS) Characterization
2.4.3. Inductively Coupled Plasma-Mass Spectra (ICP-MS) Characterization
2.4.4. Scanning Electron Microscopy (SEM) Characterization
2.4.5. Powder X-ray Diffraction (XRD) Characterization
3. Results and Discussions
3.1. Observation of Delamination
3.2. Mechanism of Transition Metal Dissolution in LNMO Cells When Stored in Gen2
3.2.1. Comparison of Vessels for the Soaking Test: Glass vs. PE Vials
3.2.2. Gen2 Soaking with Various LNMO and NMC532 Laminates
3.2.3. Gen2 Soaking with Different TMO Powders
3.3. Additives Effect in Mitigating TM Dissolution
3.3.1. Gen2 Soaking with LNMO Electrodes Adding Additives
3.3.2. Additives Cycling Results
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Electrode | Active Materials (wt.%) | Timcal C45 (wt.%) | PVDF (wt.%) | SWCNT (wt.%) | Carbon Coated Al | Container Type | Color Change Observation | Delamination Observation | |
---|---|---|---|---|---|---|---|---|---|
1 | NMC532 | 90 | 5 | 5 | \ | \ | Glass | No | No |
2 | LNMO | 90 | 6 | 4 (Solvay) | \ | \ | PE | No | No |
3 | LNMO | 90 | 6 | 4 (Solvay) | \ | \ | Glass | Yes | Yes |
4 | LNMO-1 | 90 | 6 | 4 (Kynar) | \ | \ | Glass | Yes | Yes |
5 | LNMO-2 | 90 | 5.69 | 4.26 (Solvay) | 0.05 | \ | Glass | Yes | Yes |
Additives | Delamination Observation | Color Change Observation | |
---|---|---|---|
1 | tVCBO | Yes | Light brown |
2 | TMSPi | No | Light yellow |
3 | LiDFOB | No | Colorless |
4 | PES | Yes | Brown |
5 | PTSI | No | Colorless |
6 | DEPP | No | Dark brown |
7 | DPDMS | No | Brown |
8 | SA | No | Purple |
9 | TPP | No | Dark brown |
10 | TMB | Yes | Brown |
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Wang, B.; Son, S.-B.; Badami, P.; Trask, S.E.; Abraham, D.; Qin, Y.; Yang, Z.; Wu, X.; Jansen, A.; Liao, C. Understanding and Mitigating the Dissolution and Delamination Issues Encountered with High-Voltage LiNi0.5Mn1.5O4. Batteries 2023, 9, 435. https://doi.org/10.3390/batteries9090435
Wang B, Son S-B, Badami P, Trask SE, Abraham D, Qin Y, Yang Z, Wu X, Jansen A, Liao C. Understanding and Mitigating the Dissolution and Delamination Issues Encountered with High-Voltage LiNi0.5Mn1.5O4. Batteries. 2023; 9(9):435. https://doi.org/10.3390/batteries9090435
Chicago/Turabian StyleWang, Bingning, Seoung-Bum Son, Pavan Badami, Stephen E. Trask, Daniel Abraham, Yang Qin, Zhenzhen Yang, Xianyang Wu, Andrew Jansen, and Chen Liao. 2023. "Understanding and Mitigating the Dissolution and Delamination Issues Encountered with High-Voltage LiNi0.5Mn1.5O4" Batteries 9, no. 9: 435. https://doi.org/10.3390/batteries9090435