Water Splitting with Enhanced Efficiency Using a Nickel-Based Co-Catalyst at a Cupric Oxide Photocathode
Abstract
:1. Introduction
2. Results
2.1. Physicochemical Characterization
2.1.1. X-ray Diffraction (XRD) of In-House-Prepared Co-Catalysts
2.1.2. Morphological Characterization
2.2. Electrochemical Tests
Co-Catalyst at the CuO-Based Photocathode
3. Materials and Methods
3.1. Synthesis of Photoelectrodes
3.1.1. Preparation of (110) Oriented Hematite Nanorods as Photoanodes
3.1.2. Hematite Modification with Titanium and Phosphorus
3.1.3. Preparation of Cupric Oxide onto Sigracet Gas Diffusion Layer (GDL) as a Photocathode
3.1.4. Synthesis of Co-Catalysts for the Photocathode
3.1.5. Ionomer Preparation
3.2. Assembly of the Photoelectrochemical Cell
3.3. Physicochemical Characterization
3.4. Electrochemical Tests
3.5. Efficiency of the PEC
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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Vbias (V) | Jph (mA cm−2) | ɳenth (%) | ɳthroughput (%) |
---|---|---|---|
−0.4 | 1.73 | 2.03 | 2.76 |
−0.6 | 1.97 | 1.89 | 3.13 |
−1.225 | 7.33 | 2.03 | 10.75 |
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Lo Vecchio, C.; Trocino, S.; Giacoppo, G.; Barbera, O.; Baglio, V.; Díez-García, M.I.; Contreras, M.; Gómez, R.; Aricò, A.S. Water Splitting with Enhanced Efficiency Using a Nickel-Based Co-Catalyst at a Cupric Oxide Photocathode. Catalysts 2021, 11, 1363. https://doi.org/10.3390/catal11111363
Lo Vecchio C, Trocino S, Giacoppo G, Barbera O, Baglio V, Díez-García MI, Contreras M, Gómez R, Aricò AS. Water Splitting with Enhanced Efficiency Using a Nickel-Based Co-Catalyst at a Cupric Oxide Photocathode. Catalysts. 2021; 11(11):1363. https://doi.org/10.3390/catal11111363
Chicago/Turabian StyleLo Vecchio, Carmelo, Stefano Trocino, Giosuè Giacoppo, Orazio Barbera, Vincenzo Baglio, María I. Díez-García, Maxime Contreras, Roberto Gómez, and Antonino Salvatore Aricò. 2021. "Water Splitting with Enhanced Efficiency Using a Nickel-Based Co-Catalyst at a Cupric Oxide Photocathode" Catalysts 11, no. 11: 1363. https://doi.org/10.3390/catal11111363