Flexible Lead-Free Ba0.5Sr0.5TiO3/0.4BiFeO3-0.6SrTiO3 Dielectric Film Capacitor with High Energy Storage Performance
Abstract
:1. Introduction
2. Materials and Methods
2.1. Film Fabrication
2.2. Characterization
3. Results
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
- Li, Q.; Chen, L.; Gadinski, M.R.; Zhang, S.; Zhang, G.; Li, H.U.; Iagodkine, E.; Haque, A.; Chen, L.-Q.; Jackson, T.N.; et al. Flexible high-temperature dielectric materials from polymer nanocomposites. Nature 2015, 523, 576–579. [Google Scholar] [CrossRef]
- Yan, F.; Bai, H.R.; Zhou, X.F.; Ge, G.L.; Li, G.H.; Shen, B.; Zhai, J.W. Realizing superior energy storage properties in lead-free ceramics via a macro-structure design strategy. J. Mater. Chem. A 2020, 8, 11656. [Google Scholar] [CrossRef]
- Zou, K.; Dan, Y.; Xu, H.; Zhang, Q.; Lu, Y.; Huang, H.; He, Y. Recent Advances in Lead-Free Dielectric Materials for Energy Storage. Mater. Res. Bull. 2019, 113, 190–201. [Google Scholar] [CrossRef]
- Dang, Z.-M.; Yuan, J.-K.; Yao, S.-H.; Liao, R.-J. Flexible nanodielectric materials with high permittivity for power energy storage. Adv. Mater. 2013, 25, 6334–6365. [Google Scholar] [CrossRef]
- Thackeray, M.M.; Wolverton, C.E.; Isaacs, D. Electrical energy storage for transportation- approaching the limits of, and going beyond, lithium-ion batteries. Energy Environ. Sci. 2012, 57, 7854–7863. [Google Scholar] [CrossRef]
- Pan, H.; Ma, J.; Ma, J.; Zhang, Q.H.; Liu, X.Z.; Guan, B.; Gu, L.; Zhang, X.; Zhang, Y.-J.; Li, L.L.; et al. Giant energy density and high efficiency achieved in bismuth ferrite-based film capacitors via domain engineering. Nat. Commun. 2018, 9, 1813. [Google Scholar] [CrossRef] [Green Version]
- Yan, F.; Bai, H.R.; Shi, Y.J.; Ge, G.L.; Zhou, X.F.; Lin, J.F.; Shen, B.; Zhai, J.W. Sandwich structured lead-free ceramics based on Bi0.5Na0.5TiO3 for high energy storage. Chem. Eng. J. 2021, 425, 130669. [Google Scholar] [CrossRef]
- Liu, M.L.; Zhu, H.F.; Zhang, Y.X.; Xue, C.H.; Ouyang, J. Energy Storage Characteristics of BiFeO3/BaTiO3 Bi-Layers Integrated on Si. Materials 2016, 9, 935. [Google Scholar] [CrossRef] [PubMed] [Green Version]
- Yang, L.; Kong, X.; Li, F.; Hao, H.; Cheng, Z.; Liu, H.; Li, J.-F.; Zhang, S. Perovskite lead-free dielectrics for energy storage applications. Prog. Mater. Sci. 2019, 102, 72–108. [Google Scholar] [CrossRef]
- Zhang, Y.; Feng, H.; Wu, X.B.; Wang, L.Z.; Zhang, A.Q.; Xia, T.C.; Dong, H.C.; Li, X.F.; Zhang, L.S. Progress of electrochemical capacitor electrode materials: A review. Int. J. Hydrogen Energy 2009, 34, 4889–4899. [Google Scholar] [CrossRef]
- Yan, F.; Huang, K.W.; Jiang, T.; Zhou, X.F.; Shi, Y.J.; Ge, G.L.; Shen, B.; Zhai, J.W. Significantly enhanced energy storage density and efficiency of BNT-based perovskite ceramics via A-site defect engineering. Energy Storage Mater. 2020, 30, 392–400. [Google Scholar] [CrossRef]
- Cheng, H.B.; Ouyang, J.; Zhang, Y.-X.; Ascienzo, D.; Li, Y.; Zhao, Y.-Y.; Ren, Y.H. Demonstration of ultra-high recyclable energy densities in domain-engineered ferroelectric films. Nat. Commun. 2017, 8, 1999. [Google Scholar] [CrossRef]
- Burn, I.; Smyth, D.M. Energy Storage in Ceramic Dielectrics. J. Mater. Sci. 1972, 7, 339–343. [Google Scholar] [CrossRef]
- Yang, C.H.; Qian, J.; Han, Y.J.; Lv, P.P.; Huang, S.F.; Cheng, X.; Cheng, Z.X. Design of an all-inorganic flexible Na0.5Bi0.5TiO3-based film capacitor with giant and stable energy storage performance. J. Mater. Chem. A 2019, 7, 22366. [Google Scholar] [CrossRef]
- Chen, J.; Wang, Y.F.; Yuan, Q.B.; Xu, X.W.; Niu, Y.J.; Wang, Q.; Wang, H. Multilayered ferroelectric polymer films incorporating low-dielectric constant components for concurrent enhancement of energy density and charge–discharge efficiency. Nano Energy 2018, 54, 288–296. [Google Scholar] [CrossRef]
- Li, H.; Ai, D.; Ren, L.L.; Yao, B.; Han, Z.B.; Shen, Z.H.; Wang, J.J.; Chen, L.-Q.; Wang, Q. Scalable Polymer Nanocomposites with Record High-Temperature Capacitive Performance Enabled by Rationally Designed Nanostructured Inorganic Fillers. Adv. Mater. 2019, 31, 1900875. [Google Scholar] [CrossRef] [PubMed]
- Sun, Z.X.; Wang, L.X.; Liu, M.; Ma, C.R.; Liang, Z.S.; Fan, Q.L.; Lu, L.; Lou, X.J.; Wang, H.; Jia, C.-L. Interface thickness optimization of lead-free oxide multilayer capacitors for high-performance energy storage. J. Mater. Chem. A 2018, 6, 1858–1864. [Google Scholar] [CrossRef]
- Huang, Y.H.; Wang, J.J.; Yang, T.N.; Wu, Y.J.; Chen, X.M.; Chen, L.Q. A thermodynamic potential, energy storage performances, and electrocaloric effects of Ba1-xSrxTiO3 single crystals. Appl. Phys. Lett. 2018, 112, 102901. [Google Scholar] [CrossRef]
- Pan, H.; Li, F.; Liu, Y.; Zhang, Q.; Wang, M.; Lan, S.; Zheng, Y.; Ma, J.; Gu, L.; Shen, Y.; et al. Ultrahigh-energy density lead-free dielectric films via polymorphic nanodomain design. Science 2019, 365, 578–582. [Google Scholar] [CrossRef]
- Yang, X.R.; Li, W.L.; Qiao, Y.L.; Zhang, Y.L.; He, J.; Fei, W.D. High energy-storage density of lead-free (Sr1-1.5xBix)Ti0.99Mn0.01O3 thin films induced by Bi3+-VSr dipolar defects. Phys. Chem. Chem. Phys. 2019, 21, 16359–16366. [Google Scholar] [CrossRef]
- Chen, A.; Zhi, Y. High, Purely Electrostrictive Strain in Lead-Free Dielectrics. Adv. Mater. 2006, 18, 103–106. [Google Scholar]
- Chen, A.; Zhi, Y. Dielectric relaxor and ferroelectric relaxor: Bi-doped paraelectric SrTiO3. J. Appl. Phys. 2002, 91, 1487. [Google Scholar]
- Okhay, O.; Wu, A.Y.; Vilarinho, P.M.; Tkach, A. Dielectric relaxation of Sr1-1.5xBixTiO3 sol-gel thin films. J. Appl. Phys. 2011, 109, 064103. [Google Scholar] [CrossRef]
- Rahimabady, M.; Chen, S.T.; Yao, K.; Tay, F.E.H.; Lu, L. High electric breakdown strength and energy density in vinylidene fluoride oligomer/poly(vinylidene fluoride) blend thin films. Appl. Phys. Lett. 2011, 99, 142901. [Google Scholar] [CrossRef]
- Peng, B.L.; Zhang, Q.; Li, X.; Sun, T.Y.; Fan, H.Q.; Ke, S.M.; Ye, M.; Wang, Y.; Lu, W.; Niu, H.B.; et al. Giant electric energy density in epitaxial lead-free thin films with coexistence of ferroelectrics and antiferroelectrics. Adv. Electron. Mater. 2015, 1, 1500052. [Google Scholar] [CrossRef] [Green Version]
- Chu, B.J.; Zhou, X.; Ren, K.L.; Neese, B.; Lin, M.R.; Wang, Q.; Bauer, F.; Zhang, Q.M. A dielectric polymer with high electric energy density and fast discharge speed. Science 2006, 313, 334. [Google Scholar] [CrossRef]
- Wang, Y.; Zhou, X.; Lin, M.R.; Zhang, Q.M. High-energy density in aromatic polyurea thin films. Appl. Phys. Lett. 2009, 94, 202905. [Google Scholar] [CrossRef]
- Song, B.J.; Wu, S.H.; Li, F.; Chen, P.; Shen, B.; Zhai, J.W. Excellent energy storage density and charge-discharge performance in a novel Bi0.2Sr0.7TiO3-BiFeO3 thin film. J. Mater. Chem. C 2019, 7, 10891–10900. [Google Scholar] [CrossRef]
- Fan, Q.L.; Liu, M.; Ma, C.R.; Wang, L.X.; Ren, S.P.; Lu, L.; Lou, X.J.; Jia, C.-L. Significantly enhanced energy storage density with superior thermal stability by optimizing Ba(Zr0.15Ti0.85)O3/Ba(Zr0.35Ti0.65)O3 multilayer structure. Nano Energy 2018, 51, 539–545. [Google Scholar]
- Peng, B.L.; Zhang, Q.; Li, X.; Sun, T.Y.; Fan, H.Q.; Ke, S.M.; Ye, M.; Wang, Y.; Lu, W.; Niu, H.B.; et al. Large energy storage density and high thermal stability in a highly textured (111)-oriented Pb0.8Ba0.2ZrO3 relaxor thin film with the coexistence of antiferroelectric and ferroelectric phases. ACS Appl. Mater. Interfaces 2015, 7, 13512. [Google Scholar] [CrossRef]
- Lin, Z.J.; Chen, Y.; Liu, Z.; Wang, G.S.; Rémiens, D.; Dong, X.L. Large Energy Storage Density, Low Energy Loss and Highly Stable (Pb0.97La0.02)(Zr0.66Sn0.23Ti0.11)O3 Antiferroelectric Thin-Film Capacitors. J. Eur. Ceram. Soc. 2018, 38, 3177–3181. [Google Scholar] [CrossRef]
- Park, M.H.; Kim, H.J.; Kim, Y.J.; Moon, T.; Kim, K.D.; Hwang, C.S. Thin HfxZr1-xO2 Films: A New Lead-Free System for Electrostatic Supercapacitors with Large Energy Storage Density and Robust Thermal Stability. Adv. Energy Mater. 2014, 4, 1400610. [Google Scholar] [CrossRef]
- Lomenzo, P.D.; Chung, C.-C.; Zhou, C.Z.; Jones, J.L.; Nishida, T. Doped Hf0.5Zr0.5O2 for High Efficiency Integrated Supercapacitors. Appl. Phys. Lett. 2017, 110, 232904. [Google Scholar] [CrossRef]
- Song, D.P.; Yang, J.; Yang, B.B.; Wang, Y.; Chen, L.Y.; Wang, F.; Zhu, X.B. Energy Storage in BaBi4Ti4O15 Thin Films with High Efficiency. J. Appl. Phys. 2019, 125, 134101. [Google Scholar] [CrossRef]
- Chen, P.; Wu, S.H.; Li, P.; Zhai, J.W.; Shen, B. Great enhancement of energy storage density and power density in BNBT/xBFO multilayer thin film hetero-structures. Inorg. Chem. Front. 2018, 5, 2300–2305. [Google Scholar] [CrossRef]
- Yang, C.H.; Lv, P.P.; Qian, J.; Han, Y.J.; Ouyang, J.; Lin, X.J.; Huang, S.F.; Cheng, Z.X. Fatigue-free and bending-endurable flexible Mn-doped Na0.5Bi0.5TiO3-BaTiO3-BiFeO3 film capacitor with an ultrahigh energy storage performance. Adv. Energy Mater. 2019, 9, 1803949. [Google Scholar] [CrossRef]
- Shen, B.Z.; Li, Y.; Hao, X.H. Multifunctional all-inorganic flexible capacitor for energy storage and electrocaloric refrigeration over a broad temperature range based on PLZT 9/65/35 thick films. ACS Appl Mater. Interfaces 2019, 11, 34117–34127. [Google Scholar] [CrossRef] [PubMed]
- Liang, Z.S.; Liu, M.; Shen, L.K.; Lu, L.; Ma, C.R.; Lu, X.L.; Lou, X.J.; Jia, C.-L. All-inorganic flexible embedded thin-film capacitors for dielectric energy storage with high performance. ACS Appl. Mater. Interfaces 2019, 11, 5247. [Google Scholar] [CrossRef]
- Saeed, M.A.; Kang, H.C.; Yoo, K.; Asiam, F.K.; Lee, J.-J.; Shim, J.W. Cosensitization of metal-based dyes for high-performance dye-sensitized photovoltaics under ambient lighting conditions. Dye. Pigment. 2021, 194, 109624. [Google Scholar] [CrossRef]
- Saeed, M.A.; Kim, S.H.; Baek, K.; Hyun, J.K.; Lee, S.Y.; Shim, J.W. PEDOT:PSS: CuNW-based transparent composite electrodes for high-performance and flexible organic photovoltaics under indoor lighting. Appl. Surf. Sci. 2021, 567, 150852. [Google Scholar] [CrossRef]
- Wen, Z.; Wu, D. Ferroelectric Tunnel Junctions: Modulations on the Potential Barrier. Adv. Mater. 2020, 32, 1904123. [Google Scholar] [CrossRef]
- Zhang, Y.T.; Cao, Y.Q.; Hu, H.H.; Wang, X.; Li, P.Z.; Yang, Y.; Zheng, J.; Zhang, C.; Song, Z.Q.; Li, A.D.; et al. Flexible metal-insulator transitions based on van der waals oxide heterostructures. ACS Appl. Mater. Interfaces 2019, 11, 88284–88290. [Google Scholar] [CrossRef]
- Bitla, Y.; Chu, Y.H. MICAtronics: A new platform for flexible X-tronics. FlatChem 2017, 3, 26–42. [Google Scholar] [CrossRef]
- Qian, J.; Han, Y.J.; Yang, C.H.; Lv, P.P.; Zhang, X.F.; Feng, C.; Lin, X.J.; Huang, S.F.; Cheng, X.; Cheng, Z.X. Energy storage performance of flexible NKBT/NKBT-ST multilayer film capacitor by interface engineering. Nano Energy 2020, 74, 104862. [Google Scholar] [CrossRef]
- Chu, Y.H. Van der waals oxide heteroepitaxy. npj Quantum Mater. 2017, 2, 67. [Google Scholar] [CrossRef] [Green Version]
- Lv, P.P.; Yang, C.H.; Qian, J.; Wu, H.T.; Huang, S.F.; Cheng, X.; Cheng, Z.X. Flexible Lead-Free Perovskite Oxide Multilayer Film Capacitor Based on (Na0.8K0.2)0.5Bi0.5TiO3/Ba0.5Sr0.5(Ti0.97Mn0.03)O3 for High-Performance Dielectric Energy Storage. Adv. Energy Mater. 2020, 10, 1904229. [Google Scholar] [CrossRef]
- Yang, C.H.; Qian, J.; Lv, P.P.; Wu, H.T.; Lin, X.J.; Wang, K.; Ouyang, J.; Huang, S.F.; Cheng, X.; Cheng, Z.X. Flexible lead-free BFO-based dielectric capacitor with large energy density, superior thermal stability, and reliable bending endurance. J. Mater. 2020, 6, 200–208. [Google Scholar] [CrossRef]
- Pan, H.; Zeng, Y.; Shen, Y.; Lin, Y.-H.; Ma, J.; Li, L.L.; Nan, C.-W. BiFeO3-SrTiO3 thin film as new lead-free relaxor-ferroelectric capacitor with ultrahigh energy storage performance. J. Mater. Chem. A 2017, 5, 5920. [Google Scholar] [CrossRef]
- Shen, Z.B.; Wang, X.H.; Luo, B.C.; Li, L.T. Correction: BaTiO3-BiYbO3 perovskite materials for energy storage applications. J. Mater. Chem. A 2015, 3, 18146. [Google Scholar] [CrossRef]
- Liang, Z.S.; Ma, C.R.; Shen, L.K.; Lu, L.; Lu, X.L.; Lou, X.J.; Liu, M.; Jia, C.-L. Flexible lead-free oxide film capacitors with ultrahigh energy storage performances in extremely wide operating temperature. Nano Energy 2019, 57, 519–527. [Google Scholar] [CrossRef]
- Johnson, R.W.; Evans, J.L.; Jacobsen, P.; Thompson, J.R.; Christopher, M. The Changing Automotive Environment: High-Temperature Electronics. IEEE Trans. Electron. Packag. Manuf. 2005, 27, 164–176. [Google Scholar] [CrossRef]
- Hengst, S.; Luong-Van, D.M.; Everett, J.R.; Lawrence, J.S.; Ashley, M.C.B.; Castel, D.; Storey, J.W.V. A small, high-efficiency diesel generator for high-altitude use in Antarctica. Int. J. Energy Res. 2010, 34, 827–838. [Google Scholar] [CrossRef]
- Watson, J.; Castro, G. High-Temperature Electronics Pose Design and Reliability Challenges. Analog Dialog. 2012, 46, 1–9. [Google Scholar]
- Han, S.-T.; Zhou, Y.; Roy, V.A.L. Towards the development of flexible non-volatile memories. Adv. Mater. 2013, 25, 5425–5449. [Google Scholar] [CrossRef] [PubMed]
- Zhang, Y.; Shen, L.K.; Liu, M.; Li, X.; Lu, X.L.; Lu, L.; Ma, C.R.; You, C.Y.; Chen, A.P.; Huang, C.W.; et al. Flexible quasi-two-dimensional CoFe2O4 epitaxial thin films for continuous strain tuning of magnetic properties. ACS Nano 2017, 11, 8002–8009. [Google Scholar] [CrossRef]
- Fu, H.X.; Cohen, R.E. Polarization rotation mechanism for ultrahigh electromechanical response in single-crystal piezoelectrics. Nature 2000, 403, 281–283. [Google Scholar] [CrossRef] [PubMed]
Materials | Substrate | Pm-Pr (μC/cm2) | E (kV·cm−1) | Wrec (J·cm−3) | η (%) | T (°C) | Fatigue (Cycles) | Bending Test | Ref. | |
---|---|---|---|---|---|---|---|---|---|---|
organic | P(VDF-TrFE-CTFE) | ~10 | 4000 | 9 | <150 | [19] | ||||
VDF/PVDF | ~8 | 8200 | 27.3 | 67 | <85 | [24,25] | ||||
P(VDF-CTFE) | 9 | 5750 | 17 | [26] | ||||||
P(MDA/MDI) | ~3.2 | 8000 | 12 | >90% | RT-180 | [27] | ||||
inorganic | BST-BF | Pt/Ti/SiO2/Si | ~30 | 4800 | 48.5 | 47.57 | 30–120 | [28] | ||
SBTMO | Pt/Ti/SiO2/Si | 34.3 | 1380 | 24.4 | 87 | 30–110 | [20] | |||
BFO-STO | Nb:SrTiO3 | ~45 | 3850 | 70.3 | 70 | −50–100 | 107 | [6] | ||
BZT/BZT | Nb:SrTiO3 | ~33 | 7500 | 83.9 | 78.4 | −100–200 | 106 | [29] | ||
PBZ | Pt/TiOx/SiO2/Si | 65 | 2801 | 40.18 | 64.1 | −23–250 | [30] | |||
PLZST | (La0.7Sr0.3)MnO3/Al2O3(0001) | 55 | 4000 | 46.3 | 84 | 27–107 | 105 | [31] | ||
HZO | SiO2/Si | 30 | 4500 | 46 | 53 | 25–175 | 109 | [32] | ||
Si-HZO | Si | 3500 | 50 | 80 | 25–125 | 109 | [33] | |||
BBTO | Pt/Si | 40 | 2000 | 43.3 | 87.1 | 20–140 | 108 | [34] | ||
NBT-BT/BFO | Pt/TiOx/SiO2/Si | 43.19 | 2400 | 31.96 | 61 | 25–120 | [35] | |||
Mn:NBT-BT-BFO | Pt/F-mica | 97.8 | 2285 | 81.9 | 64.4 | 25–200 | 109 | r = 2 mm or 103 at r = 4 mm | [36] | |
PLZT | LaNiO3/F-Mica | ~64 | 1998 | 40.2 | 58 | 30–180 | 107 | 2 × 103 at r = 4.5 mm | [37] | |
BZT | Indium Tin Oxide (ITO)/F-mica | ~25 | 4230 | 40.6 | 68.9 | −120–150 | 106 | r = 4 mm or 103 at r = 4 mm | [38] | |
BST/0.4BFO-0.6STO | Pt/F-mica | 56.79 | 3000 | 62 | 74 | −50–200 | 108 | r = 2 mm or 104 at r = 4 mm | This work |
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Wang, W.; Qian, J.; Geng, C.; Fan, M.; Yang, C.; Lu, L.; Cheng, Z. Flexible Lead-Free Ba0.5Sr0.5TiO3/0.4BiFeO3-0.6SrTiO3 Dielectric Film Capacitor with High Energy Storage Performance. Nanomaterials 2021, 11, 3065. https://doi.org/10.3390/nano11113065
Wang W, Qian J, Geng C, Fan M, Yang C, Lu L, Cheng Z. Flexible Lead-Free Ba0.5Sr0.5TiO3/0.4BiFeO3-0.6SrTiO3 Dielectric Film Capacitor with High Energy Storage Performance. Nanomaterials. 2021; 11(11):3065. https://doi.org/10.3390/nano11113065
Chicago/Turabian StyleWang, Wenwen, Jin Qian, Chaohui Geng, Mengjia Fan, Changhong Yang, Lingchao Lu, and Zhenxiang Cheng. 2021. "Flexible Lead-Free Ba0.5Sr0.5TiO3/0.4BiFeO3-0.6SrTiO3 Dielectric Film Capacitor with High Energy Storage Performance" Nanomaterials 11, no. 11: 3065. https://doi.org/10.3390/nano11113065