The Solvation Effect of C=O Group of Cyclic Anhydrides in Solution
Abstract
:1. Introduction
2. Results and Discussion
2.1. Solvation Effects of Anhydrides in Inert and Aprotic Solvents
2.2. Cooperativity Effects of Anhydrides in Proton Donor Solvents
3. Materials and Methods
3.1. Materials
3.2. Method
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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№ | Solvent | SVW 1 | AA | SA |
---|---|---|---|---|
1 | Triethylamine | 0.66 | 1695 | 1686 |
2 | Diethyl ether | 1.26 | 1694 | 1683 |
3 | Carbon tetrachloride | 1.38 | 1693 | 1682 |
4 | Toluene | 1.63 | 1692 | 1682 |
5 | Tetrahydrofurane | 1.81 | 1692 | 1681 |
6 | Benzene | 2.24 | 1691 | 1680 |
7 | Pyridine | 2.58 | 1690 | 1677 |
8 | Propionitrile | 2.72 | 1689 | 1677 |
9 | 1,2-Dichloroethane | 2.93 | 1689 | 1676 |
10 | Acetonitrile | 3.26 | 1687 | 1674 |
11 | Nitromethane | 3.71 | 1686 | 1673 |
12 | Chloroform | 1.86 | 1683 | 1671 |
13 | Methanol | 2.26 | 1673 | 1667 |
14 | Water | 3.08 | 1664 | 1652 |
Solvent (S) | Alanine Anhydride | Sarcosine Anhydride |
---|---|---|
Chloroform | 1692 (9) | 1681 (10) |
Methanol | 1691 (17) | 1679 (13) |
Water | 1688 (25) | 1675 (23) |
№ | Solvent (S) | SVW | Alanine Anhydride | Sarcosine Anhydride |
---|---|---|---|---|
1 | Carbon tetrachloride | 1.38 | 1677 | 1671 |
2 | Toluene | 1.65 | 1676 | 1670 |
3 | Benzene | 2.24 | 1675 | 1668 |
4 | Acetonitrile | 3.26 | 1672 | 1664 |
5 | Chloroform | 1.81 | 1665 | 1658 |
6 | Methanol | 2.26 | 1673 | 1666 |
Proton Donor (RXH) | AA | SA |
---|---|---|
Chloroform | 1.67 (10.8) | 1.99 (11.5) |
Methanol | 1.10 (1.7) | 1.16 (1.8) |
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Rakipov, I.; Akhmadiyarov, A.; Petrov, A.; Khachatrian, A.; Solomonov, B. The Solvation Effect of C=O Group of Cyclic Anhydrides in Solution. Int. J. Mol. Sci. 2023, 24, 6724. https://doi.org/10.3390/ijms24076724
Rakipov I, Akhmadiyarov A, Petrov A, Khachatrian A, Solomonov B. The Solvation Effect of C=O Group of Cyclic Anhydrides in Solution. International Journal of Molecular Sciences. 2023; 24(7):6724. https://doi.org/10.3390/ijms24076724
Chicago/Turabian StyleRakipov, Ilnaz, Aydar Akhmadiyarov, Artem Petrov, Artashes Khachatrian, and Boris Solomonov. 2023. "The Solvation Effect of C=O Group of Cyclic Anhydrides in Solution" International Journal of Molecular Sciences 24, no. 7: 6724. https://doi.org/10.3390/ijms24076724