Impact of Charge Transfer Complex on the Dielectric Relaxation Processes in Poly(methyl methacrylate) Polymer
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
3.1. Thermogravimetric Analysis
3.2. Kinetic Thermodynamic Study
3.3. Dielectric Polarization and Relaxation Processes
3.4. AC Electrical Conductivity Dispersion
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Compounds | Parameter | r | ||||
---|---|---|---|---|---|---|
E (kJ mol−1) | A (s−1) | ΔS (J mol−1 K−1) | ΔH (kJ mol−1) | ΔG (kJ mol−1) | ||
I | 99 | 3.99 × 108 | −82 | 96 | 138 | 0.9954 |
II | 46 | 2.67 × 104 | −155 | 44 | 99 | 0.9943 |
III | 65 | 4.05 × 1010 | −26 | 54 | 54 | 0.9962 |
Polymer Sheet Sample | Activation Energy (eV) | ||
---|---|---|---|
From ε2 Peak Value | From M2 Peak Value | From tanδ Peak Value | |
Free PMMA | 0.85 | 0.88 | 0.91 |
PMMA-perylene dye | 0.52 | 0.50 | 0.54 |
PMMA-perylene-PA | 0.79 | 0.76 | 0.76 |
PMMA-perylene-I2 | 0.53 | 0.51 | 0.56 |
PMMA-perylene-CLA | 0.74 | 0.76 | 0.74 |
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Alrooqi, A.; Al-Amshany, Z.M.; Al-Harbi, L.M.; Altalhi, T.A.; Refat, M.S.; Hassanien, A.M.; Atta, A.A. Impact of Charge Transfer Complex on the Dielectric Relaxation Processes in Poly(methyl methacrylate) Polymer. Molecules 2022, 27, 1993. https://doi.org/10.3390/molecules27061993
Alrooqi A, Al-Amshany ZM, Al-Harbi LM, Altalhi TA, Refat MS, Hassanien AM, Atta AA. Impact of Charge Transfer Complex on the Dielectric Relaxation Processes in Poly(methyl methacrylate) Polymer. Molecules. 2022; 27(6):1993. https://doi.org/10.3390/molecules27061993
Chicago/Turabian StyleAlrooqi, Arwa, Zahra M. Al-Amshany, Laila M. Al-Harbi, Tariq A. Altalhi, Moamen S. Refat, A. M. Hassanien, and A. A. Atta. 2022. "Impact of Charge Transfer Complex on the Dielectric Relaxation Processes in Poly(methyl methacrylate) Polymer" Molecules 27, no. 6: 1993. https://doi.org/10.3390/molecules27061993