Thermodynamic Assessment of a Solar-Driven Integrated Membrane Reactor for Ethanol Steam Reforming
Abstract
:1. Introduction
2. System Description
3. Theoretical Formulations
4. Results and Discussion
5. Conclusions
- (1)
- An ESR system can improve the conversion rate at relatively low temperatures due to simultaneous separation of hydrogen. The theoretical conversion rate of the membrane reactor at 100 °C with permeate pressure of 0.01 bar is 98.3%, compared with only 14.8% for a traditional reactor configuration.
- (2)
- Solar energy can be utilized efficiently in this system. The first-law thermodynamic efficiency, solar-to-fuel efficiency, and exergy efficiency with separation exergy and ηs→e of 40% are 82.3%, 45.3%, and 70.4%, respectively, at 215 °C and 0.20 bar. Compared with a traditional reactor, the ηHHV,real achieves the largest increment and can reach 12.0% at 130 °C with ηs→e of 40%.
- (3)
- In terms of the environmental performance of this solar-driven ESR system, higher efficiency leads to less fuel consumption and lower CO2 emissions. The SCSR and CDRR can achieve maximums of 101 g·m−2·h−1 and 247 g·m−2·h−1 at 200 °C and 0.20 bar with a corresponding hydrogen generation rate of 22.4 mol·m−2·h−1. The annual SCSR and CDRR are expected to be 201 kg·m−2·y−1 and 493 kg·m−2·y−1.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Wang, H.; Wang, B.; Lundin, S.-T.B.; Kong, H.; Su, B.; Wang, J. Thermodynamic Assessment of a Solar-Driven Integrated Membrane Reactor for Ethanol Steam Reforming. Molecules 2021, 26, 6921. https://doi.org/10.3390/molecules26226921
Wang H, Wang B, Lundin S-TB, Kong H, Su B, Wang J. Thermodynamic Assessment of a Solar-Driven Integrated Membrane Reactor for Ethanol Steam Reforming. Molecules. 2021; 26(22):6921. https://doi.org/10.3390/molecules26226921
Chicago/Turabian StyleWang, Hongsheng, Bingzheng Wang, Sean-Thomas B. Lundin, Hui Kong, Bosheng Su, and Jian Wang. 2021. "Thermodynamic Assessment of a Solar-Driven Integrated Membrane Reactor for Ethanol Steam Reforming" Molecules 26, no. 22: 6921. https://doi.org/10.3390/molecules26226921