Fabricating Homogeneous FeCoCrNi High-Entropy Alloys via SLM In Situ Alloying
Abstract
:1. Introduction
2. Materials and Methods
2.1. Specimens Fabrication
2.2. Testing Methods
2.3. Thermodynamic Calculations
3. Results and Analysis
3.1. Forming Performance
3.2. Microstructure Characterization
3.3. Mechanical Properties
4. Discussion
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Element | Fe | Co | Cr | Ni |
---|---|---|---|---|
Target composition (at %) | 25 | 25 | 25 | 25 |
Target composition (wt %) | 24.76 | 26.13 | 23.07 | 26.04 |
Mixing element weight (g) | 945 | 980 | 873 | 940 |
Melting temperature (°C) | 1538 | 1493 | 1857 | 1453 |
Boiling temperature (°C) | 2750 | 2870 | 2672 | 2732 |
Room temperature density (g/cm3) | 7.87 | 8.90 | 7.19 | 8.91 |
Sample No. | VE (J/mm3) | Laser Power (W) | Scan Speed (mm/s) |
---|---|---|---|
HEA1, HEE1 | 223.21 | 250 | 700 |
HEA2, HEE2 | 178.57 | 200 | 700 |
HEA3, HEE3 | 133.93 | 150 | 700 |
HEA4, HEE4 | 89.29 | 100 | 700 |
HEA5, HEE5 | 173.61 | 250 | 900 |
HEA6, HEE6 | 138.89 | 200 | 900 |
HEA7, HEE7 | 104.17 | 150 | 900 |
HEA8, HEE8 | 69.44 | 100 | 900 |
HEA9, HEE9 | 142.05 | 250 | 1100 |
HEA10, HEE10 | 113.64 | 200 | 1100 |
HEA11, HEE11 | 85.23 | 150 | 1100 |
HEA12, HEE12 | 56.82 | 100 | 1100 |
Sample No. | Element Composition (wt %) | Fe | Co | Cr | Ni | |
---|---|---|---|---|---|---|
- | Target | 24.76 | 26.13 | 23.07 | 26.04 | |
HEE1 | EDS | Region 1 | 25.5 | 26.28 | 19.21 | 29 |
Region 2 | 25.29 | 24.46 | 20.07 | 29.55 | ||
Region 3 | 24.99 | 25.27 | 20.88 | 28.86 | ||
Region 4 | 25.3 | 26.13 | 20.34 | 28.23 | ||
Deviation | 0.02 | −0.02 | −0.13 | 0.11 | ||
HEE5 | EDS | Region 1 | 25.5 | 22.94 | 20.96 | 30.3 |
Region 2 | 26.73 | 21.99 | 19.93 | 31.34 | ||
Region 3 | 27.31 | 22.55 | 21.15 | 29 | ||
Region 4 | 27.34 | 22.47 | 19.22 | 30.96 | ||
Deviation | 0.08 | −0.14 | −0.12 | 0.17 | ||
HEE7 | Spark spectrum | 20.74 | 29.06 | 20.93 | 29 | |
Deviation | −0.16 | +0.11 | −0.09 | +0.11 |
Materials | Process | Tensile Strength (MPa) | Yield Strength (Mpa) | Elongation | Hardness (HV) | Institute |
---|---|---|---|---|---|---|
FeCoCrNi | Elemental powder blended by SLM (173.61 J/mm3) | 679 | 511 | 22.5 | 207 | This work |
FeCoCrNi | Pre-alloyed powder by SLM | 745 | 600 | 32 | 205 | Univ. of Sheffield UK [25] |
Arc melting | 457 | 188 | 50 | 118 | ||
FeCoCrNi | Drop casting | 400 | 165 | 68 | - | Univ. of Science and Technology Beijing [26] |
FeCoCrNi | Casting and rolling | 580 | 205 | 70.3 | - | Oak Ridge National Laboratory [27] |
FeCoCrNi | Powder metallurgy and extrusion | 712.5 | 359 | 56 | - | Central south Univ. [28] |
FeCoCrNiMn | Pre-alloyed FeCoCrNi and elemental Mn powder by SLM | 681 ± 14 | - | 12.5 ± 0.5 | - | Univ. of Birmingham UK [19] |
FeCoCrNiMn | Elemental powder blend by DED | - | 260 | - | 195 | RWTH Aachen Univ. [17] |
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Hou, Y.; Su, H.; Zhang, H.; Wang, X.; Wang, C. Fabricating Homogeneous FeCoCrNi High-Entropy Alloys via SLM In Situ Alloying. Metals 2021, 11, 942. https://doi.org/10.3390/met11060942
Hou Y, Su H, Zhang H, Wang X, Wang C. Fabricating Homogeneous FeCoCrNi High-Entropy Alloys via SLM In Situ Alloying. Metals. 2021; 11(6):942. https://doi.org/10.3390/met11060942
Chicago/Turabian StyleHou, Yaqing, Hang Su, Hao Zhang, Xuandong Wang, and Changchang Wang. 2021. "Fabricating Homogeneous FeCoCrNi High-Entropy Alloys via SLM In Situ Alloying" Metals 11, no. 6: 942. https://doi.org/10.3390/met11060942