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Abstract

Alkali Activation of Silicate Mine-Tailings: Response to Different Activator Sources †

Fiber and Particle Engineering Research Unit, University of Oulu, 90014 Oulu, Finland
*
Authors to whom correspondence should be addressed.
Presented at the 1st International Conference on Smart Materials for Sustainable Construction—SMASCO 2019, Luleå, Sweden, 10–12 December 2019.
Proceedings 2019, 34(1), 10; https://doi.org/10.3390/proceedings2019034010
Published: 18 November 2019

Abstract

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To attain sustainability in construction industries, it is important to explore industrial side-streams as a potential replacement for traditional construction materials. This will avoid the depletion of natural resources and helps in preserving the environment. In this way, mining industry attracts the attention of scientific community for the huge volume of tailings generated along with the problem of disposal. This paper mainly focuses on silicate tailings (MT) from two different mining sources with high magnesium (HM) and high alumina (HA) content. To study the possibility of using these tailings as precursors in alkali activation, different activators such as, sodium silicate (Na2SiO3), sodium sulphate (Na2SO4) and sodium carbonate (Na2CO3) were employed. It was noted that the mine tailings took longer time to set in case of activators other than sodium silicate. The milled tailings were co-grinded with the respective solid activators (10%) and mixed with 30% of sodium silicate solution (accelerates setting), to make cylindrical paste specimens. The specimens were cured at 60 °C for 24 h. The results shown that tailings rich in magnesium (MT-HM) activated with sodium carbonate gives high early age strength i.e., 60% increase in average strength compared to other activators. Whereas, sodium silicate helped in achieving 10% increase in early age strength of high alumina tailings (MT-HA). However, this was not the case for the later ages. At 7th day of testing, sodium silicate activated MT-HM shown a strength improvement from 2 MPa to 6 MPa with the formation of magnesium silicate hydrate and hydrotalcite. MT-HA activated with sodium sulphate resulted in a maximum strength of 8.5 MPa due to the ettringite and zeolite in the system. Sodium carbonate does not show comparable results at 7th day of testing though it shown improvement in strength with age. It is also important to consider that there are other oxides like calcium and iron present in these tailings which could also have impacted the results.

Acknowledgments

The authors gratefully acknowledge the financial support received from the project “Geomins—Steps towards the use of mine tailings in geopolymer materials,” funded by Academy of Finland (24302993).

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MDPI and ACS Style

Perumal, P.; Illikainen, M. Alkali Activation of Silicate Mine-Tailings: Response to Different Activator Sources. Proceedings 2019, 34, 10. https://doi.org/10.3390/proceedings2019034010

AMA Style

Perumal P, Illikainen M. Alkali Activation of Silicate Mine-Tailings: Response to Different Activator Sources. Proceedings. 2019; 34(1):10. https://doi.org/10.3390/proceedings2019034010

Chicago/Turabian Style

Perumal, Priyadharshini, and Mirja Illikainen. 2019. "Alkali Activation of Silicate Mine-Tailings: Response to Different Activator Sources" Proceedings 34, no. 1: 10. https://doi.org/10.3390/proceedings2019034010

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