The Impact of Coal’s Petrographic Composition on Its Suitability for the Gasification Process: The Example of Polish Deposits
Abstract
:1. Introduction
2. Experiment
2.1. Samples
2.2. The Gasification of Coal to Carbon Dioxide
3. The Characteristics of the Examined Coal
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample No | Deposit | Seam No. | Lithotype | Telinite | Collotelinite | Collodetrinite | Vitrodetrinite | Corpogelinite | Gelinite | Macrosporinite | Microsporinite | Cutinite | Resinite | Liptodetrinite | |
1 | Jas-Mos | 510 | Coking coal | 0 | 6.5 | 70 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | |
2 | Vietnam | Anthracite | 0 | 100 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||
3 | Janina | 119/2 | Bright coal | 1.2 | 40.4 | 34.6 | 0.6 | 0.8 | 0.2 | 0.6 | 5.2 | 0.4 | 0.2 | 1.4 | |
4 | Janina | 119/2 | Dull coal | 0.6 | 11.4 | 23 | 3.4 | 0.8 | 1.2 | 2.4 | 16.4 | 1 | 1 | 7.4 | |
5 | Janina | 203/2 | Bright coal | 0.4 | 22.6 | 41 | 1 | 0.4 | 3.4 | 0.8 | 3 | 0.4 | 0.2 | 0.8 | |
6 | Janina | 203/2 | Dull coal | 0.4 | 12 | 36.2 | 2 | 3.2 | 1.6 | 0.6 | 7.8 | 2.2 | 0.4 | 2.8 | |
7 | Bielszowice | 510 | Bright coal | 0.2 | 2.8 | 58.2 | 0.2 | 0.2 | 2.6 | 0.6 | 4.4 | 0.6 | 0.6 | 0 | |
8 | Bielszowice | 510 | Dull coal | 0.6 | 2.6 | 44.6 | 0.4 | 0.4 | 1.8 | 0.6 | 8.8 | 0.2 | 1.2 | 0.4 | |
9 | Bogdanka | 391 | Bright coal | 0 | 6.6 | 76.8 | 0.4 | 0.8 | 0.4 | 0.2 | 4.6 | 1 | 1 | 0.8 | |
10 | Bogdanka | 391 | Dull coal | 0.4 | 4.2 | 40.8 | 1.4 | 0.6 | 0.2 | 2.2 | 13 | 1.2 | 2.2 | 8.8 | |
11 | Bogdanka | 381 | Bright coal | 0.2 | 8.2 | 70.6 | 0.4 | 0.8 | 0.6 | 0.4 | 6.2 | 1.2 | 0.4 | 1.4 | |
12 | Bogdanka | 381 | Dull coal | 0.2 | 3.2 | 46.6 | 0.2 | 2.8 | 1 | 0.6 | 13 | 4.6 | 1 | 6.8 | |
13 | Bogdanka | 385/2 | Bright coal | 0.2 | 16.8 | 54.6 | 0.6 | 2 | 1 | 2.6 | 8.6 | 0.8 | 0.2 | 1.2 | |
14 | Bogdanka | 385/2 | Dull coal | 2.2 | 20.8 | 20.2 | 0.8 | 0.6 | 2.2 | 7.8 | 12.8 | 1.2 | 1.4 | 3.8 | |
15 | Wesoła | 308 | Bright coal | 0.8 | 14.6 | 58.6 | 1 | 3.6 | 0.2 | 1.6 | 5.6 | 1.4 | 0.6 | 0.4 | |
16 | Wesoła | 308 | Dull coal | 0.4 | 2.2 | 31.4 | 1.8 | 2.6 | 1.6 | 3 | 12.4 | 0.8 | 0.2 | 10.4 | |
17 | Bielszowice | 405/2 | Bright coal | 1.8 | 4.8 | 53.6 | 5.8 | 1.2 | 2 | 0.2 | 6.4 | 0.2 | 0.8 | 0.6 | |
18 | Bielszowice | 405/2 | Dull coal | 1 | 4.6 | 30.2 | 2.8 | 1.2 | 2.2 | 1 | 12.8 | 0.6 | 1.6 | 2.6 | |
Sample No | Fusinite | Semifusinite | Funginite | Macrinite | Micrinite | Secretinite | Inertodetrinite | Sulfides | Carbonates | Clay minerals | Vitrinite | Liptinite | Inertinite | Mineral matter | Reflectance % |
1 | 18.5 | 0 | 1.5 | 0 | 0 | 0 | 3 | 0.5 | 0 | 0 | 76.5 | 23 | 0 | 0.5 | 1.1 |
2 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 100 | 0 | 0 | 0 | 2.3 |
3 | 3.6 | 2.4 | 2 | 0.2 | 0.4 | 0.2 | 4.4 | 0.6 | 0 | 0.6 | 77.8 | 13.2 | 7.8 | 1.2 | 0.5 |
4 | 4.2 | 6.6 | 4.6 | 3.8 | 0.4 | 0 | 10.8 | 0.8 | 0 | 0.2 | 40.4 | 30.4 | 28.2 | 1 | 0.5 |
5 | 5.6 | 8.6 | 1.4 | 1 | 0.4 | 0 | 7.4 | 0.6 | 0 | 1 | 68.8 | 24.4 | 5.2 | 1.6 | 0.5 |
6 | 3 | 3.8 | 7.8 | 0.2 | 0.2 | 0.2 | 8 | 1.4 | 0 | 6.2 | 55.4 | 23.2 | 13.8 | 7.6 | 0.5 |
7 | 2 | 2.4 | 10.4 | 3.8 | 0.6 | 0.2 | 9.8 | 0 | 0 | 0.4 | 64.2 | 29.2 | 6.2 | 0.4 | 0.7 |
8 | 3.2 | 2.4 | 8.4 | 4 | 0.2 | 0.2 | 17.6 | 0.6 | 0 | 1.8 | 50.4 | 36 | 11.2 | 2.4 | 0.7 |
9 | 0.2 | 0.8 | 1 | 0.2 | 0.8 | 0 | 1.8 | 2 | 0 | 0.6 | 85 | 4.8 | 7.6 | 2.6 | 0.6 |
10 | 5.6 | 1.6 | 2.4 | 1.2 | 0.4 | 0 | 9.6 | 3.8 | 0 | 0.4 | 47.6 | 20.8 | 27.4 | 4.2 | 0.6 |
11 | 0.6 | 2 | 3 | 0.2 | 0.2 | 0.2 | 2.8 | 0 | 0 | 0.6 | 80.8 | 9 | 9.6 | 0.6 | 0.6 |
12 | 1 | 2.8 | 4.6 | 0.8 | 0.8 | 0 | 9.4 | 0.4 | 0 | 0.2 | 54 | 19.4 | 26 | 0.6 | 0.6 |
13 | 2.4 | 2.2 | 2.8 | 0.4 | 0 | 0.2 | 2.2 | 0.8 | 0 | 0.4 | 75.2 | 10.2 | 13.4 | 1.2 | 0.6 |
14 | 4 | 7.2 | 2.4 | 1 | 1 | 0.2 | 8.8 | 0.2 | 0 | 1.4 | 46.8 | 24.6 | 27 | 1.6 | 0.6 |
15 | 1.8 | 2.4 | 2.4 | 0.2 | 0 | 0 | 1.6 | 0 | 0.4 | 2.8 | 78.8 | 8.4 | 9.6 | 3.2 | 0.6 |
16 | 6.2 | 3 | 6.8 | 1.8 | 0.2 | 0.2 | 13 | 0.4 | 0 | 1.6 | 40 | 31.2 | 26.8 | 2 | 0.6 |
17 | 7 | 3.2 | 5 | 0.6 | 0 | 0 | 6.8 | 0 | 0 | 0 | 69.2 | 22.6 | 8.2 | 0 | 0.7 |
18 | 5 | 5.6 | 8.8 | 3.4 | 0.4 | 0 | 15 | 0 | 0 | 1.2 | 42 | 38.2 | 18.6 | 1.2 | 0.7 |
Sample No. | Moisture, Mtar [%] | Ash Content, Adb [%] | Volatile Matter, Vdaf [%]f | Sulphur Content, Stdb [%] | Net Calorific Value, NCV [MJ/kg] | Carbon Content, Cdaf [%] | Hydrogen Content, Hdaf [%] | Nitrogen Content, Ndaf [%] | Oxygen Content, Odaf [%] |
---|---|---|---|---|---|---|---|---|---|
1 | 0.8 | 6.5 | 21.95 | 1.13 | 32.662 | 89.73 | 4.76 | 1.11 | 3.21 |
2 | 1.3 | 1.2 | 4.16 | 0.3 | 33.936 | 93.87 | 3.17 | 1.01 | 1.64 |
3 | 15.1 | 8.6 | 39.25 | 2.58 | 22.906 | 76.65 | 4.82 | 1.23 | 14.48 |
4 | 12.6 | 6.23 | 40.54 | 1.6 | 24.810 | 77.92 | 5.11 | 1.26 | 14.00 |
5 | 15.8 | 7.75 | 35.36 | 1.38 | 22.970 | 77.59 | 4.71 | 1.15 | 15.05 |
6 | 11.7 | 24.14 | 38.83 | 1.04 | 19.383 | 76.02 | 5.10 | 1.15 | 16.37 |
7 | 1.5 | 3.88 | 27.79 | 0.53 | 32.831 | 87.66 | 4.91 | 1.55 | 5.33 |
8 | 1.1 | 2.92 | 27.96 | 0.64 | 33.193 | 88.22 | 4.93 | 1.58 | 4.61 |
9 | 4 | 8.34 | 39.49 | 3.02 | 28.216 | 80.40 | 5.25 | 2.02 | 9.04 |
10 | 3.3 | 11.25 | 39.77 | 5.28 | 27.702 | 79.38 | 5.37 | 1.81 | 7.48 |
11 | 5.1 | 3.31 | 35.09 | 1.24 | 29.918 | 81.90 | 5.22 | 1.96 | 9.64 |
12 | 4.9 | 3.73 | 35.16 | 1.49 | 29.356 | 81.14 | 5.20 | 1.99 | 10.13 |
13 | 4.3 | 6.02 | 38.02 | 1.34 | 29.300 | 81.21 | 5.38 | 1.71 | 10.27 |
14 | 3.4 | 10.55 | 37.84 | 1.22 | 27.925 | 81.73 | 5.34 | 1.49 | 10.07 |
15 | 6.2 | 10.39 | 39.98 | 0.93 | 23.253 | 74.10 | 4.42 | 1.28 | 19.15 |
16 | 6.2 | 15.14 | 38.19 | 0.72 | 22.589 | 74.07 | 4.47 | 1.30 | 19.31 |
17 | 1.6 | 10.46 | 32.05 | 0.38 | 29.744 | 85.15 | 5.12 | 1.40 | 7.90 |
18 | 1.5 | 10.06 | 33.67 | 0.33 | 30.215 | 85.52 | 5.29 | 1.41 | 7.41 |
Sample No | Temperature | H2 | O2 | CO | CO2 | CO + CO2 | CH4 | N2 | H2S | Gas Density at 25 ° C |
---|---|---|---|---|---|---|---|---|---|---|
°C | % | % | % | % | % | % | % | % | kg/m3 | |
1 | 950 | 8.95 | 0.17 | 20.52 | 67.66 | 88.18 | 0.35 | 2.35 | 0.05 | 1.50 |
1050 | 1.38 | 0.10 | 39.30 | 58.50 | 97.8 | 0.10 | 0.62 | 0.01 | 1.52 | |
2 | 950 | 15.18 | 0.45 | 11.34 | 72.31 | 83.65 | 0.50 | 0.22 | 0.04 | 1.46 |
1050 | 1.55 | 0.21 | 28.15 | 69.88 | 98.03 | 0.01 | 0.20 | 0.01 | 1.59 | |
3 | 950 | 2.16 | 0.14 | 45.68 | 48.24 | 93.92 | 0.25 | 3.53 | 0.02 | 1.44 |
1050 | 1.47 | 0.24 | 75.86 | 16.37 | 92.23 | 0.10 | 5.96 | 0.01 | 1.24 | |
4 | 950 | 2.61 | 0.47 | 52.20 | 42.08 | 94.28 | 0.16 | 2.48 | 0.01 | 1.40 |
1050 | 1.26 | 0.31 | 73.48 | 20.42 | 93.9 | 0.11 | 4.42 | 0.01 | 1.27 | |
5 | 950 | 2.28 | 0.17 | 48.37 | 46.02 | 94.39 | 0.24 | 2.92 | 0.03 | 1.43 |
1050 | 1.63 | 0.26 | 75.29 | 19.09 | 94.38 | 0.09 | 3.64 | 0.01 | 1.25 | |
6 | 950 | 2.67 | 0.36 | 42.21 | 53.37 | 95.58 | 0.19 | 1.20 | 0.01 | 1.47 |
1050 | 1.10 | 0.12 | 60.20 | 36.83 | 97.03 | 0.09 | 1.66 | 0.01 | 1.38 | |
7 | 950 | 2.45 | 0.61 | 22.07 | 67.56 | 89.63 | 0.36 | 6.95 | 0.03 | 1.57 |
1050 | 1.35 | 0.56 | 40.47 | 56.08 | 96.55 | 0.07 | 1.47 | 0.01 | 1.50 | |
8 | 950 | 2.48 | 0.13 | 19.98 | 74.36 | 94.34 | 0.32 | 2.73 | 0.01 | 1.61 |
1050 | 1.21 | 0.16 | 42.56 | 55.03 | 97.59 | 0.14 | 0.90 | 0.01 | 1.50 | |
9 | 950 | 2.48 | 0.41 | 20.78 | 71.85 | 92.63 | 0.48 | 4.00 | 0.06 | 1.59 |
1050 | 1.17 | 0.23 | 38.17 | 49.28 | 87.45 | 0.17 | 10.98 | 0.02 | 1.46 | |
10 | 950 | 3.04 | 0.54 | 26.68 | 66.04 | 92.72 | 0.38 | 3.32 | 0.08 | 1.55 |
1050 | 1.16 | 0.48 | 52.39 | 41.84 | 94.23 | 0.13 | 4.00 | 0.02 | 1.41 | |
11 | 950 | 2.47 | 0.24 | 22.19 | 68.68 | 90.87 | 0.48 | 5.94 | 0.02 | 1.57 |
1050 | 1.19 | 2.97 | 41.43 | 41.27 | 82.7 | 0.14 | 13.00 | 0.01 | 1.41 | |
12 | 950 | 2.45 | 0.16 | 22.39 | 68.62 | 91.01 | 0.47 | 5.91 | 0.04 | 1.57 |
1050 | 1.51 | 1.71 | 45.86 | 42.23 | 88.09 | 0.16 | 8.53 | 0.01 | 1.41 | |
13 | 950 | 2.21 | 2.28 | 26.49 | 56.28 | 82.77 | 0.44 | 12.30 | 0.01 | 1.50 |
1050 | 1.42 | 0.90 | 52.80 | 38.76 | 91.56 | 0.15 | 5.9 | 0.01 | 1.39 | |
14 | 950 | 2.21 | 0.03 | 33.26 | 62.08 | 95.34 | 0.43 | 1.99 | 0.01 | 1.53 |
1050 | 1.43 | 0.04 | 57.02 | 39.81 | 96.83 | 0.18 | 1.52 | 0.01 | 1.39 | |
15 | 950 | 2.07 | 0.03 | 43.48 | 51.95 | 95.43 | 0.29 | 2.18 | 0.02 | 1.47 |
1050 | 1.67 | 0.03 | 73.02 | 22.06 | 95.08 | 0.09 | 3.13 | 0.01 | 1.27 | |
16 | 950 | 2.17 | 0.04 | 43.97 | 51.45 | 95.42 | 0.26 | 2.11 | 0.02 | 1.46 |
1050 | 1.61 | 0.03 | 71.48 | 24.11 | 95.59 | 0.08 | 2.69 | 0.01 | 1.29 | |
17 | 950 | 2.19 | 0.11 | 23.04 | 72.64 | 95.68 | 0.29 | 1.73 | 0.01 | 1.60 |
1050 | 1.18 | 0.01 | 36.18 | 62.10 | 98.28 | 0.14 | 0.39 | 0.00 | 1.54 | |
18 | 950 | 2.42 | 0.02 | 23.65 | 70.64 | 94.29 | 0.36 | 2.91 | 0.01 | 1.59 |
1050 | 1.40 | 0.01 | 43.44 | 54.86 | 98.3 | 0.25 | 0.04 | 0.01 | 1.49 |
Temperature | 600–950 °C | 950–1050 °C | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Gas Component | H2 | O2 | CO | CO2 | CH4 | N2 | H2S | H2 | O2 | CO | CO2 | CH4 | N2 | H2S |
Mt ar [%] | - | - | 0.86 | −0.86 | −0.64 | - | - | - | - | 0.82 | −0.84 | - | - | - |
Adb [%] | - | - | 0.50 | - | −0.53 | - | - | - | - | - | - | - | - | - |
Vdaf [%]f | −0.90 | - | 0.63 | −0.51 | - | - | - | - | - | 0.64 | −0.71 | - | - | - |
St db [%] | - | - | - | - | - | - | - | - | - | - | - | - | - | 0.73 |
NCV [MJ/kg] | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
Cdaf [%] | 0.66 | −0.83 | 0.75 | 0.50 | - | - | - | - | −0.85 | 0.90 | - | - | - | |
Hdaf [%] | −0.77 | - | - | - | - | - | - | - | - | - | - | 0.77 | - | - |
Ndaf [%] | - | - | - | - | 0.60 | 0.58 | - | - | 0.63 | - | - | 0.55 | 0.71 | - |
Odaf [%] | −0.56 | - | 0.88 | −0.81 | −0.59 | - | - | - | - | 0.87 | −0.88 | - | - | - |
Petrographic composition [%] | ||||||||||||||
Telinite | - | - | - | - | - | - | −0.50 | - | - | - | - | - | - | - |
Collotelinite | 0.77 | - | - | - | - | - | - | - | - | - | - | −0.55 | - | - |
Collodetrinite | - | - | - | - | - | - | - | - | - | - | - | - | 0.49 | - |
Vitrodetrinite | - | - | - | - | −0.51 | - | - | - | - | - | - | - | - | - |
Corpogelinite | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
Gelinite | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
Macrosporinite | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
Microsporinite | −0.55 | - | - | - | - | - | - | - | - | - | - | 0.52 | - | - |
Cutinite | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
Resinite | - | - | - | - | - | - | - | - | - | - | - | 0.63 | - | - |
Liptodetrinite | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
Fusinite | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
Semifusinite | - | - | 0.61 | −0.51 | - | - | −0.47 | - | - | 0.55 | −0.48 | - | - | - |
Funginite | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
Macrinite | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
Micrinite | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
Secretinite | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
Inertodetrinite | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
Sulfides | - | - | - | - | - | - | 0.66 | −0.47 | - | - | - | - | - | 0.66 |
Carbonates | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
Clay minerals | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
Vitrinite | 0.52 | - | - | - | - | - | - | - | - | - | - | - | - | - |
Liptinite | - | - | - | - | −0.51 | - | - | - | - | - | - | - | −0.50 | |
Inertinite | −0.47 | - | - | - | - | - | - | - | - | - | - | - | - | - |
Mineral matter | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
Reflectance % | 0.96 | - | −0.55 | - | - | - | - | - | - | −0.55 | 0.61 | −0.49 | - | - |
Gas composition up to 950 °C [%] | ||||||||||||||
H2 | - | - | - | - | - | - | - | - | - | −0.47 | 0.53 | −0.53 | - | - |
O2 | - | - | - | - | - | 0.79 | - | - | - | - | - | - | - | - |
CO | - | - | - | −0.95 | −0.80 | - | - | - | - | 0.97 | −0.92 | - | - | - |
CO2 | - | - | −0.95 | - | 0.70 | - | - | - | - | −0.94 | 0.91 | - | - | - |
CH4 | - | - | −0.80 | 0.70 | - | - | - | - | 0.48 | −0.70 | 0.56 | - | - | - |
N2 | - | 0.79 | - | - | - | - | - | 0.53 | - | - | - | 0.48 | - | |
H2S | - | - | - | - | - | - | - | - | - | - | - | - | - | 0.87 |
Gas composition up to 1050 °C [%] | ||||||||||||||
H2 | - | - | - | - | - | - | - | - | - | - | - | - | - | - |
O2 | - | - | - | - | 0.48 | 0.53 | - | - | - | - | - | - | 0.75 | - |
CO | −0.47 | - | 0.97 | −0.94 | −0.70 | - | - | - | - | - | −0.96 | - | - | - |
CO2 | 0.53 | - | −0.92 | 0.91 | 0.56 | - | - | - | - | −0.96 | - | - | - | - |
CH4 | −0.53 | - | - | - | - | - | - | - | - | - | - | - | - | - |
N2 | - | - | - | - | - | 0.48 | - | - | 0.75 | - | - | - | - | - |
H2S | - | - | - | - | - | - | 0.87 | - | - | - | - | - | - | - |
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Bielowicz, B.; Misiak, J. The Impact of Coal’s Petrographic Composition on Its Suitability for the Gasification Process: The Example of Polish Deposits. Resources 2020, 9, 111. https://doi.org/10.3390/resources9090111
Bielowicz B, Misiak J. The Impact of Coal’s Petrographic Composition on Its Suitability for the Gasification Process: The Example of Polish Deposits. Resources. 2020; 9(9):111. https://doi.org/10.3390/resources9090111
Chicago/Turabian StyleBielowicz, Barbara, and Jacek Misiak. 2020. "The Impact of Coal’s Petrographic Composition on Its Suitability for the Gasification Process: The Example of Polish Deposits" Resources 9, no. 9: 111. https://doi.org/10.3390/resources9090111