4.1. Application of the Monod Model in Wastewater Treatment
The influence of initial substrate concentration on growth rate is expressed as the following equation in the Modified Monod model [
75]:
where
indicates the starting concentration of substrate.
Many processes, such as aerobic fermentation and the biological treatment of industrial wastewater and pollutants, use substrate inhibition when the substrate is hazardous to the microbe. The Monod model is a proportional increase in substrate concentration; the more substrate available, the faster the microorganisms reproduce [
76]. The specific growth rate for systems susceptible to substrate inhibition is an increasing function at low substrate concentrations and a decreasing function at high substrate concentrations as the following:
where
Scr is the value of the substrate concentration where the substrate inhibition is added, i.e., the point at which the specific growth rate changes from an increasing to a decreasing function of the substrate concentration [
76].
The Contois model permits the biomass concentration to affect the specific growth rate as the following [
75],
The Contois kinetic constant is and the biomass concentration is X. Due to a growing barrier to substrate absorption, the specific growth rate in this model diminishes as the biomass grows.
In the acid phase of anaerobic digestion, a simple model for solubilization was given, with both hydrolysis and fermentation processes happening in sequence, as illustrated in Equation (2). Degradable particles (F) are hydrolyzed (
into soluble substrates in the first step (S). The soluble substrates (S) are consumed (S) in the second step to yield acid phase products (P) and biomass (X). After that, the biomass decomposes (kd) into an unknown substance (U).
In the acid phase model, Monod’s equation was utilized to represent the bacterial growth rate at constant temperature and pH. Hybrid differential evolution was used to estimate the parameters of the Monod model for recombinant fermentation [
22]. The model profiles based on the starting glucose levels were found to be a good fit for the experimental data [
22].
Model equations were used to calculate the concentrations of microorganisms, biodegradable particles, inert material, and soluble substrate in a well-stirred, well-aerated bioreactor. The assumption that the membrane bioreactor is well-agitated means that the substrate is combined with the membrane bioreactor contents instantly and uniformly. Because the reactor is well-aerated, oxygen is not a rate-limiting material. We further assume that the flow through the membrane bioreactor is rapid enough that cell growth does not occur on the reactor walls, i.e., there is no biofilm on the reactor walls, and operational variables such as pH and temperature are automatically maintained. For membrane filtration safety, the ideal value (a maximum desired value) of volatile suspended particles is [
77]:
The rate of change of soluble substrate is described by the equation as follows:
The change rate of the biomass:
The non-biodegradable particles:
The change rate of the biodegradable particles:
The residence time is calculated by:
The chemical demand oxygen (COD) is given by:
The total volatile suspended solids are calculated by:
where the substrate concentration in the membrane bioreactor is S, the bioreactor flow rate is F (dm
3 hr
−1), the Monod constant is Ks, and the recycling ratio is R based on volumetric flow rates. The bioreactor volume (dm3) is V, the substrate concentration entering the membrane bioreactor is S0, the biomass concentration is Xb, and the concentration of non-biodegradable particulate material is Xi. The biodegradable particulate substrate concentration is Xs, the feed concentration into the membrane bioreactor is Xj;0 (j = b; I s), and the total volatile suspended solids concentration is Xt. The death coefficient (hr
−1) is kd, the fraction of dead biomass converted to the soluble substrate is fs, the fraction of dead biomass converted to inert material is fi, and the hydrolysis rate of insoluble organic compounds (hr
−1) is kh. The yield factor for insoluble organic compound hydrolysis is α
h, the yield factor for biomass growth is α
g, and the yield factor for dead biomass conversion to the soluble substrate is α
s. The maximum specific growth rate (hr
−1) is μm, and the specific growth rate model (hr
−1) is μs.
It is worth noting that we assumed the settling unit is equally effective at concentrating the biological component (Xb) and the particles (Xs and Xi). The units of soluble substrate concentration are indicated by S, while the units of biomass, non-biodegradable particulate material, and biodegradable particulate substrate concentration are represented by X in the following [
78]. The recycling concentration factor (C) is used in these calculations, and the settling unit design conditions determine the value of this factor. However, the typical parameter unit for the model are stated in
Table 2 below:
Several accurately structured descriptive models for the sludge processes like ASM-1, ASM-2, and ASM-3 were approved [
79,
80]. The ASM-1 model consists of 13 different equations and eight processes, including the production and decline of heterotrophic and automotive biomass, organic ammonification, and hydrolysis. Aerobic processes, including nitrogen, chemical oxygen, nitrification, and denitrification, may be anticipated in the model. Following biological nutrient removal in an activated sludge system, Henze et al. [
81] created the ASM-1 model, which leads to ASM-2 modeling. The biological use of phosphorus was incorporated into the fundamental ASM1 Framework. The biological removal shall be carried out by adding a factor to the model of improved biological deletion of phosphorus as well as by precipitating the chemical deletion of phosphorus. The biological absorption and removal of phosphorus by the activated sludge system exceed the amount removed by a conventional aerobic activated sludge system. The innovative technique of storing organic substrates was further expanded by Henze et al. [
82] which improves the modeling of endogenous respiration lysis (decay) by storing organic substrates. The direct integrations of these numerical equations are used to examine the models [
83]. Without recycling, Nelson and Sidhu [
84] examined the steady states of the model ASM-1 to assess how the reactor’s performance changes in the context of control factors, including oxygen transfer and residence duration. In addition, in residence duration, there is a key bifurcation point that influences reactor performance. During the organic breakdown of carbon dioxide and methane, Mosey [
85] investigated four kinds of bacteria. These groupings are methane bacteria that are acid, acetogénic, acetoclastic, and hydrogen-used. A mathematical model was constructed to represent each of the phases of the kinetic processes utilized for simulating the reaction by the Monod model. Kalyuzhnyi [
86] created a batch mathematical model of anaerobic glucose digestion, involving five distinct bacterial types: acidic, ethanologenic, acetogenic, and acetic butyrate-degrade, methanogenic, acetoclastic, and hydrogenotrophic. This model also included numerous variables and possible bacterial inhibitors. An earlier kinetic model was created for use in the simulation of the different processes involved in the degradation of the substrate material in an anaerobic batch reactor (ASBR) [
87]. Münch et al. [
88] constructed and verified the model of volatile acid generation with the literature’s experimental data. In the wastewater process in which sulphates occur in high quantities. Moreover, Knobel and Lewis [
89] have created a mathematical model for assessing the process of anaerobic digestion. Their model was based on the Debye-Huckle theory and may be used to determine activity coefficients, including sulphate reduction, hydrolysis, acidgenesis, long chain fatty acid beta oxidation, acetogenesis, and methanogenesis in many other factors. Furthermore, the treatment process is fixed, and corresponding adjustments cannot be made according to changes in time or space [
90].
In addition,
Table 3 lists the top ten nations based on the number of publications published in the SCOPUS database between 2018 and 2022 that include the keywords “Monod model and growth rate.”
Figure 6 also shows the Visualization Network map of the top countries with the most articles published in the SCOPUS database from 2018 to 2022 for the keywords “Monod model and growth rate.”
4.2. Application of the Contois Model
Both aerobic and anaerobic industrial wastewater treatment systems have benefited from the use of the Contois growth model in recent years. The Contois model has been proven to be applicable to the fitting of experimental data for a wide variety of organic materials [
91,
92,
93].
Black olive wastewater was subjected to an aerobic biological degrading process and bio-logical ozonation in the research described by -Beltran-Heredia et al. [
94]. The Contois kinetic was utilized to describe the decomposition rate in aerobic biological therapy. It was determined that the Contois model provides an excellent fit to the experimental data, proving that it is applicable to the current experimental setup. Anaerobic treatment of cow dung digesters was explored by Krzystek et al. [
95], who looked at the fit of Monod and Contois kinetics to experimental data. According to the comparison’s findings, the Contois kinetic model is superior to the Monod kinetic model for fitting experimental data from cow dung digesters. Using the Monod and Contois kinetic models, Hu et al. [
96] studied the process kinetics of the anaerobic digestion of ice cream effluent. The root means square for the Contois kinetic was discovered to be much larger than that of the Monod kinetic. Therefore, the Contois model is more appropriate than the Monod model for modeling the process kinetics of the anaerobic digestion of ice-cream wastewater, i.e., predicting the performance of the anaerobic digester reactor, as indicated by the highest correlation coefficient of 0.918 between experimental data and predicted values obtained from the two models. The Contois model outperformed the Monod model in predicting both microbial growth and the efficiency of the anaerobic digester reactor. The Contois kinetic model accounted for the influence of the influent substrate, hence its forecast was more accurate. Anaerobic digestion of sulfate-rich wastewater was also investigated by Hu, Thayanithy, and Forster [
83] using models based on Monod and Contois kinetics in a constantly stirred tank reactor. According to the kinetic investigations, the Contois model was superior to the Monod model in predicting the kinetic reactions of the process, with a correlation value of 0.989. This showed excellent agreement with the experimental data. The Contois kinetic model outperformed the Monod kinetic model in predicting the efficiency of the anaerobic digester reactor and the development of the microorganisms. Therefore, the attachment of biomass to the walls of the reactor, which may supply a source of inoculum, is the reason for the successful prediction of Contois’s kinetic model. Işik and Sponza [
97] employed different models, including Monod, Contois, Grau second order, modified Stover-Kincannon, and first-order kinetic, to examine the process kinetics of the anaerobic treatment of textile wastewater in a lab-scale upflow anaerobic sludge blanket reactor. Compared to the Monod and first-order kinetic models, the Contois kinetic model better describes microbial dynamics, as shown by their investigations (r = 0.967). The findings further indicated that the Contois model is the most appropriate one for forecasting anaerobic digester performance. Using the Monod, Chen & Hashimoto, and Contois models, Moosa et al. [
98] studied the kinetics of anaerobic sulfate reduction in continuous bioreactors. When it came to defining the dependence of the specific growth rate of bacteria on sulfate concentration, the Contois kinetic model offered the best agreement with experimental results on the anaerobic reduction of sulfate. The removal of sulfate from industrial wastewater and acid mine drainage are only two of the many uses for this technique. Different influent sulfate concentrations were used to calculate the Contois model’s kinetic coefficients. The coefficient for the mortality rate was shown to be stable throughout a wide range of starting sulfate concentrations. Nonetheless, the saturation constant (Ks) rose dramatically with increasing initial sulfate concentration whereas the maximal specific growth rate (max) changed little. Tessier, Monod, and Contois models of biodegradation kinetics were employed to model the process. The experimental data were well-fit by each of the models. However, the strongest correlation value (0.984) was reported for the Contois kinetic model in describing the microbial growth of Xhhh growth. Abdurahman et al. [
99] also studied the treatment of palm oil mill effluent utilizing a membrane anaerobic system, but they did it via the lens of three kinetic models: the Monod, Contois, and Chen & Hashimoto models. Both investigations demonstrated that the Contois model had a very good fit for experimental data (r = 0.962 and r = 0.997, respectively). The greatest value for the correlation coefficient was obtained using the Contois model in the second scenario. Methane generation rate from anaerobic digestion of cow dung in bench-scale gas-lift digesters was predicted using a novel model presented by Karim et al. [
100] proposed a new model, including the Contois kinetic model and an endogenous decay model to predict the methane production rate from the anaerobic digestion of cow manure in bench-scale gas-lift digesters. The proposed model and two other well-known kinetic models, the Hill [
101] models, which included the Contois kinetic model and an endogenous decay model. The experimental data for methane production rate was fitted using the suggested model and two additional well-known kinetic models, the Hill [
95] models. Although the Chen and Hash-imoto and Hill models performed poorly in fitting the experimental data (correlation coefficients of 0.86 and 0.51, respectively), the novel model including Contois kinetics performed very well (r = 0.99). The suggested model, which incorporates the Con-tois model, performed better than the other two models in predicting the rate of methane generation when compared to experimental data. For the hydrolysis of particulate organic material in anaerobic digestion, Vavilin et al. [
102] examined four kinetic models, including Monod, first-order, two-phase, and Contois kinetics. The acquired findings demonstrated that good fits to the experimental data could be achieved by using the Contois kinetic for the hydrolysis kinetics of swine waste, sewage sludge, cow manure, and cellulose. The lactate fermentation properties of B. Coagulans in a batch reactor were modeled by Hidaka et al. [
103] Substrate, lactate (product), sodium chloride, and bacterial growth were all accounted for in the model as inhibitors. The degradation of carbohydrate particles was simulated using the Contois kinetic model. Based on their findings, they concluded that the Contois model is superior to the first-order reaction model for modeling the hydrolysis of kitchen trash particles. Anaerobic hydrolysis of organic waste particles is described using the Contois model, and this finding is consistent with previous work [
34,
104] that employed this model.
In many analyses, researchers found that the Contois equation well described the kinetics of fungal growth. The growth kinetics of the fungus Rhizopus nigricans in response to glucose was investigated by Zhou et al. [
105] using the Contois model. With a correlation coefficient of 0.99, the findings demonstrated the validity of the Contois model for modeling the kinetics of cell growth.
The Rhodotorula red yeast strains that Hernalsteens and Maugeri [
106] studied generated an extracellular enzyme. The Contois model was used to characterize the microbial growth dynamics. In contrast to the standard Monod model, the Contois model was shown to provide an excellent match to the experimental data (r = 0.95).
Furthermore,
Table 4 displays the top ten countries based on the number of articles published in the SCOPUS database between 2018 and 2022 with the keywords “Contois model and growth rate.”
Figure 7 also illustrates the Visualization Network map of top countries published in the SCOPUS database, as well as the relationship between them, from 2018 to 2022 for the keywords “Contois model and growth rate”.
4.3. Application of RSM
Relational statistical modeling (RSM) uses experimental data to construct mathematical models that characterize the associations between causes (independent variables) and response variables (responses). Independent variables and interaction effects on responses are analyzed and optimized using these models. 2-D contours and 3-D plots are the most common ways to display the findings. To implement the RSM, one must use statistical experimental design, linear regression modeling, and optimization techniques. The process of using RSM as an optimization technique consists of many phases. The steps are (i) deciding on which variables to use and what ranges to use them in, (ii) deciding on an experimental design and carrying it out, (iii) generating a linear regression model equation from the experimental results, (iv) checking the model’s sufficiency, and (v) visualizing the model to determine the best settings.
Multiple process factors affect the efficacy of the various procedures used in water and wastewater treatment. If these procedures could be optimized to provide optimum results, not only would costs be reduced, but so would the usage of precious resources like energy and materials. The conventional way of optimizing a problem involves considering just a single variable at a time. With this method, we may isolate the effects of a single variable by holding all others constant. This process is then repeated with more variables until the optimal circumstances are achieved. However, this method cannot provide a full picture of the impacts of the variables on the process since it does not show the interaction effects among the variables evaluated. The one-factor-at-a-time method is both time-consuming and expensive since it requires several experiments [
107].
The design of experiments has been used to find solutions to these issues. The design of experiments has several benefits, such as the ability to learn the same amount with fewer trials, estimate relationships between components, and create empirical models. The response surface methodology (RSM) [
108] is a technique for designing experiments from a graphical viewpoint. Response Surface Methodology (RSM) is a set of mathematical and statistical methodologies for getting the optimal conditions for responses with a minimal number of scheduled tests [
109].
Recent years have seen an increase in the use of RSM for optimizing and analyzing various water and wastewater treatment processes, including coagulation-flocculation, adsorption, advanced oxidation processes, electrochemical processes, and disinfection. The availability of various RSM-specific computer programs has made implementing RSM a very straightforward undertaking. However, it has also led to the inappropriate application of RSM. For the RSM to be successfully used, both the process being researched, and its limits and applicability must be understood in depth.
Heavy metals and harmful organic compounds may be removed from water by the use of adsorption and biosorption methods, which are utilized in water and wastewater treatment. In adsorption, the ions or molecules in a solution are focused on an appropriate contact. pH, ionic strength, adsorbing surface type, and adsorbent/adsorbate ratio all play significant roles in the adsorption process [
110]. The present article provides a review of some of the published research that uses RSM to optimize operational parameters during adsorption and biosorption.
The removal of methyl orange dye by activated carbon was studied by Tripathi et al. [
111] using the RSM with Box–Behnken Design. Adsorbent dosage (5–20 mg/L), contact period (2-6 h), temperature (25–55 W C), and pH were all taken into account (2–8). The optimum conditions of adsorbent dosage = 15.7 mg/L, contact duration = 4 h, temperature = 40 W C, and pH = 2 resulted in a 99.11% removal efficiency. Using the noxious plant Parthenium hysterophorus as a cheap adsorbent, Chatterjee et al. [
112] investigated methylene blue removal. By using RSM, we were able to statistically optimize the factors involved in both adsorbent preparation and dye removal and recovery. Carbonizing parameters studied included activating agent to Par-thenium weight ratio (1.0–1.5), carbonizing temperature (450–550 W C), and carbonizing duration (1–2 h). Response decolorizing power was maximized at a weight ratio of 1.05:1 and after being carbonized at 550 °W for 1 h. The cleaned sample was put to use in further research on dye elimination. Initial dye concentration (25–50 mg/L), adsorbent weight (0.2–0.5 mg/L), pH (5–8), and temperature (25 C–35 C) were all taken into account (30–40 WC). The optimal conditions for maximal dye removal were 25 mg/L starting concentration, 0.5 g adsorbent weight, pH 7, and 35 °C. The independent factors used to determine the most effective dye recovery method were the quantity of wasted adsorbent (0.2–0.5 g), pH (5–9), and contact duration (1–3 h). The model showed that the recovery rate increased both with decreasing pH and with increasing contact duration. Biosorption of heavy metals including Cu(II), Ni(II), and Zn(II) on surfactant-modified chitosan bead was optimized using RSM by Sarkar and Majumdar [
113]. For this reason, a half factorial design with 251 components was used to determine which ones were most relevant. After a series of trials, the optimal values for pH, metal concentration, and adsorbent dose were determined. For the same amount of adsorbent, more adsorption occurred when more adsorbent was used. Through RSM with a central composite design, the optimal parameters for Cu(II) adsorption were determined to be pH 5.5, adsorbent dose 0.5 g/L, and starting concentration of 30 mg/L.
The increased oxidation of direct red 28 dye by photo-Fenton treatment with RSM was studied by Ay et al. [
114]. The experimental layout was a Box–Behnken design. Color and total organic carbon (TOC) removals were studied to determine the impact of dyestuff concentration, peroxide dosage, and Fe(II) dose. It was shown using RSM modeling that the efficiency of color removal decreased as a function of dyestuff concentration while improving with increasing H
2O
2 and Fe(II) dosages. Dyestuff, H
2O
2, and Fe(II) dosages all contributed to greater TOC elimination. The estimated ideal peroxide/Fe(II) ratio at the highest starting dyestuff concentration of 250 mg/L was 715/71 mg/L for 100% color removal, and this ratio was 1.550/96.5 mg/L for 97.5% TOC removal.
The electro-Fenton procedure employing RSM was studied by Mohajeri et al. [
115] to remove stubborn organics from semi-aerobic landfill leachate. The experimental runs were planned using a central composite design, with the molar ratio of H
2O
2 to Fe
2+, current density, pH, and reaction duration serving as input variables and the elimination of COD and color serving as responses. The experimental design was simplified by holding constant the remaining variables, including temperature, stirring rate, and electrode separation. The optimal parameters found to remove 94.16% COD and 95.83% color were a current density of 40 mA/cm
2, a pH of 3, a reaction period of 43 min, and a molar ratio of H
2O
2/Fe
2+ of 1. Values from validation studies were found to be in reasonable agreement with these.
By identifying the optimal operating conditions for a system and creating a response surface model that predicts a response based on a combination of factor levels, RSM is a very effective process. More so, it details how several variables influence the final result and how those aspects interact with one another. Because of this, they have found widespread use in the modeling of water and sewage treatment systems and processes, as this overview demonstrates.
The majority of published research on optimizing systems or processes did so without taking economic factors into account. This means that it is important to consider cost when trying to find the best configuration for a system or process, and fortunately, RSM makes this very easy to do. In addition, RSM may be used to pinpoint an area of the factor space where all the necessary operational conditions hold. When it comes to water and wastewater treatment systems, where many regulations and requirements must be satisfied, this is of paramount importance.
The experimenter’s background knowledge of the process under investigation is essential for generating reliable results from an RSM analysis. Evidence from this research indicates that, in many experiments involving optimization, true optimum points were not located because the range of independent variables was incorrectly chosen, causing the optimal circumstances to lie outside the experimental area. Conditions associated with maximum/minimum responses are incorrectly represented as optimal in such cases. This demonstrates the need of doing the necessary groundwork beforehand to determine the appropriate range of independent variables in experimental design.
There is a wealth of material on the use of RSM in the lab for water and sewage purification, but very little on its actual use in the real world. As a result, additional research into the method’s potential practical uses is required. Additionally, further study is required to evaluate and integrate RSM with other modeling approaches such as ANN and fuzzy logic for modeling various water and wastewater treatment processes.
Additionally,
Table 5 lists the top ten nations based on the volume of publications containing the keywords “response surface methodology and wastewater treatment” that were published in the SCOPUS database between 2018 and 2022.
Figure 8 also shows the Visualization Network map of the most popular nations from 2018 to 2022 for the keywords “response surface methodology and wastewater treatment,” along with the relationships between them.
4.4. Application of ANN
Treatment of wastewater is a complex nonlinear system characterized by significant random disturbance, time fluctuation, and uncertainty. Current wastewater treatment plant planning and operations are based mostly on experiments, which leads to significant inaccuracies. In-depth studies have been conducted on the system for years, and several mechanism models have been proposed, but due to complexity and uncertainty, real-time control has not yet been achieved. Artificial neural networks (ANN) have been the focus of a great deal of study [
116,
117] due to their capacity to provide approximations to complicated and nonlinear equations. A neural network (ANN) is a kind of information processing system that takes its cues from the study of biological brain processing. Biological neural networks are composed of many individual neurons that are non-linear and densely coupled. To facilitate its logical parallelism, an ANN organizes its neurons into layered structures. In serial operations, information is sent from one layer to another [
118]. An ANN’s fundamental structure typically consists of three different levels: an input layer, where data are supplied to the ANN; a hidden layer or layers, where data are processed; and an output layer, where the findings of the ANN are shown. Adjustable rules specify the relative relevance of weights for input. The ANN is constructed by applying weights between neurons and a transfer function that regulates the formation of the output. During training, the ANN assigns relative significance to the weights and fine-tunes them using iterative methods [
119].
Using water temperature, SS (suspended solid) concentration, influent COD concentration, NH3-N, MLSS, MLVSS, and SV30 (volume ratio after 30 min settlement), Yang et al. [
120] proposed a stable and sensitive dynamic neural network model for predicting effluent quality and potential real-time adjustment of wastewater treatment operations.
As a means of training a well-designed neural network, Liu [
121] employed analog data input and output from EFOR software based on activated sludge mathematical models, and then modified the input and compared it to the output. The findings suggested that the neural network might be used for dynamic modeling of biological nitrogen and phosphorus elimination. In order to predict effluent TP and TN from the carrousel oxidation ditch system in a wastewater treatment plant, Chen et al. [
122] used an RBF neural network. Principal component analysis and cluster analysis were helpful in data mining during the model-building process, and preprocessing the data was essential in lowering the prediction error rate. With TN 94% accuracy and TP 70% accuracy in effluent parameter predictions, the neural network has an excellent performance in tests and can adapt to different scenarios. According to the results of the correlation coefficient test, TN was 0.95 and TP was 0.89.
Based on the multiple neural networks, Yu et al. [
123] suggested an effluent quality prediction model. The input space is partitioned into numerous subspaces using subtractive clustering, and matching models are constructed using a neural network. After that, the models are integrated using principal component regression to get rid of the high degree of correlation between them and boost the model’s precision and stability (PCR). Additionally, a modified objective function and weighted feedback correction are used to enhance the model’s generalization capacity and prediction accuracy of the high measured value. The effluent from a wastewater treatment facility is tested for NH3-N ammonia nitrogen using the suggested approach, and the findings are promising.
Effluent from an SBR may be used to calculate BOD content using a soft sensing approach suggested by Liu et al. [
124], which is based on the radial basic function (RBF). The SBR analysis led us to choose TOC, DO SS, and response time as input variables, and TOC as the desired outcome. Then, using the established correlation between TOC and BOD5, BOD5 was acquired by conversion. We trained an RBF neural network and found that its simulation may be utilized to calculate BOD5 for controlling the wastewater treatment process in real-time
To predict BOD5 and COD in treated wastewater drainage, Xu and Pan [
125] used a sophisticated model including a support vector machine (SVM) and features between BOD5 and COD. This approach to SVM parameter optimization uses a particle swarm optimization algorithm, which has superior search abilities and was proposed to address the issue of parameter selection in SVM. The parameters of the control system for wastewater treatment are then collected using soft sensing.
For sequential wastewater treatment operations, Wang et al. [
126] provided a complete assessment on the soft-sensing of water quality in a wastewater treatment process (WWTP) using artificial neural networks (ANNs). They primarily offered issue formulation for water quality soft-sensing, typical soft-sensing models, practical soft-sensing examples, and a discussion of soft-sensing model performance.
Simultaneous determination of Au and Pd concentration in wastewater was performed using BP neural network-spectrophotometry approach, as described by Zheng et al. [
127]. To improve its solubility and sensitivity to test Fe, Ni, and Cu in wastewater, Mingjin [
128] created wavelet packets with analysis-simple recurrent neural network (Elman) spectrophotometry using 5-Br-PADAP as a colorizing agent in the presence of nonionic surfactant.
Since the physical phenomena for As (III) and As (VI) removal by individual bacterial Biomass [
8] and mixed dried biomass [
7] is complex, the prediction of As (III) and As (V) adsorption using an artificial neural network (ANN) model is involved. An ANN model, based on 128 sets of experimental data, was developed to simulate the way the human brain works. The ratio of input neurons to those in the hidden layer to those in the output layer was 5-7-1. Of the batch data, 75% was set aside for the learning process, 10% for the testing phase, and 15% for the validation. There was very little mean squared error and a very high degree of correlation (R2 = 0.9959) between the projected output vector and the experimental data (MSE; 0.3462). The suggested model’s anticipated results matched the batch work within a tolerable margin of error. An ANN model, based on batch experimental data, was developed to simulate the human brain’s processing capabilities. An equal number of neurons (5-7-1) were distributed throughout the input, hidden, and output layers. It was decided that 75% of the batch data would be used for instruction, 10% for experiments, and 15% for verification. Predicted results from the suggested model were found to be in fair agreement with batch experiments. Meanwhile, during testing and training, we looked at the network’s mean squared error (MSE) and mean error to gauge its performance. However, the training phase was crucial in demonstrating the network model’s capacity to anticipate responses to batches of data. For this reason, it is advised to observe both the mean squared error (MSE) and the mean error during the testing and validation processes, since both metrics are uniquely suited to assessing the model’s efficacy. After 188 iterations, the optimal output vector for a specific set of experimental data input was found, with a minimal MSE of 0.6131. Furthermore, it was found that the mean error (M) and mean square error (MSE) for the training data were 0.1091 and 0.6131, respectively, whereas the corresponding values for the testing data were 0.0767 and 0.3462. In terms of statistical indicators (correlation coefficient), values of 0.9909 and 0.9959 were attained for the training data and the testing data, respectively.
Even though there have been several studies on the use of neural networks in wastewater treatment, most of the techniques are still only used in the lab. There is a need for further research into using neural networks for full and high-quality control of wastewater treatment. The integration of neural networks with other control methods is an intriguing area to investigate due to the networks’ superior research capabilities and inherent flaws. The use of ANN is regarded as a successful approach owing to its versatility in simulation, estimation, and modeling. The significance of ANN is that it is structurally consistent and can learn from previous data. Furthermore, the main advantage of ANN over RSM is that it does not require a prior specification of the best fitting function and has universal approximation functionality, i.e., it can approximate nearly all types of nonlinear functions, including quadratic functions, whereas RSM is only useful for quadratic approximations [
129,
130,
131]. Although ANN has gained popularity for its usage in a variety of engineering domains, several studies for modeling and improving adsorption processes have used this technique [
132,
133].
In addition, the top ten nations are ranked in
Table 6 according to the total number of articles containing the keywords “artificial neural networks and wastewater treatment” that are expected to be added to the SCOPUS database between the years 2018 and 2022.
Figure 9 also provides an illustration of the Visualization Network map of the top nations published in the SCOPUS database from 2018 to 2022 for the keywords “artificial neural networks and wastewater treatment”, as well as the link between these countries.