Probing Effect of Papirindustriens Forskningsinstitut (PFI) Refining on Aggregation Structure of Cellulose: Crystal Packing and Hydrogen-Bonding Network
Abstract
:1. Introduction
2. Methods
2.1. PFI Refining
2.2. Morphological Analysis of Fibers and Mechanical Properties of Sheets
2.3. Water Retention Value (WRV)
2.4. XRD Analysis
2.5. FT-IR Analysis
3. Results and Discussions
3.1. The Morphological Analysis, Swelling, and Mechanical Properties
3.2. Effect of PFI Refining on Crystalline Index and Crystallite Size
3.3. Effect of PFI Refining on H-Bonding Energies, H-Bonding Distances, and Content of H-Bonds
3.4. Correlation between CI and Content of Inter-Molecular H-Bonds during PFI Refining
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Conflicts of Interest
References
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(a) | |||||
Revolutions | CI (%) | Crystallite Size (nm) | |||
CI-XI a | CI-XA b | (110) | (200) | ||
0 | 73.23 | 40.46 | 3.2 | 3.5 | 4.5 |
4000 | 70.42 | 37.71 | 3.1 | 3.4 | 4.6 |
8000 | 72.54 | 39.65 | 3.2 | 3.4 | 4.6 |
12,000 | 70.93 | 36.22 | 3.1 | 3.7 | 4.7 |
16,000 | 69.82 | 34.20 | 3.2 | 3.5 | 4.7 |
(b) | |||||
Revolutions | CI (%) | Crystallite Size (nm) | |||
CI-XI a | CI-XA b | (110) | (200) | ||
0 | 75.55 | 47.16 | 3.1 | 3.1 | 4.5 |
4000 | 73.01 | 36.26 | 3.1 | 3.3 | 4.7 |
8000 | 75.06 | 42.35 | 3.1 | 3.5 | 4.8 |
12,000 | 74.57 | 39.21 | 2.9 | 4.0 | 4.8 |
16,000 | 73.55 | 38.01 | 3.0 | 3.7 | 4.7 |
(a) | |||||
Revolutions | O(6)H⋯O(3ʹ) | O(3)H⋯O(5) | O(2)H⋯O(6) | Free OH(2) and OH(6) | r2 |
0 | 28.23 | 28.44 | 31.40 | 11.93 | 0.9995 |
4000 | 26.05 | 31.31 | 32.50 | 10.14 | 0.9995 |
8000 | 28.43 | 30.86 | 25.87 | 14.84 | 0.9995 |
12,000 | 26.68 | 32.58 | 25.49 | 15.25 | 0.9996 |
16,000 | 23.56 | 34.92 | 29.38 | 12.14 | 0.9996 |
(b) | |||||
Revolutions | O(6)H⋯O(3ʹ) | O(3)H⋯O(5) | O(2)H⋯O(6) | Free OH(2) and OH(6) | r2 |
0 | 26.55 | 29.09 | 30.04 | 14.32 | 0.9990 |
4000 | 24.44 | 33.06 | 31.28 | 11.22 | 0.9991 |
8000 | 26.89 | 29.81 | 28.99 | 14.31 | 0.9991 |
12,000 | 27.01 | 29.28 | 27.40 | 16.31 | 0.9992 |
16,000 | 24.98 | 31.65 | 29.85 | 13.52 | 0.9989 |
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Li, K.; Zhao, L.; He, B. Probing Effect of Papirindustriens Forskningsinstitut (PFI) Refining on Aggregation Structure of Cellulose: Crystal Packing and Hydrogen-Bonding Network. Polymers 2020, 12, 2912. https://doi.org/10.3390/polym12122912
Li K, Zhao L, He B. Probing Effect of Papirindustriens Forskningsinstitut (PFI) Refining on Aggregation Structure of Cellulose: Crystal Packing and Hydrogen-Bonding Network. Polymers. 2020; 12(12):2912. https://doi.org/10.3390/polym12122912
Chicago/Turabian StyleLi, Kunpeng, Lihong Zhao, and Beihai He. 2020. "Probing Effect of Papirindustriens Forskningsinstitut (PFI) Refining on Aggregation Structure of Cellulose: Crystal Packing and Hydrogen-Bonding Network" Polymers 12, no. 12: 2912. https://doi.org/10.3390/polym12122912