A New Approach to the Synthesis of Functionalized Bicyclo[3.2.1]octanes

Ismiev, Arif Idris; Mamedova, Gunay Zakhid; Dotsenko, Victor V.; Aksenov, Nikolai A.; Aksenova, Inna V.; Magerramov, Abel Mamedali

doi:10.3390/ecsoc-22-05794

Open AccessExtended Abstract

A New Approach to the Synthesis of Functionalized Bicyclo[3.2.1]octanes^†

by

Arif Idris Ismiev

¹,

Gunay Zakhid Mamedova

¹,

Victor V. Dotsenko

^2,3,4,*

,

Nikolai A. Aksenov

³,

Inna V. Aksenova

³ and

Abel Mamedali Magerramov

¹

Department of Chemistry, Baku State University, Akademik Zahid Xəlilov küçəsi-23, Baku 1148, Azerbaijan

²

Department of Chemistry and High Technologies, Kuban State University, 149 Stavropolskaya Str., 350040 Krasnodar, Russia

³

Department of Chemistry, North Caucasus Federal University, 1a Pushkina Str., 355009 Stavropol, Russia

⁴

ChemEx Lab, Vladimir Dal’ Lugansk National University, 20A Molodezhny, 91034 Lugansk, Russia

^*

Author to whom correspondence should be addressed.

^†

Presented at the 22nd International Electronic Conference on Synthetic Organic Chemistry, 15 November–15 December 2018; Available Online: https://sciforum.net/conference/ecsoc-22.

Proceedings 2019, 9(1), 1; https://doi.org/10.3390/ecsoc-22-05794

Published: 14 March 2019

(This article belongs to the Proceedings of 22nd International Electronic Conference on Synthetic Organic Chemistry)

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Abstract

The reaction of furfural with secondary amines and isopropyl cyanoacetate leads to the formation of the previously unknown diisopropyl 8-(dialkylamino)-2,4-dicyano-3-(2-furyl)-6- oxobicyclo[3.2.1]octane-2,4-dicarboxylates. The structures of the products were confirmed by NMR and X-ray analysis.

Keywords: furfural; isopropyl cyanoacetate; Stenhouse salt; Nazarov reaction; carbocyclization; bicyclo[3.2.1]octane

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MDPI and ACS Style

Ismiev, A.I.; Mamedova, G.Z.; Dotsenko, V.V.; Aksenov, N.A.; Aksenova, I.V.; Magerramov, A.M. A New Approach to the Synthesis of Functionalized Bicyclo[3.2.1]octanes. Proceedings 2019, 9, 1. https://doi.org/10.3390/ecsoc-22-05794

AMA Style

Ismiev AI, Mamedova GZ, Dotsenko VV, Aksenov NA, Aksenova IV, Magerramov AM. A New Approach to the Synthesis of Functionalized Bicyclo[3.2.1]octanes. Proceedings. 2019; 9(1):1. https://doi.org/10.3390/ecsoc-22-05794

Chicago/Turabian Style

Ismiev, Arif Idris, Gunay Zakhid Mamedova, Victor V. Dotsenko, Nikolai A. Aksenov, Inna V. Aksenova, and Abel Mamedali Magerramov. 2019. "A New Approach to the Synthesis of Functionalized Bicyclo[3.2.1]octanes" Proceedings 9, no. 1: 1. https://doi.org/10.3390/ecsoc-22-05794

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A New Approach to the Synthesis of Functionalized Bicyclo[3.2.1]octanes^†

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A New Approach to the Synthesis of Functionalized Bicyclo[3.2.1]octanes^†