Mono-, Bi-, and Tri-Metallic DES Are Prepared from Nb, Zr, and Mo for n-Butane Selective Oxidation via VPO Catalyst
Abstract
:1. Introduction
2. Materials and Methods
2.1. Reagents and Solutions
2.2. Synthesis of DES
2.3. Catalyst Preparation
2.4. Characterization
2.5. Catalyst Activity Tests
2.6. Catalysts Evaluation
3. Results and Discussion
3.1. Characterization of DES
3.1.1. Characterization of Precursors and Catalysts
3.1.2. Performance of Promoted Catalysts
3.2. Discussion
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
- Hansen, B.B.; Spittle, S.; Chen, B.; Poe, D.; Zhang, Y.; Klein, J.M.; Horton, A.; Adhikari, L.; Zelovich, T.; Doherty, B.W.; et al. Deep Eutectic Solvents: A Review of Fundamentals and Applications. Chem. Rev. 2021, 121, 1232–1285. [Google Scholar] [CrossRef]
- Cheng, M.-J.; Goddard, W.A. The Critical Role of Phosphate in Vanadium Phosphate Oxide for the Catalytic Activation and Functionalization of n-Butane to Maleic Anhydride. J. Am. Chem. Soc. 2013, 135, 4600–4603. [Google Scholar] [CrossRef] [PubMed]
- Schulz, C.; Pohl, F.; Driess, M.; Glaum, R.; Rosowski, F.; Frank, B. Selective Oxidation of n-Butane over Vanadium Phosphate Based Catalysts: Reaction Network and Kinetic Analysis. Ind. Eng. Chem. Res. 2019, 58, 2492–2502. [Google Scholar] [CrossRef]
- Letters, C. Polynt plans US maleic anhydride plant. C&EN Glob. Enterp. 2020, 98, 14. [Google Scholar]
- Garside, M. Global Production Capacity of Maleic Anhydride 2018–2023. 2019. Available online: www.statista.com (accessed on 15 April 2021).
- Bordes, E. Crystallochemistry of V—P—O phases and application to catalysis. Catal. Today 1987, 1, 499–526. [Google Scholar] [CrossRef]
- Hutchings, G.J. Heterogeneous catalysts—Discovery and design. J. Mater. Chem. 2009, 19, 1222–1235. [Google Scholar] [CrossRef] [Green Version]
- Dai, F.; Li, Z.; Chen, X.; He, B.; Liu, R.; Zhang, S. Synthesis of vanadium phosphorus oxide catalysts promoted by iron-based ionic liquids and their catalytic performance in selective oxidation of n-butane. Catal. Sci. Technol. 2018, 8, 4515–4525. [Google Scholar] [CrossRef]
- Dong, Y.; Geske, M.; Korup, O.; Ellenfeld, N.; Rosowski, F.; Dobner, C.; Horn, R. What happens in a catalytic fixed-bed reactor for n-butane oxidation to maleic anhydride? Insights from spatial profile measurements and particle resolved CFD simulations. Chem. Eng. J. 2018, 350, 799–811. [Google Scholar] [CrossRef]
- Müller, M.; Kutscherauer, M.; Böcklein, S.; Mestl, G.; Turek, T. Improved Kinetics of n-Butane Oxidation to Maleic Anhydride: The Role of Byproducts. Ind. Eng. Chem. Res. 2021, 60, 218–229. [Google Scholar] [CrossRef]
- Li, X.; Teschner, D.; Streibel, V.; Lunkenbein, T.; Masliuk, L.; Fu, T.; Wang, Y.; Jones, T.; Seitz, F.; Girgsdies, F.; et al. How to control selectivity in alkane oxidation? Chem. Sci. 2019, 10, 2429–2443. [Google Scholar] [CrossRef] [Green Version]
- Dai, F.; Shi, Y.; Zhang, T.; Faizan, M.; Li, Z.; Zhang, R.; Liu, R.; Zhang, S. Phosphorus-Based Ionic Liquid as Dual Function Promoter Oriented Synthesis of Efficient VPO Catalyst for Selective Oxidation of n-butane. Catal. Lett. 2021, 151, 255–266. [Google Scholar] [CrossRef]
- Goo, K.-Z.; Yap, Y.-H.; Lin, K.-S.; Leong, L.-K. Effect of direct ultrasound synthesis via a sesquihydrate route on bismuth-promoted vanadyl pyrophosphate catalysts. J. Chin. Chem. Soc. 2020, 67, 94–102. [Google Scholar] [CrossRef]
- Hamzehlouia, S.; Shabanian, J.; Latifi, M.; Chaouki, J. Effect of microwave heating on the performance of catalytic oxidation of n-butane in a gas-solid fluidized bed reactor. Chem. Eng. Sci. 2018, 192, 1177–1188. [Google Scholar] [CrossRef]
- Wang, X.; Xu, L.; Chen, X.; Ji, W.; Yan, Q.; Chen, Y. Novel modifications in preparing vanadium phosphorus oxides and their applications for partial oxidation of n-butane. J. Mol. Catal. A Chem. 2003, 206, 261–268. [Google Scholar] [CrossRef]
- Zhang, Z.; Guo, J.; Fu, J.; Zheng, L.; Zhu, D.; Xu, Y.; Song, Y. Hydrothermal Syntheses and Crystal Structures of Two New Vanadium Phosphates. J. Clust. Sci. 2012, 23, 177–187. [Google Scholar] [CrossRef]
- Berenguer, R.; Guerrero-Pérez, M.O.; Guzmán, I.; Rodríguez-Mirasol, J.; Cordero, T. Synthesis of Vanadium Oxide Nanofibers with Variable Crystallinity and V5+/V4+ Ratios. ACS Omega 2017, 2, 7739–7745. [Google Scholar] [CrossRef]
- Zazhigalov, V.A.; Diyuk, E.A. Barothermal Synthesis and Catalytic Properties of Vanadium–Phosphorus Oxide Systems in Oxidative Transformations of Butane and Ethane. Theor. Exp. Chem. 2018, 54, 66–72. [Google Scholar] [CrossRef]
- Taufiq-Yap, Y.H.; Nurul Suziana, N.M.; Hussein, M.Z. Influences of the Various Metal Dopants for the Nanosized Vanadium Phosphate Catalysts. Catal. Lett. 2011, 141, 136–148. [Google Scholar] [CrossRef]
- Liu, J.; Wang, F.; Gu, Z.; Xu, X. Vanadium phosphorus oxide catalyst modified by silver doping for mild oxidation of styrene to benzaldehyde. Chem. Eng. J. 2009, 151, 319–323. [Google Scholar] [CrossRef]
- Leong, L.K.; Chin, K.S.; Taufiq-Yap, Y.H. The effect of Bi promoter on vanadium phosphate catalysts synthesized via sesquihydrate route. Cata. Today 2011, 164, 341–346. [Google Scholar] [CrossRef]
- Behera, G.C.; Parida, K.M.; Das, D.P. Facile fabrication of aluminum-promoted vanadium phosphate: A highly active heterogeneous catalyst for isopropylation of toluene to cymene. J. Catal. 2012, 289, 190–198. [Google Scholar] [CrossRef]
- Duarte de Farias, A.M.; Gonzalez, W.D.A.; Pries de Oliveira, P.G.; Eon, J.-G.; Herrmann, J.-M.; Aouine, M.; Loridant, S.; Volta, J.-C. Vanadium Phosphorus Oxide Catalyst Modified by Niobium Doping for Mild Oxidation of n-Butane to Maleic Anhydride. J. Catal. 2002, 208, 238–246. [Google Scholar] [CrossRef]
- Irusta, S.; Boix, A.; Pierini, B.; Caspani, C.; Petunchi, J. Effect of Mo on the Active Sites of VPO Catalysts upon the Selective Oxidation of n-Butane. J. Catal. 1999, 187, 298–310. [Google Scholar] [CrossRef]
- He, B.; Li, Z.; Zhang, H.; Dai, F.; Li, K.; Liu, R.; Zhang, S. Synthesis of Vanadium Phosphorus Oxide Catalysts Assisted by Deep-Eutectic Solvents for n-Butane Selective Oxidation. Ind. Eng. Chem. Res. 2019, 58, 2857–2867. [Google Scholar] [CrossRef]
- He, B.; Li, Y.; Zhang, T.; Shi, Y.; Li, K.; Dai, F.; Zhang, R.; Liu, R.; Zhang, S. Synthesis of Porous and Highly Crystallinity Vanadium Phosphorus Oxide Catalysts by Multifunctional Biomass-Based Deep Eutectic Solvents. J. Phys. Chem. B 2020, 124, 3743–3753. [Google Scholar] [CrossRef]
- Shi, Y.; Dai, F.; Zhang, T.; He, B.; Zhang, R.; Liu, R.; Ren, B. Hydroxyl-Rich Deep Eutectic Solvents Assistant Synthesis of VPO and Its Application in Selective Oxidation of n-Butane. ChemistrySelect 2020, 5, 6907–6917. [Google Scholar] [CrossRef]
- Muzart, J. Ionic Liquids as Solvents for Catalyzed Oxidations of Organic Compounds. Adv. Synth. Catal. 2006, 348, 275–295. [Google Scholar] [CrossRef]
- Dai, C.; Zhang, J.; Huang, C.; Lei, Z. Ionic Liquids in Selective Oxidation: Catalysts and Solvents. Chem. Rev. 2017, 117, 6929–6983. [Google Scholar] [CrossRef]
- Qiao, Y.; Ma, W.; Theyssen, N.; Chen, C.; Hou, Z. Temperature-Responsive Ionic Liquids: Fundamental Behaviors and Catalytic Applications. Chem. Rev. 2017, 117, 6881–6928. [Google Scholar] [CrossRef]
- Liu, Y.; Dai, Z.; Zhang, Z.; Zeng, S.; Li, F.; Zhang, X.; Nie, Y.; Zhang, L.; Zhang, S.; Ji, X. Ionic liquids/deep eutectic solvents for CO2 capture: Reviewing and evaluating. Green Energy Environ. 2021, 6, 314–328. [Google Scholar] [CrossRef]
- Smith, E.L.; Abbott, A.P.; Ryder, K.S. Deep Eutectic Solvents (DESs) and Their Applications. Chem. Rev. 2014, 114, 11060–11082. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Nguyen Dinh, M.T.; Nguyen, T.L.; Phan, M.D.; Nguyen Dinh, L.; Truong, Q.D.; Bordes-Richard, E. Control of the crystal morphology of VOHPO4·0.5H2O precursors prepared via light alcohols-assisted solvothermal synthesis and influence on the selective oxidation of n-butane. J. Catal. 2019, 377, 638–651. [Google Scholar] [CrossRef]
- Weng, W.; Al Otaibi, R.; Alhumaimess, M.; Conte, M.; Bartley, J.K.; Dummer, N.F.; Hutchings, G.J.; Kiely, C.J. Controlling vanadium phosphate catalyst precursor morphology by adding alkane solvents in the reduction step of VOPO4·2H2O to VOHPO4·0.5H2O. J. Mater. Chem. 2011, 21, 16136–16146. [Google Scholar] [CrossRef] [Green Version]
- Wang, P.; Fu, G.; Wan, H. How High Valence Transition Metal Spreads Its Activity over Nonmetal Oxoes: A Proof-of-Concept Study. ACS Catal. 2017, 7, 5544–5548. [Google Scholar] [CrossRef]
- Dummer, N.F.; Bartley, J.K.; Hutchings, G.J. Vanadium Phosphate Materials as Selective Oxidation Catalysts. Adv. Catal. 2011, 54, 189–247. [Google Scholar]
- Okuhara, T.; Misono, M. Key reaction steps and active surface phase of vanadyl pyrophosphate for selective oxidation of butane. Catal. Today 1993, 16, 61–67. [Google Scholar] [CrossRef]
- Schuurman, Y.; Gleaves, J.T. Activation of vanadium phosphorus oxide catalysts for alkane oxidation—The influence of the oxidation-state on catalyst selectivity. Ind. Eng. Chem. Res. 1994, 33, 2935–2941. [Google Scholar] [CrossRef]
- Hutchings, G.J. Chemically Induced Fast Solid-State Transitions of w-VOPO4 in Vanadium Phosphate Catalysts. Science 2006, 313, 1270–1273. [Google Scholar]
Sample | PVPO | PVPO | PVPO | VPO | VPO | VPO |
---|---|---|---|---|---|---|
I(001)/I(130) | FWHM/nm (001) | Crystallite size/nm | I(200)/I(013) | FWHM/nm (200) | Crystallite size/nm | |
Blank | 52.4 | 0.0456 | 18.1 | 78.4 | 0.0456 | 14.5 |
DES-Nb (1:0.5) | 61.3 | 0.0397 | 20.9 | 40.5 | 0.0268 | 18.4 |
DES-Mo (1:0.5) | 82.6 | 0.0268 | 32.2 | 62.4 | 0.0506 | 16.4 |
DES-Zr (1:0.5) | 84.5 | 0.0276 | 31.2 | 57.4 | 0.0558 | 14.8 |
DES-Zr-Mo (1:0.5) | 90.2 | 0.0260 | 33.4 | 55.3 | 0.0494 | 16.8 |
DES-Zr-Nb (1:0.5) | 82.1 | 0.0249 | 35.2 | 53.3 | 0.0470 | 21.9 |
DES-Zr-Mo-Nb (1:0.5) | 95.1 | 0.0226 | 39.5 | 31.5 | 0.0360 | 23.4 |
Catalyst | Acid Sites Distribution, n(NH3)/(mmol/g) | |||
---|---|---|---|---|
Weak (α) | Medium (β) | Strong (λ) | Total | |
Blank | 1.40191 | 4.48255 | – | 5.88446 |
VPO-DES-Zr | 1.26426 | 4.53262 | 4.82319 | 10.620 |
Catalyst | V2p3/2 | O1s | Peak Area of Lat-O (a) | Peak Area of Sur-O (a) | Lat-O/Sur-O | Vox (b) | P/V | |
---|---|---|---|---|---|---|---|---|
531.1 eV | 532.1 eV | 533.2 eV | ||||||
Blank-VPO | 517.45 | 531.67 | 10035.1 | 8903.108 | 4996.28 | 3.79 | 4.150 | 1.561 |
VPO-DES-Nb | 517.02 | 531.26 | 22507.8 | 15029.52 | 7401.14 | 5.07 | 4.136 | 1.552 |
VPO-DES-Mo | 516.57 | 530.81 | 19937.3 | 15750.58 | 8108.17 | 4.40 | 4.136 | 1.545 |
VPO-DES-Zr | 517.40 | 531.62 | 11653.5 | 9694.215 | 5190.03 | 4.11 | 4.150 | 1.462 |
VPO-DES-Zr-Mo | 517.37 | 531.61 | 19168.9 | 16500.02 | 9144.49 | 3.90 | 4.136 | 1.552 |
VPO-DES-Zr-Nb | 517.05 | 531.2 | 22665.2 | 22665.26 | 6880.56 | 6.58 | 4.198 | 1.584 |
VPO-DES-Zr-Mo-Nb | 517.4 | 531.7 | 17999.6 | 15427.97 | 7232.43 | 4.62 | 4.096 | 1.573 |
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Faizan, M.; Niazi, K.U.K.; Nawaz, H.; Muhammad, N.; Li, H.; Dai, F.; Zhang, R.; Liu, R.; Zhang, S. Mono-, Bi-, and Tri-Metallic DES Are Prepared from Nb, Zr, and Mo for n-Butane Selective Oxidation via VPO Catalyst. Processes 2021, 9, 1487. https://doi.org/10.3390/pr9091487
Faizan M, Niazi KUK, Nawaz H, Muhammad N, Li H, Dai F, Zhang R, Liu R, Zhang S. Mono-, Bi-, and Tri-Metallic DES Are Prepared from Nb, Zr, and Mo for n-Butane Selective Oxidation via VPO Catalyst. Processes. 2021; 9(9):1487. https://doi.org/10.3390/pr9091487
Chicago/Turabian StyleFaizan, Muhammad, Kifayat Ullah Khan Niazi, Hasnain Nawaz, Niaz Muhammad, Hao Li, Fei Dai, Ruirui Zhang, Ruixia Liu, and Suojiang Zhang. 2021. "Mono-, Bi-, and Tri-Metallic DES Are Prepared from Nb, Zr, and Mo for n-Butane Selective Oxidation via VPO Catalyst" Processes 9, no. 9: 1487. https://doi.org/10.3390/pr9091487