Thermoresponsive Shape-Memory Biobased Photopolymers of Tetrahydrofurfuryl Acrylate and Tridecyl Methacrylate
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation of Photopolymer Specimens
2.3. Characterization Techniques
2.4. Real-Time Photorheometry
3. Results
3.1. Monitoring of Photocuring Kinetics by Real-Time Photorheometry
3.2. Characterization of Photopolymer Structure
3.3. Thermal Properties of Photopolymers
3.4. Shape-Memory Properties of Photopolymers
3.5. Mechanical Characteristics of Photopolymers
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Resin | Amount of THFA, mol | Amount of C13-MA, mol | Amount of BDT, mol | Amount of TPOL, mol.% | Calculated Biorenewable Carbon Content, % |
---|---|---|---|---|---|
C0 | 0 | 0.5 | 0.03 | 3 | 74.9 |
C1 | 1 | 0.5 | 0.03 | 3 | 68.9 |
C2 | 2 | 0.5 | 0.03 | 3 | 66.9 |
C3 | 3 | 0.5 | 0.03 | 3 | 65.8 |
C4 | 4 | 0.5 | 0.03 | 3 | 65.1 |
C5 | 5 | 0.5 | 0.03 | 3 | 64.7 |
C6 | 6 | 0.5 | 0.03 | 3 | 64.4 |
C7 | 7 | 0.5 | 0.03 | 3 | 64.2 |
C8 | 8 | 0.5 | 0.03 | 3 | 64.0 |
C9 | 9 | 0.5 | 0.03 | 3 | 63.8 |
C10 | 10 | 0.5 | 0.03 | 3 | 63.7 |
Resin | Storage Modulus, G′, MPa | Loss Modulus, G″, MPa | Loss Factor, tan δ | Complex Viscosity η *, MPa.s | Gel Point tgel, s | Induction Period, s | Shrinkage, % |
---|---|---|---|---|---|---|---|
C0 | 0.001 | 5.7110−8 | 5.010−5 | 1.8210−5 | - * | - | 0.0 |
C1 | 0.011 | 0.069 | 6.520 | 0.001 | - | 19.2 | 0.0 |
C2 | 0.167 | 0.291 | 1.740 | 0.535 | - | 4.8 | 0.0 |
C3 | 0.487 | 0.515 | 1.060 | 0.113 | - | 2.4 | 1.0 |
C4 | 0.634 | 0.545 | 0.860 | 0.013 | 9.6 | 2.4 | 2.0 |
C5 | 0.742 | 0.601 | 0.810 | 0.015 | 2.4 | 2.4 | 3.0 |
C6 | 1.106 | 0.800 | 0.724 | 0.022 | 2.4 | 2.4 | 4.0 |
C7 | 1.256 | 0.853 | 0.675 | 0.024 | 2.4 | 2.4 | 5.1 |
C8 | 1.340 | 0.825 | 0.616 | 0.025 | 2.4 | 2.4 | 6.1 |
C9 | 1.477 | 0.941 | 0.637 | 0.028 | 2.4 | 2.4 | 7.1 |
C10 | 1.915 | 1.148 | 0.600 | 0.036 | 2.4 | 2.4 | 8.1 |
Polymer | Yield of Insoluble Fraction, % | Swelling Value in Acetone | Swelling Value in Toluene | Tdec.−15%, °C * | Tg, °C ** |
---|---|---|---|---|---|
C3 | 55 | 168 | 296 | 331 | −29 |
C4 | 59 | 171 | 240 | 344 | −28 |
C5 | 75 | 155 | 240 | 358 | −28 |
C6 | 68 | 152 | 241 | 356 | −27 |
C7 | 67 | 131 | 229 | 354 | −23 |
C8 | 69 | 130 | 192 | 357 | −21 |
C9 | 83 | 119 | 139 | 365 | −19 |
C10 | 82 | 120 | 142 | 364 | −20 |
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Jaras, J.; Navaruckiene, A.; Ostrauskaite, J. Thermoresponsive Shape-Memory Biobased Photopolymers of Tetrahydrofurfuryl Acrylate and Tridecyl Methacrylate. Materials 2023, 16, 2156. https://doi.org/10.3390/ma16062156
Jaras J, Navaruckiene A, Ostrauskaite J. Thermoresponsive Shape-Memory Biobased Photopolymers of Tetrahydrofurfuryl Acrylate and Tridecyl Methacrylate. Materials. 2023; 16(6):2156. https://doi.org/10.3390/ma16062156
Chicago/Turabian StyleJaras, Justinas, Aukse Navaruckiene, and Jolita Ostrauskaite. 2023. "Thermoresponsive Shape-Memory Biobased Photopolymers of Tetrahydrofurfuryl Acrylate and Tridecyl Methacrylate" Materials 16, no. 6: 2156. https://doi.org/10.3390/ma16062156