Water Pollution and Agriculture Pesticide
Abstract
:1. Introduction
Biopesticides and Nanotechnology
- Microbial pesticides are microorganisms, such as viruses, bacteria, or fungi that prey on the pests that cause harm to crops
- Plant-incorporated pesticides are produced by plants that mostly have been genetically modified.
- Biochemical pesticides are herbal pesticides that have naturally chemicals that possess pest-repelling properties.
2. Water Pollution by Pesticides
Wastewater Treatment
3. Modeling and Simulation
4. Wastewater Treatment Cost
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Conflicts of Interest
References
- The Environmental Impact of Pesticides. Available online: https://www.worldatlas.com/articles/what-is-the-environmental-impact-of-pesticides.html (accessed on 16 June 2022).
- Abdollahdokht, D.; Asadikaram, G.; Abolhassani, M.; Pourghadamyari, H.; Abbasi-Jorjandi, M.; Faramarz, S.; Nematollahi, M.H. Pesticide exposure and related health problems among farmworkers’ children: A case-control study in southeast Iran. Environ. Sci. Pollut. Res. 2021, 28, 57216–57231. [Google Scholar] [CrossRef] [PubMed]
- FAO. The State of Food and Agriculture. 2019. Available online: https://www.tandfonline.com/doi/full/10.1080/23308249.2019.1649634 (accessed on 12 June 2022).
- Brasil, Ministério da Agricultura, P.A. de D.A. Portaria No. 43, de 21 de Fevereiro de 2020, a Technical Report in 4 pages. Available online: http://www.agricultura.gov.br/assuntos/insumos-agropecuarios/insumos-agricolas/agrotoxicos/informacoes-tecnicas (accessed on 6 June 2022).
- Youssef, G.; Younes, R.A.-O. Photocatalytic degradation of atrazine by heteropolyoxotungstates. J. Taibah Univ. Sci. 2019, 13, 274–279. [Google Scholar] [CrossRef]
- Sharma, A.; Kumar, V.; Shahzad, B.; Tanveer, M.; Sidhu, G.P.S.; Handa, N.; Kohli, S.K.; Yadav, P.; Bali, A.S.; Parihar, R.D. Worldwide pesticide usage and its impacts on ecosystem. SN Appl. Sci. 2019, 10, 1446. [Google Scholar] [CrossRef] [Green Version]
- Monneret, C. What is an endocrine disruptor? Comptes. Rendus. Biol. 2017, 340, 403–405. [Google Scholar] [CrossRef] [PubMed]
- Gundogan, K.; Donmez-Altuntas, H.; Hamurcu, Z.; Akbudak, I.H.; Sungur, M.; Bitgen, N.; Baskol, G.; Bayram, F. Evaluation of chromosomal DNA damage, cytotoxicity, cytostasis, oxidative DNA damage and their relationship with endocrine hormones in patients with acute organophosphate poisoning. Mutat. Res. Toxicol. Environ. Mutagen. 2018, 825, 1–7. [Google Scholar] [CrossRef] [PubMed]
- Jokanovi, C.M. Neurotoxic effects of organophosphorus pesticides and possible association with neurodegenerative diseases in man: A review. Toxicology 2018, 410, 125–131. [Google Scholar] [CrossRef]
- Search—Our World in Data. Available online: https://ourworldindata.org (accessed on 15 June 2022).
- Parks, C.; Costenbader, K.; Long, S.; Hofmann, J.; Beane, F.L.; Sandler, D. Pesticide use and risk of systemic autoimmune diseases in the Agricultural Health Study. Environ. Res. 2022, 209, 112862. [Google Scholar] [CrossRef]
- Kim, K.-H.; Kabir, E.; Jahan, S.A. Exposure to pesticides and the associated human health effects. Sci. Total Environ. 2017, 575, 525–535. [Google Scholar] [CrossRef]
- Dereumeaux, C.; Fillol, C.; Quenel, P.; Denys, S. Pesticide exposures for residents living close to agricultural lands: A review. Environ. Int. 2020, 134, 105210. [Google Scholar] [CrossRef]
- Muturi, E.J.; Donthu, R.K.; Fields, C.J.; Moise, I.K.; Kim, C.-H. Effect of pesticides on microbial communities in container aquatic habitats. Sci. Rep. 2017, 7, 44565. [Google Scholar] [CrossRef]
- Wyszkowska, J.; Kucharski, J.; Kucharski, M.; Borowik, A. Effect of cadmium, copper and zinc on plants, soil microorganisms and soil enzymes. J. Elem. 2013, 18, 769–796. [Google Scholar] [CrossRef]
- Mateo-Sagasta, J.; Zadeh, S.M.; Turral, H.; Burke, J. Water Pollution from Agriculture, A Global Review; The Food and Agriculture Organization of the United States: Rome, Italy, 2017. [Google Scholar]
- Norman. List of emerging substances. Network of Reference Laboratories, Research Centers, and related Organizations for Monitoring of Emerging Environmental Substances NORMAN—2016. Available online: www.norman-network.net/?q=node/235 (accessed on 22 June 2022).
- Thebo, A.L.; Drechsel, P.; Lambin, E.F.; Nelson, K.L. A global, spatially explicit assessment of irrigated croplands influenced by urban wastewater flows. Environ. Res. Lett. 2017, 12, 074008. [Google Scholar] [CrossRef]
- Ortiz-Hernández, M.L.; Sánchez-Salinas, E.; Dantán-González, E.; Castrejón-Godínez, M.L. Pesticide biodegradation: Mechanisms, genetics, and strategies to enhance the process. Biodegrad. Life Sci. 2013, 10, 251–287. [Google Scholar] [CrossRef] [Green Version]
- National Research Council. Board on Agriculture. Committee on Long-Range Soil and Water Conservation Policy. In Soil and Water Quality: An Agenda for Agriculture; National Academies Press: Cambridge, MA, USA, 1993. [Google Scholar]
- Ikehata, K.; El-Din, M.G. Aqueous Pesticide Degradation by Ozonation and Ozone-Based Advanced Oxidation Processes: A Review (Part I). Ozone Sci. Eng. 2005, 27, 83–114. [Google Scholar] [CrossRef]
- Agriculture and Agri-Food Canada. Available online: https://agriculture.canada.ca/ (accessed on 2 June 2022).
- Armaan Gvalanim. What Are Biopesticides? Available online: https://www.scienceabc.com/ (accessed on 22 January 2022).
- Pentak, D.; Kozik, V.; Bąk, A.; Dybał, P.; Sochanik, A.; Jampilek, J. Methotrexate and cytarabine—Loaded nanocarriers for multidrug cancer therapy. Spectroscopic study. Molecules 2016, 21, 1689. [Google Scholar] [CrossRef] [Green Version]
- Jampílek, J.; Kráľová, K. Nanobiopesticides in agriculture: State of the art and future opportunities. In Nano-Biopesticides Today and Future Perspectives; Koul, O., Ed.; Elsevier Inc.: Amsterdam, The Netherlands, 2019; pp. 397–447. [Google Scholar]
- Rakshit, A.; Meena, V.S.; Abhilash, P.C.; Sarma, B.K.; Fraceto, L.; Parihar, M.; Singh, A.K. Biopesticides: Volume 2: Advances in Bio-Inoculants; Woodhead Publishing: Sawston, UK, 2021; Available online: https://www.sciencedirect.com/book/9780128233559/biopesticides (accessed on 17 April 2022).
- Abdollahdokht, D.; Gao, Y.; Faramarz, S.; Poustforoosh, A.; Abbasi, M.; Asadikaram, G.; Nematollahi, M.H. Conventional agrochemicals towards nano-biopesticides: An overview on recent advances. Chem. Biol. Technol. Agric. 2022, 9, 13. [Google Scholar] [CrossRef]
- A Snapshot of the World’s Water Quality: Towards a Global Assessment. Nairobi, United Nations Environment Program (UNEP). 2016. Available online: https://wedocs.unep.org/20.500.11822/32729 (accessed on 19 June 2022).
- FAO. Area equipped for irrigation. Infographic. AQUASTAT: FAO’s Information System on Water and Agriculture. Rome, Food and Agriculture Organization of the United Nations (FAO). 2014. Available online: http://www.fao.org/nr/water/aquastat/infographics/Irrigation_eng.pdf (accessed on 19 April 2022).
- Sonawane, H.; Shelke, D.; Chambhare, M.; Dixit, N.; Math, S.; Sen, S.; Borah, S.N.; Islam, N.F.; Joshi, S.J.; Yousaf, B.; et al. Fungi-derived agriculturally important nanoparticles and their application in crop stress management—Prospects and environmental risks. Environ. Res. 2022, 212, 113543. [Google Scholar] [CrossRef]
- Available online: https://agriculture.canada.ca/en/agriculture-and-environment/agriculture-and-water (accessed on 2 June 2022).
- Kole, R.K.; Banerjee, H.; Bhattacharyya, A. Monitoring of market fish samples for Endosulfan and Hexachlorocyclohexane residues in and around Calcutta. Bull. Envirron. Contam. Toxicol. 2001, 67, 554–559. [Google Scholar] [CrossRef]
- Aktar, W.; Sengupta, D.; Chowdhury, A. Impact of pesticides use in agriculture: Their benefits and hazards. Interdiscip. Toxicol. 2009, 2, 1–12. [Google Scholar] [CrossRef] [Green Version]
- European Environment Agency, Pesticides in Rivers, Lakes and Groundwater in Europe, December 2021. Available online: https://www.eea.europa.eu/ims/ (accessed on 12 June 2022).
- Available online: https://link.springer.com/article/10.1007/s10661-015-4287-y#Tab4 (accessed on 6 June 2022).
- DeSimone, L.A.; McMahon, P.B.; Rosen, M.R. The Quality of Our Nation’s Waters—Water Quality in Principal Aquifers of the United States, 1991–2010; Circular 1360; U.S. Geological Survey: Reston, VA, USA, 2014. [Google Scholar]
- Suk, W.A.; Olden, K.; Yang, R.S.H. Chemical mixtures research: Significance and future perspectives. Environ. Health Perspect. 2002, 110, 891–892. [Google Scholar] [CrossRef]
- Close, M.E.; Humphries, B.; Northcott, G. Outcomes of the first combined national survey of pesticides and emerging organic contaminants (EOCs) in groundwater in New Zealand 2018. Sci. Total Environ. 2020, 754, 142005. [Google Scholar] [CrossRef]
- Rosecrans, C.Z.; Musgrove, M. Water Quality of Groundwater Used for Public Supply in Principal Aquifers of the United States; Scientific Investigations Report 2020–5078; U.S. Geological Survey: Reston, VA, USA, 2020. [Google Scholar]
- Wieben, C.M. Estimated Annual Agricultural Pesticide Use by Major Crop or Crop Group for States of the Conterminous United States, 1992–2017; ver. 2.0, May 2020; data release; U.S. Geological Survey: Reston, VA, USA, 2019. [Google Scholar]
- El-Nahhal, I.; El-Nahhal, Y. Pesticide residues in drinking water, their potential risk to human health and removal options. J. Environ. Manag. 2021, 299, 113611. [Google Scholar] [CrossRef]
- Yoon, Y.; Westerhoff, P.; Snyder, S.A.; Wert, E.C.; Yoon, J. Removal of endocrine disrupting compounds and pharmaceuticals by nanofiltration and ultrafiltration membranes. Desalination 2007, 202, 16–23. Available online: https://www.sciencedirect.com/science/article/abs/pii/S0011916406011908 (accessed on 12 June 2022). [CrossRef]
- Margot, J.; Kienle, C.; Magnet, A.; Weil, M.; Rossi, L.; de Alencastro, L.F.; Abegglen, C.; Thonney, D.; Chèvre, N.; Schärer, M.; et al. Treatment of micropollutants in municipal wastewater: Ozone or powdered activated carbon? Sci. Total Environ. 2013, 461–462, 480–498. [Google Scholar] [CrossRef] [PubMed]
- Rodriguez, E.; Campinas, M.; Acero, J.L.; Rosa, M.J. Investigating PPCP removal from wastewater by powdered activated carbon/ultrafiltration. Water Air Soil Pollut. 2016, 227, 177. [Google Scholar] [CrossRef]
- Alves, A.; Ruiz, G.; Nonato, T.; Pelissari, C.; Dervanoski, A.; Sens, M.L. Combined microfiltration and adsorption process applied to public water supply treatment: Water quality influence on pesticides removal. Environ. Technol. 2020, 41, 2382–2392. [Google Scholar] [CrossRef] [PubMed]
- Zhu, C.; Fang, G.; Dionysiou, D.D.; Liu, C.; Gao, J.; Qin, W.; Zhou, D. Efficient transformation of DDTs with persulfate activation by zero-valent iron nanoparticles: A mechanistic study. J. Hazard Mater. 2016, 316, 232–241. [Google Scholar] [CrossRef]
- Marican, A.; Durán-Lara, E. A review on pesticide removal through different processes. Environ. Sci. Pollut. Res. Int. 2018, 25, 2051–2064. [Google Scholar] [CrossRef]
- Derbalah, A.; Sunday, M.; Chidya, R.; Jadoon, W.; Sakugawa, H. Kinetics of photocatalytic removal of imidacloprid from water by advanced oxidation processes with respect to nanotechnology. J. Water Health 2019, 17, 254–265. [Google Scholar] [CrossRef] [Green Version]
- Ormad, M.P.; Miguel, N.; Claver, A.; Matesanz, J.M.; Ovelleiro, J.L. Pesticides removal in the process of drinking water production. Chemosphere 2008, 71, 97–106. [Google Scholar] [CrossRef]
- Jariyal, M.; Jindal, V.; Mandal, K.; Gupta, V.K.; Singh, B. Bioremediation of organophosphorus pesticide phorate in soil by microbial consortia. Ecotoxicol. Environ. Saf. 2018, 159, 310–316. [Google Scholar] [CrossRef]
- Wu, P.; Chen, Z.; Zhang, Y.; Wang, Y.; Zhu, F.; Cao, B.; Jin, L.; Hou, Y.; Wu, Y.; Li, N. Carbaryl waste-water treatment by Rhodopseudomonas sphaeroides. Chemosphere 2020, 233, 597–602. [Google Scholar] [CrossRef]
- Wu, P.; Xie, L.; Mo, W.; Wang, B.; Ge, H.; Sun, X.; Tian, Y.; Zhao, R.; Zhu, F.; Zhang, Y.; et al. The biodegradation of carbaryl in soil with Rhodopseudomonas capsulata in wastewater treatment effluent. J. Environ. Manag. 2019, 249, 109226. [Google Scholar] [CrossRef]
- Escoto, D.F.; Gayer, M.C.; Bianchini, M.C.; da Cruz Pereira, G.; Roehrs, R.; Denardin, E. Use of Pistia stratiotes for phytoremediation of water resources contaminated by clomazone. Chemosphere 2019, 227, 299–304. [Google Scholar] [CrossRef]
- Gahukar, R.T. Integrated Pest Management Current Concepts and Ecological Perspective; Academic Press: Cambridge, MA, USA, 2014; pp. 125–139. ISBN 978-0-12-398529-3. [Google Scholar]
- Lusk, J.L.; Jamal, M.; Kurlander, L.; Roucan, M.; Taulman, L. A Meta-Analysis of Genetically Modified Food Valuation Studies. J. Agric. Resour. Econ. 2005, 30, 28–44. [Google Scholar]
- Borah, D.K.; Bera, M. Watershed-scale hydrologic and nonpoint-source pollution models: Review of applications. Trans. ASAE 2004, 47, 789–803. [Google Scholar] [CrossRef] [Green Version]
- Wang, Q.; Li, S.; Jia, P.; Qi, C.; Ding, F. A review of surface water quality models. Sci. World J. 2013, 2013, 231768. [Google Scholar] [CrossRef] [Green Version]
- Abraha, T.; Al Basir, F.; Obsu, L.L.; Torres, D.F.M. Farming awareness based optimum interventions for crop pest control. Math. Biosci. Eng. 2021, 18, 5364–5391. [Google Scholar] [CrossRef]
- Mandal, D.S.; Chekroun, A.; Samanta, S.; Chattopadhyay, J. A mathematical study of a crop-pest–natural enemy model with Z-type control. Math. Comput. Simul. 2021, 187, 468–488. [Google Scholar] [CrossRef]
- Chowdhury, J.; Al Basir, F.; Takeuchi, Y.; Ghosh, M.; Roy, P.K. A mathematical model for pest management in Jatropha curcas with integrated pesticides—An optimal control approach. Ecol. Complex. 2019, 37, 24–31. [Google Scholar] [CrossRef]
- Pathak, S.; Maiti, A. Pest control using virus as control agent: A mathematical model. Nonlinear Anal. Model. Control 2012, 17, 67–90. [Google Scholar] [CrossRef]
- Jana, S.; Kar, T.K. A mathematical study of a prey–predator model in relevance to pest control. Nonlinear Dyn. 2013, 74, 667–683. [Google Scholar] [CrossRef]
- Zaffaroni, M.; Cunniffe, N.J.; Bevacqua, D. An ecophysiological model of plant–pest interactions: The role of nutrient and water availability. J. R. Soc. Interface 2020, 17, 20200356. [Google Scholar] [CrossRef]
- Shen, Y.; Zhao, E.; Zhang, W.; Baccarelli, A.A.; Gao, F. Predicting pesticide dissipation half-life intervals in plants with machine learning models. J. Hazard. Mater. 2022, 436, 129177. [Google Scholar] [CrossRef]
- Yadav, S.; Kumar, V. A prey–predator model approach to increase the production of crops: Mathematical modeling and qualitative analysis. Int. J. Biomath. 2022, 15, 2250042. [Google Scholar] [CrossRef]
- Holvoet, K.M.A.; Seuntjens, P.; Vanrolleghem, P.A. Vanrolleghema.Monitoring and modeling pesticide fate in surface waters at the catchment scale. Ecol. Model. 2007, 2009, 53–64. [Google Scholar] [CrossRef]
- FAO. Global Livestock Environmental Assessment Model, Model Description, Version 2.0. 2018. Available online: https://www.fao.org/gleam/en (accessed on 16 June 2022).
- Hutson, J.L.; Wagenet, R.J. Chapter 19—An Overview of LEACHM: A Process Based Model of Water and Solute Movement, Transformations, Plant Uptake and Chemical Reactions in the Unsaturated Zone. In Chemical Equilibrium and Reaction Models; SSSA Special Publication: Madison, WI, USA, 1995; Volume 42. [Google Scholar] [CrossRef]
- Abraha, M.; Chen, J.; Hamilton, S.K.; Sciusco, P.; Lei, C.; Shirkey, G.; Yuan, J.; Robertson, G.P. Albedo-induced global warming impact of Conservation Reserve Program grasslands converted to annual and perennial bioenergy crops. Environ. Res. Lett. 2021, 16, 084059. [Google Scholar] [CrossRef]
- Tang, S.; Cheke, R.A. State-dependent impulsive models of integrated pest management (IPM) strategies and their dynamic consequences. J. Math. Biol. 2004, 50, 257–292. [Google Scholar] [CrossRef] [PubMed]
- Wang, X.; Tao, Y.; Song, X. Analysis of pest-epidemic model by releasing diseased pest with impulsive transmission. Nonlinear Dyn. 2011, 65, 175–185. [Google Scholar] [CrossRef]
- Wang, T.; Wang, Y.; Liu, F. Dynamical analysis of a new microbial pesticide model with the Monod growth rate. J. Appl. Math. Comput. 2017, 54, 325–355. [Google Scholar] [CrossRef]
- Sun, S.; Chen, L. Mathematical modelling to control a pest population by infected pests. Appl. Math. Model. 2009, 33, 2864–2873. [Google Scholar] [CrossRef]
- Merritt, W.; Letcher, R.; Jakeman, A. A review of erosion and sediment transport models. Environ. Model. Softw. 2003, 18, 761–799. [Google Scholar] [CrossRef]
- Borah, D.K.; Xia, R.; Bera, M. DWSM—A dynamic watershed simulation model. In Mathematical Models of Small Watershed Hydrology and Applications; Singh, V.P., Frevert, D.K., Eds.; Water Resources Publications: Littleton, CO, USA, 2002; pp. 113–116. [Google Scholar]
- Bingner, R.L.; Theurer, F.D. AnnAGNPS Technical Processes: Documentation Version 2. Available online: http://www.ars.usda.gov/Research/docs.htm?docid=5222-17/01/2007 (accessed on 25 June 2022).
- Donigian, A.S., Jr.; Bicknell, B.R.; Imhoff, J.C. Hydrological simulation program—Fortran (HSPF). In Computer Models of Watershed Hydrology; Singh, V.P., Ed.; Water Resources Publications: Littleton, CO, USA, 1995; pp. 395–442. [Google Scholar]
- Neitsch, S.L.; Arnold, J.G.; Kiniry, J.R.; Williams, J.R.; King, K.W. Soil and Water Assessment Tool User’s Manual: Version 2000; Texas Water Resources Institute: College Station, TX, USA, 2002. [Google Scholar]
- Borah, D.K.; Bera, M. Watershed-scale hydrologic and nonpoint-source pollution models: Review of mathematical bases. Trans. ASAE 2003, 46, 1553–1566. [Google Scholar] [CrossRef] [Green Version]
- Loague, K.; VanderKwaak, J.E. Simulating hydrologic response for the R-5 catchment: Comparison of two models and the impact of the roads. Hydrol. Proc. 2002, 16, 1015–1032. [Google Scholar] [CrossRef]
- Panday, S.; Huyakorn, P.S. A fully coupled physically based spatially distributed model for evaluating surface/subsurface flow. Adv. Water Resour. 2004, 27, 361–382. [Google Scholar] [CrossRef]
- Colautti, D.; Sudicky, E.A.; Sykes, J.F. Impacts of Climate Change on the Surface and Subsurface Hydrology of the Grand River Watershed; American Geophysical Union: Washington, DC, USA, 2005. [Google Scholar]
- Burns, L.A. Exposure Analysis Modeling System (EXAMS): User Manual and System Documentation; EPA/600/R-00/081; U.S. Environmental Protection Agency: Durham, NC, USA, 2000; p. 206. [Google Scholar]
- Mackay, D. Multimedia Environmental Models: The Fugacity Approach, 2nd ed.; Lewis Publishers: Boca Raton, FL, USA, 2001; p. 261. [Google Scholar]
- Brown, L.C.; Barnwell, T.O. The Enhanced Stream Water Quality Models QUAL2E and QUAL2E-UNCAS: Documentation and User Manual; EPA/6003-87/007; US Environmental Protection Agency, Office of Research and Development, Environmental Research Laboratory: Athens, GA, USA, 1987. [Google Scholar]
- Gramatica, P.; Di Guardo, A. Screening of pesticides for environmental partitioning tendency. Chemosphere 2002, 47, 947–956. [Google Scholar] [CrossRef]
- DHI, MIKE 11 User and Reference Manual. 1995. Available online: https://www.sciencedirect.com/science/article/pii/S004565350200007 (accessed on 28 June 2022).
- Wallingford, H.R. Wallingford Software—Software Tools for the Water Industry. Available online: Wateronline.com (accessed on 28 June 2022).
- Reichert, P.; Brochardt, D.; Henze, M.; Rauch, W.; Shanahan, P.; Somlyody, L.; Vanrolleghem, P.A. Scientific and Technical Report No. 12: River Water Quality Model No. 1; IWA Publishing: London, UK, 2001; p. 136. [Google Scholar]
- Wool, T.A.; Ambrose, R.B.; Martin, J.L.; Comer, E.A. WASP6Users Manual; US Environmental Protection Agency: Atlanta, GA, USA, 2001; p. 267. [Google Scholar]
- FOCUS. FOCUS Surface Water Scenarios in the EU Evaluation Process under 91/414/EEC. In Report of the FOCUS Working Group on Surface Water Scenarios; EC Document Reference SANCO/4802/2001-rev.2; European Commission: Brussels, Belgium, 2001; p. 245. [Google Scholar]
- Van den Brink, P.J.; Brown, C.J.; Dubus, I.G. Using the expert model PERPEST to translate measured and predicted pesticide exposure data into ecological risks. Ecol. Model. 2006, 191, 106–117. [Google Scholar] [CrossRef]
- Gallego-Valero, L.; Moral-Parajes, E.; Román-Sánchez, I.M. Wastewater treatment costs: A research overview through bibliometric analysis. Sustainability 2021, 13, 5066. [Google Scholar] [CrossRef]
- How Much Does a Wastewater Treatment System Cost? (Pricing, Factors, etc.). Available online: https://samcotech.com/cost-wastewater-treatment-system/ (accessed on 16 June 2022).
- Big Fish Environmental. Available online: www.mi-wea.org/docs/The%20cost%20of%20Biosolids.pdf (accessed on 16 June 2022).
- Pistocchi, A.; Andersen, H.R.; Bertanza, G.; Brander, A.; Choubert, J.M.; Cimbritz, M.; Drewes, J.E.; Koehler, C.; Krampe, J.; Launay, M.; et al. Thornberg. Treatment of micropollutants in wastewater: Balancing effectiveness, costs and implications. Sci. Total Environ. 2022, 850, 157593. [Google Scholar] [CrossRef]
Pollutant Category | Indicators/Examples’ | Crops | Relative Contribution by: Livestock | A |
---|---|---|---|---|
Nutrients | Primarily nitrogen and phosphorus present in chemical and organic fertilizers as well as animal excreta and normally found in water as nitrate, ammonia, or phosphate | *** | *** | * |
Pesticides | Herbicides, insecticides, fungicides, and bactericides, including organophosphates, carbamates, pyrethroids, organochlorine pesticides, and others (many, such as DDT, are banned in most countries but are still being used illegally and persistently) | *** | _ | _ |
Salts | E.g., ions of sodium, chloride, potassium, magnesium, sulphate, calcium, and bicarbonate. Measured in water, either directly as total dissolved solids or indirectly as electric conductivity | *** | * | * |
Sediment | Measured in water as total suspended solids or nephelometric turbidity units—especially from pond drainage during harvesting | *** | *** | * |
Organic matter | Chemical or biochemical oxygendemanding substances (e.g., organic materials such as plant matter and livestock excreta), which use up dissolved oxygen in water when they degrade | * | *** | ** |
Pathogens | Bacteria and pathogen indicators., e.g., Escherichia coli, total coliforms, faecal coliforms, and enterococci | * | *** | * |
Metals | E.g., selenium, lead, copper, mercury, arsenic, and manganese | * | * | * |
Emerging pollutants | E.g., drug residues, hormones, and feed additives | _ | *** | ** |
Pesticide | Class: Substance |
---|---|
Insecticide | Organochlorine: Endosulfa |
Organophosphate: Diazinon, Malathion, parathion, chloropyrifos | |
Carbamate: Aldicarb, carbofuran, carbary1 | |
Pyrethroid: Deltamethrin, Fenpropathrin | |
Neonicotinoid: Acetamiprid, thiamethoxam | |
Phenylpyrazole degradate: Aldicarb sulfoxide, Endosulfan sulfate | |
Herbiside | Triazine: Atrazine, cyanazine |
Cloroacetamide: alaclor, butachlor, dimethenamid, metolachlor | |
Fungiside | Benzamide: Fluopicolide, zoxamide |
Carboxamide: Boscalid captofol | |
Chlorinated hydrocarbon: Hexachlorbenzene | |
Organophosphate: Edifenphos, iprobenfos | |
Chlorophenyl: Dichloran, quintozene |
Group | Chemical Composition | Characteristics | Effects |
---|---|---|---|
Organochlorine (DDT, aldrin, lindane, chlordane) | Non-polar and lipophilic atoms including carbon, chlorine, hydrogen atoms. | Lipid soluble, toxic to variety of animals and long-term persistence. | Tend to accumulate in fatty tissue of animals, biomagnification effect via food chain. |
Organophosphate (Malathion, diazinon, parathion) | Aliphatic, cyclic, and heterocyclic possess central phosphorus atom in molecule. | Soluble in organic solvent as well as water. Less persistence than chlorinated hydrocarbons. | Tend to infiltrate into aquifers and reach groundwater. Affects central nervous system. |
Pyrethroids (pyrethrins) | Alkaloid obtained from petals of plant species, namely Chysanthemun cinerariefolium. | Less persistent than other pesticides, therefore safest to be used as household insecticides. | Affects nervous system. |
Carbamates (Carbaryl) | Chemical structure based on alkaloid of a plant species, namely Physostigma venenosum. | Relatively low persistence. | Only killed limited spectrum insects but highly toxic to vertebrate species. |
Biological (Becillus thuringiensis, Bt and its subspecies) | Microorganism, viruses, and their metabolic products. | Applied against forest pests (butterflies) and crops. | Affect other caterpillars. |
Description | Model | Reference |
---|---|---|
Crop Pest management and control | Based on IPM * technique | Abraha et al., 2021 [69] |
Optimum control approach | Chowdhury et al., 2019 [61] | |
Prey–predator based | Tang and Cheke, 2005 [70] | |
pest-epidemic model | Wang et al., 2011 [71] | |
microbial pesticide model | Wang et al., 2017 [72] | |
Pest Population control by infected pasts | Sun and Chen, 2009 [73] | |
Watershed model, single-event capabilities | AGNPS | Merritt et al., 2003 [74] |
DWSM | Borah et al., 2002 [75] | |
Long-term effects of hydrological changes and water and soil management practices | AnnAGNPS | Bingner and Theurer, 2001 [76] |
HSPF | Donigian et al., 1995 [77] | |
SWAT | Neitsch et al., 2002 [78] | |
Study of hydrology and non-point source pollution, small watersheds | MIKE SHE | Borah and Bera, 2003 [79] |
Numerical models considering surface and subsurface hydrologic | InHM | Loague and VanderKwaak, 2002 [80] |
MOD-HMS | Panday and Huyakorn, 2004 [81] | |
HydroGeoSphere | Colautti et al., 2005 [82] | |
Concentration of pesticides and their fate in rivers, steady state conditions | EXAMS | Burns, 2000 [83] |
the Mackay Level III Model | Mackay, 2001 [84] | |
QUAL2E | Brown and Barnwell, 1987 [85] | |
principal component analysis | Gramatica and Di Guardo, 2002 [86] | |
Dynamic in-stream water quality models | MIKE11 | DHI 1995 [87] |
ISIS | HR Wallingford and HalcrowUK, 1998 [88] | |
RWQM1 | Reichert et al., 2001 [89] | |
WASP | Wool et al., 2001 [90] | |
Pesticide fate modeling in surface water | TOXSWA | FOCUS, 2001 [91] |
PERPEST | Van den Brink et al., 2006 [92] |
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Rad, S.M.; Ray, A.K.; Barghi, S. Water Pollution and Agriculture Pesticide. Clean Technol. 2022, 4, 1088-1102. https://doi.org/10.3390/cleantechnol4040066
Rad SM, Ray AK, Barghi S. Water Pollution and Agriculture Pesticide. Clean Technologies. 2022; 4(4):1088-1102. https://doi.org/10.3390/cleantechnol4040066
Chicago/Turabian StyleRad, Samira Mosalaei, Ajay K. Ray, and Shahzad Barghi. 2022. "Water Pollution and Agriculture Pesticide" Clean Technologies 4, no. 4: 1088-1102. https://doi.org/10.3390/cleantechnol4040066