A Non–Enzymatic Electrochemical Sensor of Cu@Co–MOF Composite for Glucose Detection with High Sensitivity and Selectivity
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials and Instruments
2.2. Preparation
2.3. Electrochemical Measurements
2.4. Crystal Structure Determination
3. Results
3.1. Structure Description
3.2. Characterizations
3.3. Electrochemically Sensing Glu by Non–Enzymatic Cu@Co–MOF
3.4. Sensing Glu in Human Serum and Orange Juice
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Electrodes | Detection Limit (μM) | Detection Range (mM) | Sensitivity (μA·mM−1·cm−2) | Refs. |
---|---|---|---|---|
Cu@Co–MOF | 1.6 | 0.005–0.4 | 282.89 | This work |
0.4–1.8 | 113.15 | |||
Ni/Co(HHTP)MOF/CC a | 0.1 | 0.3–2.312 | 3250 | [37] |
CoZn–BTC/GCE b | 4.7 | 0.001–0.255 | 1218 | [22] |
0.255–2.53 | 510 | |||
Co0.33Ni0.67–HLDH c | 3.1 | 0.01–2 | 242.9 | [38] |
Cu@HHNs d | 1.97 | 0.005–3 | 1594.2 | [39] |
NiCo–LDH/CC e | 0.12 | 0.001–1.5 | 5.12 | [40] |
Ni(TPA)–SWCNTf | 4.6 | 0.02–4.4 | − | [41] |
Ni0.7Co0.3(OH)2 | 3.42 | 0.5–2.5 | 1541 | [42] |
CuTiPNPs g | 7 | 0.25–2 | 7.81 | [43] |
Co–MOF/EG h | 0.58 | 0.001–3.3 | 330 | [44] |
Cu(OH)2@CoNi–LDH NT–NSs/GSPE i | 0.6 | 0.002–3.2 | 1895 | [45] |
3.2–7.7 | 1322 | |||
Au@Ni–BTC | 1.5 | 0.005–7.4 | 1447.1 | [46] |
CPO–27–NiII j | 1.46 | 0.04–6 | 40.95 | [47] |
SiCNPs–ENFM k | 0.56 | 0.5–20 | 30.75 | [3] |
Cu–in–ZIF–8/SPCE l | 2.76 | 0–0.7 | 412 | [20] |
Cu–Ni/NF m | 2 | 0.001–0.6 | 11340 | [48] |
MWCNTs–PB n | 4.95 | 0.01–1 | 105.93 | [21] |
NiCo–MOF | 0.29 | 0.001–3.8 | 684.4 | [49] |
UiO–67@Ni–MOF | 0.98 | 0.005–3.9 | 203.4 | [50] |
CoPO MA/NF o | 1 | 0.001–1.16 | 3.55 | [51] |
Cu2O@ZIF–67 | 6.5 | 0.01–10 | 307.02 | [52] |
10–16.3 | 181.34 | |||
AgNPs/MOF–74 p | 4.7 | 0.01–4 | 1.29 | [53] |
Ag@TiO2@ZIF–67 | 0.99 | 0.048–1 | 78.8 | [54] |
CoII–MOF/Acb q | 1.7 | 0.005–1 | 255 | [55] |
Cu–hemin MOFs r | 2.73 | 0.009–36 | 22.77 | [56] |
Tb@mesoMOFs–CNT s | 8 | 0.025–17 | − | [57] |
Co NP/Porous C | 5.69 | 0.1–1.1 | 227 | [58] |
Samples | Added (μM) | Found ± SD (μM) | Recovery (%) | RSD |
---|---|---|---|---|
Serum | 50 | 50.01 ± 2.15 | 100.02 | 4.30% |
100 | 94.93 ± 2.61 | 94.93 | 2.75% | |
200 | 188.97 ± 4.23 | 94.49 | 2.24% | |
Orange juice | 50 | 49.04 ± 1.60 | 98.08 | 1.61% |
100 | 93.27 ± 2.87 | 93.27 | 3.08% | |
200 | 189.54 ± 4.46 | 94.77 | 2.35% |
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Ma, Z.-Z.; Wang, Y.-S.; Liu, B.; Jiao, H.; Xu, L. A Non–Enzymatic Electrochemical Sensor of Cu@Co–MOF Composite for Glucose Detection with High Sensitivity and Selectivity. Chemosensors 2022, 10, 416. https://doi.org/10.3390/chemosensors10100416
Ma Z-Z, Wang Y-S, Liu B, Jiao H, Xu L. A Non–Enzymatic Electrochemical Sensor of Cu@Co–MOF Composite for Glucose Detection with High Sensitivity and Selectivity. Chemosensors. 2022; 10(10):416. https://doi.org/10.3390/chemosensors10100416
Chicago/Turabian StyleMa, Zhen-Zhen, Yue-Shu Wang, Bing Liu, Huan Jiao, and Ling Xu. 2022. "A Non–Enzymatic Electrochemical Sensor of Cu@Co–MOF Composite for Glucose Detection with High Sensitivity and Selectivity" Chemosensors 10, no. 10: 416. https://doi.org/10.3390/chemosensors10100416