A Hydrogen-Bromate Flow Battery as a Rechargeable Chemical Power Source
Abstract
:1. Introduction
BrO3− + 5 Br− + 6 H+ = 3 Br2 + 3 H2O in solution
A + Red = P + Ox in solution
2. Materials and Methods
2.1. Design of a Hydrogen-Bromate Redox Flow Battery
2.2. Methods
2.2.1. Electrochemical Methods and Operando-Spectroscopic Control of the Catholyte Composition during Electrochemical Tests of the Hydrogen-Bromate Flow Battery
2.2.2. Impedance Spectroscopy
2.2.3. Cyclic Voltammetry for Assessing the Degradation of the Positive Electrode Material
2.2.4. Investigation of a Hydrogen-Bromate Flow Battery Electrode Polarization
2.2.5. Square-Wave Voltammetry for Evaluating the Crossover of Br-Containing Compounds
3. Results and Discussion
- Charges during the charging and discharging half-cycles, Qcharge and Qdischarge, respectively;
- Average voltage during charging and discharging half-cycles, Ucharge and Udischarge respectively;
- Coulombic efficiency (ηQ)—the ratio of the charge passed during discharge to the charge passed during charge in percent;
- Voltaic efficiency (ηU)—the ratio of the average discharge voltage to the average charge voltage in percent;
- Energy efficiency (ηE) of a hydrogen-bromate flow battery charge—discharge tests—the multiplication product of Coulombic and voltaic efficiencies;
- Capacity utilization (Qdischarge/Qtot)—the ratio of the charge received while discharging the battery to the theoretical charge in percent (6 × F × c × V, where F is Faraday’s constant, c is the concentration of electroactive compounds, V is the electrolyte volume).
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Conflicts of Interest
References
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No. | Qcharge, ×103 Kл | Qdischarge, ×103 C | Ucharge, V | Udischarge, V | ηQ, % | ηU, % | ηE, % | Qdischarge/Qtot, % |
---|---|---|---|---|---|---|---|---|
1 | 3.1 | 1.9 | 1.6 | 1.2 | 61 | 75 | 46 | 90 |
2 | 2.3 | 1.6 | 1.6 | 1.1 | 70 | 69 | 48 | 70 |
3 | 1.1 | 0.9 | 1.6 | 1 | 82 | 62 | 51 | 40 |
4 | 0.5 | 0.4 | 1.5 | 1 | 80 | 67 | 54 | 20 |
Amount of Bromine Atoms Before Cycling, mmol | Amount of Bromine Atoms After Cycling (Figure 5), mmol | Relative Change in Bromine Content, % | |
---|---|---|---|
Catholyte | 3.98 | 3.07 | 77 |
Escaping hydrogen trap | 0 | 0.06 | 1.6 |
Anodic half-cell | 0 | 0.06 | 1.6 |
Total amount of bromine atoms | 3.98 | 3.19 | 80.2 |
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Kartashova, N.V.; Konev, D.V.; Loktionov, P.A.; Glazkov, A.T.; Goncharova, O.A.; Petrov, M.M.; Antipov, A.E.; Vorotyntsev, M.A. A Hydrogen-Bromate Flow Battery as a Rechargeable Chemical Power Source. Membranes 2022, 12, 1228. https://doi.org/10.3390/membranes12121228
Kartashova NV, Konev DV, Loktionov PA, Glazkov AT, Goncharova OA, Petrov MM, Antipov AE, Vorotyntsev MA. A Hydrogen-Bromate Flow Battery as a Rechargeable Chemical Power Source. Membranes. 2022; 12(12):1228. https://doi.org/10.3390/membranes12121228
Chicago/Turabian StyleKartashova, Natalia V., Dmitry V. Konev, Pavel A. Loktionov, Artem T. Glazkov, Olga A. Goncharova, Mikhail M. Petrov, Anatoly E. Antipov, and Mikhail A. Vorotyntsev. 2022. "A Hydrogen-Bromate Flow Battery as a Rechargeable Chemical Power Source" Membranes 12, no. 12: 1228. https://doi.org/10.3390/membranes12121228