Low-Pressure Microwave Plasma Reduction of Iron and Copper Salt Compounds at Low Temperatures for Oxidation State Alteration and Functional Applications
Abstract
:1. Introduction
2. Materials and Methods
3. Results
3.1. Initial Oxidation and Reduction Plasma Tests with Metal Strips
3.2. Reduction of Oxidized Metals in Salt Compounds
3.3. Evaluation of the Reduction of the Low-Pressure Plasma-Treated Metal Salt Layers by XPS
4. Conclusions
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- Microwave ambient air plasma oxidized copper strips, while steel strips remained unchanged.
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- CuCl2 and FeSO4 crystals changed significantly with a Varigon plasma treatment.
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- A time-dependent reduction trend with Varigon plasma was observed on CuCl2 layers with a clear reduction from Cu2+ to Cu+ → hydrogen-containing microwave plasma reduced copper-salt layers.
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- The reduction of base metal salt layers (FeCl3 and FeSO4) in a Varigon plasma was successful by implementing an ambient air plasma pre-treatment → metal compounds with a lower standard electrode potential compared with hydrogen were reduced by hydrogen-containing plasma.
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- Surface activation effects and the influence of ambient air after treatment caused the reduction impact to decrease in the FeSO4 layers.
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- The plasma treatments succeeded at low temperatures between 30 °C and 50 °C.
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Reference | Category | Key Message |
---|---|---|
[1,2] | Basic principles of the redox state of iron and copper | Iron and copper exist in a variety of oxidation states in nature. The most prominent state for iron is iron(III) and for copper copper(II). |
[3,5,9,10] | Parylene–metal multilayer system creation for semiconductor structures | Plasma was used to deposit conducting metal structures in nanometer scale within a semiconductor unit (silicon wafer, interposer, and CMOS) via sputter or beam deposition processes. |
[4,6,7,11] | Parylene–metal material compounds for medical implants | Implants for electric conduction purposes and the increase in fracture resistance were designed from parylene metal multilayer systems. The deposition of metals was realized using sputtering processes. The multilayers are intended for use in retinal, brain, and dental implants. |
[8,12] | Thin metal layers for electronic devices in combination with parylene layers (for references [8,9]) | Metal oxides (Ta2O5, FeOx) as examples of oxidized metals are included in electrical devices for electrowetting and ferromagnetic layers to manipulate exchange bias. |
[13,14,15,16,17,18,19,20,21,25,26,27] | Plasma as a tool for the redox state alteration of metal compounds and thin films | Nanoparticles of various metal compounds (TaC, TaN, Ag, Au, Ir) were mostly synthesized from metal salt solution or directly from the elemental state by the application of plasma technology. This technology also causes reductive changes in thin films of oxidized metals. |
[22,23,24] | Examination of the plasma mode of functioning on several metal compounds | A mixture of argon and hydrogen gases causes the highest change in aluminum surfaces. Atomic hydrogen provides a better plasma reduction effort, and the plasma influences solved metal salts via the generation of hydrogen peroxide, hydroxyl radicals, and hydrated electrons. |
Sample | Cu 2p3 [at.%] | Fe 2p3 [at.%] | O 1s [at.%] | C1s [at.%] |
---|---|---|---|---|
Cu (reference) | 0.55 | 2.01 | 2.10 | |
Cu (air plasma) | 17.80 | 10.27 | 8.38 | |
Fe (reference) | 0.27 | 2.66 | 3.34 | |
Fe (air plasma) | 1.21 | 3.23 | 1.95 |
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Weber, M.; Scheglov, A.; Dörries, W.; Meyer, J.B.; Viöl, W. Low-Pressure Microwave Plasma Reduction of Iron and Copper Salt Compounds at Low Temperatures for Oxidation State Alteration and Functional Applications. Materials 2023, 16, 3221. https://doi.org/10.3390/ma16083221
Weber M, Scheglov A, Dörries W, Meyer JB, Viöl W. Low-Pressure Microwave Plasma Reduction of Iron and Copper Salt Compounds at Low Temperatures for Oxidation State Alteration and Functional Applications. Materials. 2023; 16(8):3221. https://doi.org/10.3390/ma16083221
Chicago/Turabian StyleWeber, Mirco, Anna Scheglov, Wiebke Dörries, Johann Benedikt Meyer, and Wolfgang Viöl. 2023. "Low-Pressure Microwave Plasma Reduction of Iron and Copper Salt Compounds at Low Temperatures for Oxidation State Alteration and Functional Applications" Materials 16, no. 8: 3221. https://doi.org/10.3390/ma16083221