Long-Term Stability Improvement of Non-Toxic Dye-Sensitized Solar Cells via Poly(ethylene oxide) Gel Electrolytes for Future Textile-Based Solar Cells
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
3.1. Influence of DMSO and Distilled Water as Solvents on Photovoltaic Performance
3.2. Influence of the PEO Concentration on Photovoltaic Performance
3.3. Influence of Drying before Assembly on Photovoltaic Performance
3.4. Influence of the PEO-Based Gel Electrolyte on the Long-Term Stability
4. Conclusions and Outlook
Author Contributions
Funding
Conflicts of Interest
References
- Mohamad, A.A. Absorbency and conductivity of quasi-solid-state polymer electrolytes for dye-sensitized solar cells: A characterization review. J. Power Sour. 2016, 329, 57–71. [Google Scholar] [CrossRef]
- Syairah, A.; Khanmirzaei, M.H.; Saidi, N.M.; Farhana, N.K.; Ramesh, S.; Ramesh, K. Effect of different imidazolium-based ionic liquids on gel polymer electrolytes for dye-sensitized solar cells. Ionics 2019, 25, 2427–2435. [Google Scholar] [CrossRef]
- Gossen, K.; Ehrmann, A. Glycerin-based electrolyte for reduced drying of dye-sensitized solar cells. Optik 2020, 207, 163772. [Google Scholar] [CrossRef]
- Mamun, A.; Trabelsi, M.; Klöcker, M.; Sabantina, L.; Großerhode, C.; Blachowicz, T.; Grötsch, G.; Cornelißen, C.; Streitenberger, A.; Ehrmann, A. electrospun nanofiber mats with embedded non-sintered TiO2 for dye-sensitized solar cells (DSSCs). Fibers 2019, 7, 60. [Google Scholar] [CrossRef] [Green Version]
- O’Regan, B.; Grätzel, M. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature 1991, 353, 737–740. [Google Scholar] [CrossRef]
- Singh, P.K.; Nagarale, R.K.; Pandey, S.P.; Rhee, H.W.; Bhattacharya, B. Present status of solid state photoelectrochemical solar cells and dye sensitized solar cells using PEO-based polymer electrolytes. Adv. Nat. Sci. Nanosci. Nanotechnol. 2011, 2, 23002. [Google Scholar] [CrossRef]
- Wang, Y. Recent research progress on polymer electrolytes for dye-sensitized solar cells. Sol. Energy Mater. Sol. Cells 2009, 93, 1167–1175. [Google Scholar] [CrossRef]
- Iftikhar, H.; Sonai, G.G.; Hashmi, S.G.; Nogueira, A.F.; Lund, P.D. Progress on electrolytes development in dye-sensitized solar cells. Materials 2019, 12, 1998. [Google Scholar] [CrossRef] [Green Version]
- Asghar, M.I.; Miettunen, K.; Halme, J.; Vahermaa, P.; Toivola, M.; Aitola, K.; Lund, P. Review of stability for advanced dye solar cells. Energy Environ. Sci. 2010, 3, 418. [Google Scholar] [CrossRef]
- Ehrmann, A.; Blachowicz, T. Recent coating materials for textile-based solar cells. Aims Mater. Sci. 2019, 6, 234–251. [Google Scholar] [CrossRef]
- Song, D.; Cho, W.; Lee, J.H.; Kang, Y.S. Toward higher energy conversion efficiency for solid polymer electrolyte dye-sensitized solar cells: Ionic conductivity and TiO2 pore-filling. J. Phys. Chem. Lett. 2014, 5, 1249–1258. [Google Scholar] [CrossRef] [PubMed]
- Huang, L.; Nagapudi, K.; Apkarian, R.P.; Chaikof, E.L. Engineered collagen-PEO nanofibers and fabrics. J. Biomater. Sci. Polym. Ed. 2001, 12, 979–993. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Lei, B.; Li, G.-R.; Chen, P.; Gao, X.-P. A quasi-solid-state solar rechargeable battery with polyethylene oxide gel electrolyte. ACS Appl. Energy Mater. 2019, 2, 1000–1005. [Google Scholar] [CrossRef]
- Ida, J.; Suthanthiraraj, S.A. Investigation on the effect of nitrogenous compound benzotriazole on the structural, thermal and dielectric properties of PEO-PMMA blended polymer electrolyte system and its performance in dye sensitized solar cells. Macromol. Res. 2019, 27, 346–353. [Google Scholar] [CrossRef]
- Dissanayake, M.A.K.L.; Ekanayake, E.M.B.S.; Bandara, L.R.A.K.; Seneviratne, V.A.; Thotawatthage, C.A.; Jayaratne, S.L.; Senadeera, G.K.R. Efficiency enhancement by mixed cation effect in polyethylene oxide (PEO)-based dye-sensitized solar cells. J. Solid State Electrochem. 2016, 20, 193–201. [Google Scholar] [CrossRef]
- Nogueira, A.F.; Durrant, J.R.; de Paoli, M.A. Dye-sensitized nanocrystalline solar cells employing a polymer electrolyte. Adv. Mater. 2001, 13, 826–830. [Google Scholar] [CrossRef]
- Nei de Freitas, J.; Nogueira, A.F.; de Paoli, M.-A. New insights into dye-sensitized solar cells with polymer electrolytes. J. Mater. Chem. 2009, 19, 5279. [Google Scholar] [CrossRef] [Green Version]
- Song, J.Y.; Wang, Y.Y.; Wan, C.C. Review of gel-type polymer electrolytes for lithium-ion batteries. J. Power Sour. 1999, 77, 183–197. [Google Scholar] [CrossRef]
- Anantharaj, G.; Joseph, J.; Selvaraj, M.; Jeyakumar, D. Fabrication of stable dye sensitized solar cell with gel electrolytes using poly(ethylene oxide)-poly(ethylene glycol). Electrochim. Acta 2015, 176, 1403–1409. [Google Scholar] [CrossRef]
- Kohn, S.; Wehlage, D.; Juhász Junger, I.; Ehrmann, A. Electrospinning a dye-sensitized solar cell. Catalysts 2019, 9, 975. [Google Scholar] [CrossRef] [Green Version]
- Juhász Junger, I.; Großerhode, C.; Storck, J.L.; Kohn, S.; Grethe, T.; Grassmann, C.; Schwarz-Pfeiffer, A.; Grimmelsmann, N.; Meissner, H.; Blachowicz, T.; et al. Influence of graphite-coating methods on the DSSC performance. Optik 2018, 174, 40–45. [Google Scholar] [CrossRef]
- Juhász Junger, I.; Wehlage, D.; Böttjer, R.; Grothe, T.; Juhász, L.; Grassmann, C.; Blachowicz, T.; Ehrmann, A. Dye-sensitized solar cells with electrospun nanofiber mat-based counter electrodes. Materials 2018, 11, 1604. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Bella, F.; Nair, J.R.; Gerbaldi, C. Towards green, efficient and durable quasi-solid dye-sensitized solar cells integrated with a cellulose-based gel-polymer electrolyte optimized by a chemometric DoE approach. RSC Adv. 2013, 3, 15993. [Google Scholar] [CrossRef]
- Soroko, I.; Bhole, Y.; Livingston, A.G. Environmentally friendly route for the preparation of solvent resistant polyimide nanofiltration membranes. Green Chem. 2011, 13, 162–168. [Google Scholar] [CrossRef]
- Gong, J.; Sumathy, K.; Qiao, Q.; Zhou, Z. Review on dye-sensitized solar cells (DSSCs): Advanced techniques and research trends. Renew. Sustain. Energy Rev. 2017, 68, 234–246. [Google Scholar] [CrossRef]
- Kohn, S.; Großerhode, C.; Storck, J.L.; Grötsch, G.; Cornelißen, C.; Streitenberger, A.; Grassmann, C.; Schwarz-Pfeiffer, A.; Ehrmann, A. Commercially available teas as possible dyes for dye-sensitized solar cells. Optik 2019, 185, 178–182. [Google Scholar] [CrossRef]
- Bohnenkamp, B.; Linnemann, J.-H.; Juhász Junger, I.; Schwenzfeier-Hellkamp, E.; Ehrmann, A. Influence of different solvents on the electrical properties of dye-sensitized solar cells. J. Renew. Sustain. Energy 2018, 10, 63701. [Google Scholar] [CrossRef]
- Juhász Junger, I.; Vanessa Homburg, S.; Meissner, H.; Grethe, T.; Schwarz Pfeiffer, A.; Fiedler, J.; Herrmann, A.; Blachowicz, T.; Ehrmann, A. Influence of the pH value of anthocyanins on the electrical properties of dye-sensitized solar cells. Aims Energy 2017, 5, 258–267. [Google Scholar] [CrossRef]
- Juhász Junger, I.; Udomrungkhajornchai, S.; Grimmelsmann, N.; Blachowicz, T.; Ehrmann, A. Effect of caffeine copigmentation of anthocyanin dyes on DSSC efficiency. Materials 2019, 12, 2692. [Google Scholar] [CrossRef] [Green Version]
- Hölscher, F.; Trümper, P.-R.; Juhász Junger, I.; Schwenzfeier-Hellkamp, E.; Ehrmann, A. Raising reproducibility in dye-sensitized solar cells under laboratory conditions. J. Renew. Sustain. Energy 2018, 10, 13506. [Google Scholar] [CrossRef]
- Junger, I.J.; Homburg, S.V.; Grethe, T.; Herrmann, A.; Fiedler, J.; Schwarz-Pfeiffer, A.; Blachowicz, T.; Ehrmann, A. Examination of the sintering process-dependent properties of TiO2 on glass and textile substrates. J. Photon. Energy 2017, 7, 15001. [Google Scholar] [CrossRef]
- Storck, J.L.; Dotter, M.; Brockhagen, B.; Grothe, T. Evaluation of novel glycerol/PEO gel polymer electrolytes for non-toxic dye-sensitized solar cells with natural dyes regarding long-term stability and reproducibility. Crystals 2020. accepted. [Google Scholar]
- Park, S.J.; Yoo, K.; Kim, J.-Y.; Kim, J.Y.; Lee, D.-K.; Kim, B.; Kim, H.; Kim, J.H.; Cho, J.; Ko, M.J. Water-based thixotropic polymer gel electrolyte for dye-sensitized solar cells. ACS Nano 2013, 7, 4050–4056. [Google Scholar] [CrossRef] [PubMed]
- Awadhia, A.; Agrawal, S.L. Structural, thermal and electrical characterizations of PVA:DMSO:NH4SCN gel electrolytes. Solid State Ion. 2007, 178, 951–958. [Google Scholar] [CrossRef]
- Hsu, H.-L.; Tien, C.-F.; Yang, Y.-T.; Leu, J. Dye-sensitized solar cells based on agarose gel electrolytes using allylimidazolium iodides and environmentally benign solvents. Electrochim. Acta 2013, 91, 208–213. [Google Scholar] [CrossRef]
- Qian, X.; Han, B.; Liu, Y.; Yan, H.; Liu, R. Vapor pressure of dimethyl sulfoxide and water binary system. J. Solut. Chem 1995, 24, 1183–1189. [Google Scholar] [CrossRef]
- Lu, H.-L.; Lee, Y.-H.; Huang, S.-T.; Su, C.; Yang, T.C.-K. Influences of water in bis-benzimidazole-derivative electrolyte additives to the degradation of the dye-sensitized solar cells. Sol. Energy Mater. Sol. Cells 2011, 95, 158–162. [Google Scholar] [CrossRef]
- Pettersson, H.; Gruszecki, T. Long-term stability of low-power dye-sensitised solar cells prepared by industrial methods. Sol. Energy Mater. Sol. Cells 2001, 70, 203–212. [Google Scholar] [CrossRef]
- Bella, F.; Galliano, S.; Falco, M.; Viscardi, G.; Barolo, C.; Grätzel, M.; Gerbaldi, C. Unveiling iodine-Based electrolytes chemistry in aqueous dye-Sensitized solar cells. Chem. Sci. 2016, 7, 4880–4890. [Google Scholar] [CrossRef] [Green Version]
- Galliano, S.; Bella, F.; Piana, G.; Giacona, G.; Viscardi, G.; Gerbaldi, C.; Grätzel, M.; Barolo, C. Finely tuning electrolytes and photoanodes in aqueous solar cells by experimental design. Sol. Energy 2018, 163, 251–255. [Google Scholar] [CrossRef]
- Bella, F.; Galliano, S.; Piana, G.; Giacona, G.; Viscardi, G.; Grätzel, M.; Barolo, C.; Gerbaldi, C. Boosting the efficiency of aqueous solar cells: A photoelectrochemical estimation on the effectiveness of TiCl4 treatment. Electrochim. Acta 2019, 302, 31–37. [Google Scholar] [CrossRef]
- Glinka, A.; Gierszewski, M.; Ziółek, M. Effects of aqueous electrolyte, active layer thickness and bias irradiation on charge transfer rates in solar cells sensitized with top efficient carbazole dyes. J. Phys. Chem. C 2018, 122, 8147–8158. [Google Scholar] [CrossRef]
- Shi, Y.; Zhan, C.; Wang, L.; Ma, B.; Gao, R.; Zhu, Y.; Qiu, Y. The electrically conductive function of high-molecular weight poly(ethylene oxide) in polymer gel electrolytes used for dye-sensitized solar cells. Phys. Chem. Chem. Phys. 2009, 11, 4230–4235. [Google Scholar] [CrossRef] [PubMed]
- Kalaignan, G.; Kang, M.; Kang, Y. Effects of compositions on properties of PEO–KI–I2 salts polymer electrolytes for DSSC. Solid State Ion. 2006, 177, 1091–1097. [Google Scholar] [CrossRef]
- Yoon, J.; Kang, D.k.; Won, J.; Park, J.-Y.; Kang, Y.S. Dye-sensitized solar cells using ion-gel electrolytes for long-term stability. J. Power Sour. 2012, 201, 395–401. [Google Scholar] [CrossRef]
- Agarwala, S.; Thummalakunta, L.N.S.A.; Cook, C.A.; Peh, C.K.N.; Wong, A.S.W.; Ke, L.; Ho, G.W. Co-existence of LiI and KI in filler-free, quasi-solid-state electrolyte for efficient and stable dye-sensitized solar cell. J. Power Sour. 2011, 196, 1651–1656. [Google Scholar] [CrossRef]
- Sonai, G.G.; Tiihonen, A.; Miettunen, K.; Lund, P.D.; Nogueira, A.F. Long-term stability of dye-sensitized solar cells assembled with cobalt polymer gel electrolyte. J. Phys. Chem. C 2017, 121, 17577–17585. [Google Scholar] [CrossRef]
- Xia, J.; Li, F.; Huang, C.; Zhai, J.; Jiang, L. Improved stability quasi-solid-state dye-sensitized solar cell based on polyether framework gel electrolytes. Sol. Energy Mater. Sol. Cells 2006, 90, 944–952. [Google Scholar] [CrossRef]
- Ehrmann, A.; Blachowicz, T. Comment on ‘Dye-sensitized solar cells using aloe vera and cladode of cactus extracts as natural sensitizers’ [Chem. Phys. Lett. 679 (2017) 97–101]. Chem. Phys. Lett. 2019, 714, 227–229. [Google Scholar] [CrossRef]
- Gossen, K.; Storck, J.L.; Ehrmann, A. Influence of solvents on aloe vera gel performance in dye-sensitized solar cells. Optik 2019, 180, 615–618. [Google Scholar] [CrossRef]
- Safety Data Sheet of Solaronix Ruthenizer 535-4TBA (N712). Available online: http://www.solaronix.com/msds/MSDS_Ruthenizer_535-4TBA.pdf (accessed on 7 December 2020).
- Shelke, R.S.; Thombre, S.B.; Patrikar, S.R. Status and perspectives of dyes used in dye sensitized solar cells. Int. J. Renew. Energy Res. 2017, 3, 54–61. [Google Scholar]
- Solaronix Ruthenizer 535-4TBA (N712) Product Website. Available online: https://shop.solaronix.com/ruthenizer-535-4tba.html (accessed on 7 December 2020).
- Lee, W.J.; Ramasamy, E.; Lee, D.Y.; Song, J.S. Dye-sensitized solar cells: Scale up and current–voltage characterization. Sol. Energy Mater. Sol. Cells 2007, 91, 1676–1680. [Google Scholar] [CrossRef]
- Chien, C.-H.; Tsai, M.-L.; Hsieh, C.-C.; Li, Y.-H.; Chao, Y.J. A light harvesting policy on black counter electrode for enhanced performance of dye-sensitized solar cells. J. Sol. Energy Eng. 2014, 136. [Google Scholar] [CrossRef]
Sample Number | Solvent | Electrolytic Salts (KI + I2) (wt%) | PEO (wt%) | Drying |
---|---|---|---|---|
1 | DMSO | 13.0 | 17.4 | 0 h |
2 | Distilled water | 13.0 | 17.4 | 0 h |
3 | DMSO | 14.3 | 9.5 | 0 h |
4 | DMSO | 12.0 | 24.0 | 0 h |
5 | DMSO | 12.0 | 8.0 | 0 h |
6 | DMSO | 12.0 | 8.0 | 0.5 h |
7 | DMSO | 12.0 | 8.0 | 1 h |
8 | DMSO | 12.0 | 8.0 | 2 h |
9 | DMSO | 13.0 | 17.4 | 2 h, 80 °C, oven |
reference | - | Man Solar electrolyte | - | - |
Sample Number | Ionic Conductivity (mS/cm) |
---|---|
1 | 2.85 ± 0.01 |
2 | 4.76 ± 0.01 |
3 | 3.15 ± 0.01 |
4 | 2.71 ± 0.01 |
5 | 3.21 ± 0.01 |
reference | 0.47 ± 0.01 |
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Storck, J.L.; Dotter, M.; Adabra, S.; Surjawidjaja, M.; Brockhagen, B.; Grothe, T. Long-Term Stability Improvement of Non-Toxic Dye-Sensitized Solar Cells via Poly(ethylene oxide) Gel Electrolytes for Future Textile-Based Solar Cells. Polymers 2020, 12, 3035. https://doi.org/10.3390/polym12123035
Storck JL, Dotter M, Adabra S, Surjawidjaja M, Brockhagen B, Grothe T. Long-Term Stability Improvement of Non-Toxic Dye-Sensitized Solar Cells via Poly(ethylene oxide) Gel Electrolytes for Future Textile-Based Solar Cells. Polymers. 2020; 12(12):3035. https://doi.org/10.3390/polym12123035
Chicago/Turabian StyleStorck, Jan Lukas, Marius Dotter, Sonia Adabra, Michelle Surjawidjaja, Bennet Brockhagen, and Timo Grothe. 2020. "Long-Term Stability Improvement of Non-Toxic Dye-Sensitized Solar Cells via Poly(ethylene oxide) Gel Electrolytes for Future Textile-Based Solar Cells" Polymers 12, no. 12: 3035. https://doi.org/10.3390/polym12123035