Preparation and Characterization of Mesocarbon Microbeads by the Co-Polycondensation of High-Temperature Coal Tar Pitch and Coal Pyrolytic Extracts
Abstract
:1. Introduction
2. Experimental Sections
2.1. Raw Materials
2.2. Preparation of MCMB
2.3. Characterization
3. Results and Discussion
3.1. Ultimate Analysis of HCTP and CPE
3.2. FTIR Analysis of HCTP and CPE
3.3. Polarized Microstructure of Green MCMBs
3.4. Particle Size of MCMBs
3.5. Surface Morphology of MCMBs
3.6. XRD Analysis of MCMBs
3.7. Raman Analysis of MCMBs
3.8. Alternating Current Impedance Spectrum Analysis of MCMBs
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
- Sun, C.K.; Zhang, X.; Li, C.; Wang, K.; Sun, X.Z.; Ma, Y.W. Recent advances in prelithiation materials and approaches for lithium-ion batteries and capacitors. Energy Storage Mater. 2020, 32, 497–516. [Google Scholar] [CrossRef]
- Zhang, B.; Zhou, J.C.; Sun, X.X.; Luo, B.R.; Li, D.J.; Gu, X.X.; Zhao, Y. Encapsulating Sn(OH)4 Nanoparticles in Micropores of Mesocarbon Microbeads: A New Anode Material for High-Performance Lithium Ion Batteries. Adv. Mater. Technol. 2021, 6, 2000849. [Google Scholar] [CrossRef]
- Zhang, J.; Wang, J.; Shi, Z.Q.; Xu, Z.W. Mesoporous carbon material as cathode for high performance lithium-ion capacitor. Chin. Chem. Lett. 2018, 29, 620–623. [Google Scholar] [CrossRef]
- Muralidharan, N.; Nallathamby, K. In-situ Formed Polar Fe2N/MCMB Hybrid Interlayer for High-Rate Li−S Batteries. Energ. Fuel 2021, 35, 17930–17939. [Google Scholar] [CrossRef]
- Liu, C.; Zheng, H.J.; Yu, K.; Feng, D.M.; Li, H.; Yao, J.J.; Zhang, X.; Ma, T.Y.; Qiu, J.S. Direct synthesis of P/O-enriched pitch-based carbon microspheres from a coordinated emulsification and pre-oxidation towards high-rate potassium-ion batteries. Carbon 2022, 194, 176–184. [Google Scholar] [CrossRef]
- Wang, X.J.; Yao, X.M.; Zhang, H.; Liu, X.J.; Huang, Z.R. Microstructure and Tribological Performance of Mesocarbon Microbead–Silicon Carbide Composites. Materials 2019, 12, 2137. [Google Scholar] [CrossRef] [Green Version]
- Li, H.X.; Shi, W.J.; Zhang, X.H.; Liu, P.X.; Cao, Q.; Jin, L.E. Catalytic hydrolysis of cellulose to total reducing sugars with superior recyclable magnetic multifunctional MCMB-based solid acid as a catalyst. J. Chem. Technol. Biotechnol. 2020, 95, 770–780. [Google Scholar] [CrossRef]
- Wang, J.C.; Zhang, T.Y.; Jiang, S.; Ma, X.Y.; Shao, X.; Liu, Y.W.; Wang, D.; Li, X.G.; Li, B. Controllable self-assembly of BiOI/oxidized mesocarbon microbeads core-shell composites: A novel hierarchical structure facilitated photocatalytic activities. Chem. Eng. Sci. 2020, 221, 115653. [Google Scholar] [CrossRef]
- Bi, H.H.; He, X.J.; Yang, L.; Li, H.Q.; Jin, B.Y.; Qiu, J.S. Interconnected carbon nanocapsules with high N/S co-doping as stable and high-capacity potassium-ion battery anode. J. Energy Chem. 2022, 66, 195–204. [Google Scholar] [CrossRef]
- Zhu, Y.M.; Zhao, X.F.; Gao, L.J.; Lv, J.; Cheng, J.X.; Lai, S.Q. Properties and micro-morphology of primary quinoline insoluble and mesocarbon microbeads. J. Mater. Sci. 2016, 51, 8098–8107. [Google Scholar] [CrossRef]
- Zheng, J.X.; Tian, Y.C.; Hao, B.T.; Dan, Y.; Li, W.H.; Huang, Y.; Gao, F.; Li, D. Preparation of medium and low temperature coal tar-based mesocarbon microbeads. Chem. Ind. Eng. Prog. 2022, 39, 649–657. [Google Scholar]
- Li, L.; Lin, X.C.; He, J.; Zhang, Y.K.; Lv, J.X.; Wang, Y.G. Preparation of mesocarbon microbeads from coal tar pitch with blending of biomass tar pitch. J. Anal. Appl. Pyrol. 2021, 155, 105039. [Google Scholar] [CrossRef]
- Guo, A.J.; Wang, F.; Jiao, S.H.; Ibrahim, U.K.; Liu, D.; Liu, H.; Chen, K.; Wang, Z.X. Preparation of mesocarbon microbeads as anode material for lithium-ion battery by thermal polymerization of a distillate fraction from an FCC slurry oil after hydrofifining with suspended catalyst. Fuel 2020, 276, 118037. [Google Scholar] [CrossRef]
- Gong, X.; Lou, B.; Yu, R.; Zhang, Z.C.; Guo, S.H.; Li, G.; Wu, B.; Liu, D. Carbonization of mesocarbon microbeads prepared from mesophase pitch with different anisotropic contents and their application in lithium-ion batteries. Fuel Process. Technol. 2021, 217, 106832. [Google Scholar] [CrossRef]
- Zhang, D.K.; Zhang, L.Z.; Fang, X.L.; Xu, Z.M.; Sun, X.W.; Zhao, S.Q. Enhancement of mesocarbon microbead (MCMB) preparation through supercritical flfluid extraction and fractionation. Fuel 2019, 237, 753–762. [Google Scholar] [CrossRef]
- Wang, C.Y.; Chen, M.M.; Li, M.W. Pitch-Based Carbon Materials; Chemical Industry Press: Beijing, China, 2018. [Google Scholar]
- Wang, C.Y. Theory and Application of Carbonaceous Mesophase; Science Press Ltd.: Beijing, China, 2015. [Google Scholar]
- Ahamad, S.; Gupta, A. Understanding composition and morphology of solid-electrolyte interphase in mesocarbon microbeads electrodes with nano-conducting additives. Electrochim. Acta 2020, 341, 136015. [Google Scholar] [CrossRef]
- Wang, F.M.; Xing, G.Z.; Xing, X.H.; Jin, L.E.; Xie, X.L.; Cao, Q. Influence of nano-zinc oxide on particle size of mesocarbon microbeads. Carbon Techniq. 2018, 37, 21–25. [Google Scholar] [CrossRef]
- Cheng, Y.L.; Zhang, Q.L.; Fang, C.Q.; Chen, J.; Guo, S.H.; Che, X.C. Controllable morphologies and electrochemical properties of graphitizing MCMB-based hybrids with nanostructure via a simple chemical vapor deposition method. J. Alloys Compound. 2017, 724, 443–449. [Google Scholar] [CrossRef]
- Yan, B.F.; Wang, G.Y. Mechanisms and characteristics of mesocarbon microbeads prepared by co-carbonization of coal tar pitch and direct coal liquefaction residue. Int. J. Coal Sci. Technol. 2019, 6, 633–642. [Google Scholar] [CrossRef] [Green Version]
- Zhu, Y.M.; Zhao, C.L.; Xu, Y.L.; Hu, C.S.; Zhao, X.F. Preparation and Characterization of Coal Pitch-Based Needle Coke (Part I): The Effects of Aromatic Index (fa) in Refined Coal Pitch. Energ. Fuels 2019, 33, 3456–3464. [Google Scholar] [CrossRef]
- Meng, F.R.; Yu, J.L.; Tahmasebi, A.; Han, Y.N.; Zhao, H.; Lucas, J.; Wall, T. Characteristics of Chars from Low-Temperature Pyrolysis of Lignite. Energ. Fuels 2014, 28, 275–284. [Google Scholar] [CrossRef]
- Hu, C.S.; Chu, H.Y.; Zhu, Y.M.; Xu, Y.L.; Cheng, J.X.; Gao, L.J.; Lai, S.Q.; Zhao, X.F. Differences and correlations between microstructure and macroscopic properties of mesophase cokes derived from the components of high temperature coal tar pitch. Fuel 2022, 310, 122330. [Google Scholar] [CrossRef]
- Zhu, Y.M.; Liu, H.M.; Xu, Y.L.; Hu, C.S.; Zhao, C.L.; Cheng, J.X.; Chen, X.X.; Zhao, X.F. Preparation and Characterization of Coal-Pitch-Based Needle Coke (Part III): The Effects of Quinoline Insoluble in Coal Tar Pitch. Energ. Fuels 2020, 34, 8676–8684. [Google Scholar] [CrossRef]
- Guo, L.C.; Jin, L.E.; Zhong, C.G.; Wang, Y.; Cao, Q. Effects of a dioctyl phthalate addition to coal tar pitch on the microstructures and electrochemical properties of derived semi-cokes. New Carbon Mater. 2017, 32, 71–76. [Google Scholar] [CrossRef]
Samples | C/% | H/% | N/% | S/% | O*/% | C/H |
---|---|---|---|---|---|---|
HCTP | 89.56 | 4.12 | 1.14 | 0.61 | 4.57 | 1.81 |
CPE | 84.18 | 4.53 | 1.57 | 0.41 | 9.31 | 1.55 |
Samples | D50 (μm) | D90 (μm) | D(4, 3) (μm) | U* |
---|---|---|---|---|
MCMB-0% | 16.96 | 26.28 | 16.78 | 0.55 |
MCMB-1.5% | 19.83 | 29.78 | 19.41 | 0.50 |
MCMB-3% | 21.63 | 37.20 | 23.86 | 0.72 |
MCMB-5% | 25.60 | 40.57 | 26.20 | 0.58 |
MCMB-7% | 28.64 | 45.93 | 29.97 | 0.60 |
Samples | γ | π | Aγ | Aπ | Ig/% |
---|---|---|---|---|---|
MCMB-0% | 23.57565 | 25.67931 | 6406.26182 | 30,171.5896 | 82.49 |
MCMB-1.5% | 23.7749 | 25.72322 | 7370.29101 | 31,561.16705 | 81.07 |
MCMB-3% | 23.5886 | 25.74459 | 6543.85787 | 32,977.80438 | 83.44 |
MCMB-5% | 23.48543 | 25.61029 | 6742.52079 | 26,262.90231 | 79.57 |
MCMB-7% | 23.64086 | 25.5899 | 7292.6567 | 27,555.09149 | 79.07 |
Samples | ID1 | ID2 | ID3 | ID4 | IG | IG/IAll | ID3/IAll |
---|---|---|---|---|---|---|---|
MCMB-0% | 48,307.03 | 30,446.43 | 36,422.87 | 71,154.28 | 26,150.28 | 12.31 | 17.14 |
MCMB-1.5% | 48,569.87 | 30,117.34 | 38,907.44 | 79,668.92 | 28,547.29 | 12.64 | 17.23 |
MCMB-3% | 48,760.46 | 25,364.84 | 33,454.24 | 64,318.97 | 27,863.58 | 13.95 | 16.75 |
MCMB-5% | 38,189.04 | 22,729.50 | 34,637.22 | 56,431.36 | 23,735.38 | 13.51 | 19.71 |
MCMB-7% | 42,814.085 | 28,622.92 | 33,024.65 | 60,251.85 | 25,688.22 | 13.49 | 17.34 |
Samples | Rs (Ω) | Rct (Ω) | W (Ω)/10−5 |
---|---|---|---|
MCMB-0% | 1.540 | 7.555 | 11.032 |
MCMB-1.5% | 1.489 | 4.941 | 10.952 |
MCMB-3% | 1.410 | 4.677 | 10.764 |
MCMB-5% | 1.472 | 4.981 | 12.840 |
MCMB-7% | 1.500 | 5.988 | 9.459 |
Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. |
© 2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
Share and Cite
Yan, L.; Fang, Y.; Deng, J.; Zhu, Y.; Zhang, Y.; Cheng, J.; Zhao, X. Preparation and Characterization of Mesocarbon Microbeads by the Co-Polycondensation of High-Temperature Coal Tar Pitch and Coal Pyrolytic Extracts. Materials 2022, 15, 5136. https://doi.org/10.3390/ma15155136
Yan L, Fang Y, Deng J, Zhu Y, Zhang Y, Cheng J, Zhao X. Preparation and Characterization of Mesocarbon Microbeads by the Co-Polycondensation of High-Temperature Coal Tar Pitch and Coal Pyrolytic Extracts. Materials. 2022; 15(15):5136. https://doi.org/10.3390/ma15155136
Chicago/Turabian StyleYan, Lidong, Yilin Fang, Jianfeng Deng, Yaming Zhu, Yuzhu Zhang, Junxia Cheng, and Xuefei Zhao. 2022. "Preparation and Characterization of Mesocarbon Microbeads by the Co-Polycondensation of High-Temperature Coal Tar Pitch and Coal Pyrolytic Extracts" Materials 15, no. 15: 5136. https://doi.org/10.3390/ma15155136