Shape Memory Behaviour of PMMA-Coated NiTi Alloy under Thermal Cycle
Abstract
:1. Introduction
2. Materials and Methods
2.1. Fabrication of Composite System by Spin Coating Method
2.2. Characterization of NiTi and Composite System Using Various Techniques
3. Results
3.1. Surface Morphology of PMMA Films Spin Coated on NiTi Substrates
3.2. Thermal Response of Individual Components of the Composite
3.3. Thermal Response of Composite as a Function of Heating and Cooling Cycle
3.4. Thermomechanical Behavior of Composite with Multiple Cycles
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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PMMA: Toluene (g/mL) | Spin Coating Parameters (Speed, Time of Duration) | Sample Thickness (mm) | Observation |
---|---|---|---|
1:12 (SE) | Speed: 3200 rpm, t: 30 s | 0.216 ± 0.034 | Samples with pinholes |
Speed: 500 rpm, t: 30 s | 0.376 ± 0.052 | Sample thickness improves | |
1:24 (SMA) | Speed: 500 rpm, t: 30 s | 0.240 ± 0.023 | Sample with fewer pinholes |
Speed: 100 rpm, t: 40 s Speed: 500 rpm t: 5 s | 0.232 ± 0.030 | fewer pinholes | |
1:24 (SE) | Step 1 + 2: Speed: 200 rpm, t: 40 s + 500 rpm, t: 20 s | 0.492 ± 0.048 | Thickness improves with better surface quality |
Sample | Rs (°C) | Rf (°C) | Ms (°C) | Mf (°C) | As (°C) | Af (°C) | Enthalpy A→R (J/g) | Enthalpy R→M (J/g) | Enthalpy M→A (J/g) |
---|---|---|---|---|---|---|---|---|---|
SE–NiTi | 13.30 | −28.18 | −58.71 | −84.41 | −26.47 | 14.45 | 2.7 | 2.0 | 10.7 |
SE–Laser-lines | 13.30 | −28.18 | −58.71 | −84.41 | −26.47 | 14.45 | 2.7 | 2.0 | 10.7 |
SE–PMMA | 13.30 | −28.18 | −58.71 | −84.41 | −26.47 | 14.45 | 2.7 | 2.0 | 10.7 |
SMA–NiTi | 63.07 | 37.37 | 37.37 | −4.35 | 37.02 | 76.41 | 4.7 | 6.6 | 18.0 |
SMA–Laser-lines | 63.07 | 37.37 | 37.37 | −4.35 | 37.02 | 76.41 | 4.7 | 6.6 | 18.0 |
SMA–PMMA | 63.07 | 37.37 | 37.37 | −4.35 | 37.02 | 76.41 | 4.7 | 6.6 | 18.0 |
Sample Case | Cycle Number | ||||
---|---|---|---|---|---|
Cycle 1 (Stress in MPa) | Cycle 2 (Stress in MPa) | Cycle 3 (Stress in MPa) | Cycle 4 (Stress in MPa) | Cycle 5 (Stress in MPa) | |
SMA_PMMA (100 °C) | 0.54 ± 0.001 | 0.81 ± 0.002 | 0.52 ± 0.001 | 0.81 ± 0.002 | 0.84 ± 0.003 |
SMA_PMMA (0 °C) | 0.71 ± 0.004 | 0.73 ± 0.004 | 0.62 ± 0.003 | 0.73 ± 0.004 | 0.8 ± 0.01 |
SE_PMMA (100 °C) | 1.26 ± 0.008 | 1.24 ± 0.008 | 1.23 ± 0.008 | 1.27 ± 0.008 | 1.29 ± 0.008 |
SE_PMMA (0 °C) | 0.61 ± 0.003 | 0.73 ± 0.004 | 0.72 ± 0.004 | 0.53 ± 0.002 | 0.44 ± 0.002 |
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Samal, S.; Kosjakova, O.; Vokoun, D.; Stachiv, I. Shape Memory Behaviour of PMMA-Coated NiTi Alloy under Thermal Cycle. Polymers 2022, 14, 2932. https://doi.org/10.3390/polym14142932
Samal S, Kosjakova O, Vokoun D, Stachiv I. Shape Memory Behaviour of PMMA-Coated NiTi Alloy under Thermal Cycle. Polymers. 2022; 14(14):2932. https://doi.org/10.3390/polym14142932
Chicago/Turabian StyleSamal, Sneha, Olga Kosjakova, David Vokoun, and Ivo Stachiv. 2022. "Shape Memory Behaviour of PMMA-Coated NiTi Alloy under Thermal Cycle" Polymers 14, no. 14: 2932. https://doi.org/10.3390/polym14142932