Magnetic Nanoparticles of Fe3O4 Biosynthesized by Cnicus benedictus Extract: Photocatalytic Study of Organic Dye Degradation and Antibacterial Behavior
Abstract
:1. Introduction
2. Materials and Methods
2.1. Bio-Synthesis of Fe3O4 Nanoparticles
2.2. Materials CHARACTERIZATION
2.3. Congo Red Photo Degradation
2.4. Antibacterial Activity
3. Results and Discussion
3.1. Scanning Electron Microscopy
3.2. X-Ray Analysis of the Nano-Crystalline Fe3O4
3.3. Williamson-Hall Analysis
3.4. Raman Spectroscopy
3.5. Analysis of Magnetic Properties of the Fe3O4 Obtained by Green Route
3.6. Photocatalytic Effect: Congo Red (CR) Degradation
3.7. Theoretical Adsorption Kinetic Models
3.8. Antibacterial Effect
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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2θ | d-spacing | hkl | FWHM (Corrected) | Asymmetry | Areal Asymmetry | Integral Breadth | Shape Factor | Size Uncorrected | Size Corrected |
---|---|---|---|---|---|---|---|---|---|
30.24 | 2.9571 | 220 | 0.5069 | 1.0005 | 1.6403 | 0.588 | 0.861 | 18.03811703 | 18.3 |
35.62 | 2.5185 | 311 | 0.6984 | 0.7643 | 0.7378 | 0.893 | 0.782 | 13.27506532 | 13.4 |
38.1 | 2.4213 | 222 | 0.4058 | 0.6814 | 0.8878 | 0.242 | 1.68 | 23.01235689 | 24.1 |
43.2 | 2.0925 | 400 | 0.8135 | 1.4181 | 1.2442 | 0.277 | 2.936 | 11.67014924 | 11.8 |
53.62 | 1.7061 | 422 | 0.46792 | 1.1632 | 1.0717 | 0.3921 | 1.052 | 21.13618779 | 21.1 |
57.08 | 1.6102 | 511 | 0.7651 | 1.7009 | 1.1468 | 0.486 | 1.576 | 13.13289818 | 13.5 |
62.84 | 1.4802 | 440 | 0.6574 | 0.8412 | 0.994 | 0.646 | 1.017 | 15.73424925 | 16.6 |
Profile Function | Profile Broadening | Size (nm) | Strain (%) |
---|---|---|---|
Pseudo-Voigt | FWHM | 14.45 ± 6.27 | 0.289 ± 0.145 |
Integral breadth | 18.10 ± 4.32 | 0.1624 ± 0.192 | |
Lorentzian | FWHM | 18.04 ± 2.11 | 0.0640 ± 0.017 |
Integral breadth | 22.11 ± 4.98 | 0.032 ± 0.016 | |
Gaussian | FWHM | 13.89 ± 3.32 | 0.09 ± 0.181 |
Integral breadth | 17.70 ± 5.78 | 0.012 ± 0.154 |
Phase | Center Max | Phonon Modes | Max Height | FWHM | Area | % Phase |
---|---|---|---|---|---|---|
Magnetite | 337.223 | T2g | 205.855 | 454.371 | 1145.410 | 8.82417337 |
467.565 | T2g | 649.779 | 100.823 | 470.199 | 3.6223863 | |
490.854 | T2g | 169.265 | 389.238 | 845.322 | 6.51231252 | |
561.327 | T2g | 868.329 | 127.992 | 818.774 | 6.30778824 | |
665.161 | A1g | 350.471 | 524.393 | 2627.970 | 20.2457311 | |
45.5123916 | ||||||
Hematite | 224.171 | A1g | 193.966 | 615.686 | 908.971 | 7.00266079 |
287.060 | Eg | 434.132 | 275.124 | 1047.700 | 8.0714211 | |
392.236 | Eg | 266.167 | 444.447 | 1656.890 | 12.7645861 | |
617.429 | Eg | 169.405 | 38.060 | 1554.730 | 11.9775513 | |
39.8162194 | ||||||
Maghemite | 715.584 | A1g | 285.457 | 43.956 | 1904.400 | 14.6713891 |
Theoretical Model | Equation |
---|---|
Pseudo first order | |
Pseudo second order | |
Elovich | |
Intraparticle diffusion |
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Ruíz-Baltazar, Á.d.J.; Méndez-Lozano, N.; Larrañaga-Ordáz, D.; Reyes-López, S.Y.; Zamora Antuñano, M.A.; Pérez Campos, R. Magnetic Nanoparticles of Fe3O4 Biosynthesized by Cnicus benedictus Extract: Photocatalytic Study of Organic Dye Degradation and Antibacterial Behavior. Processes 2020, 8, 946. https://doi.org/10.3390/pr8080946
Ruíz-Baltazar ÁdJ, Méndez-Lozano N, Larrañaga-Ordáz D, Reyes-López SY, Zamora Antuñano MA, Pérez Campos R. Magnetic Nanoparticles of Fe3O4 Biosynthesized by Cnicus benedictus Extract: Photocatalytic Study of Organic Dye Degradation and Antibacterial Behavior. Processes. 2020; 8(8):946. https://doi.org/10.3390/pr8080946
Chicago/Turabian StyleRuíz-Baltazar, Álvaro de Jesús, Nestor Méndez-Lozano, Daniel Larrañaga-Ordáz, Simón Yobanny Reyes-López, Marco Antonio Zamora Antuñano, and Ramiro Pérez Campos. 2020. "Magnetic Nanoparticles of Fe3O4 Biosynthesized by Cnicus benedictus Extract: Photocatalytic Study of Organic Dye Degradation and Antibacterial Behavior" Processes 8, no. 8: 946. https://doi.org/10.3390/pr8080946