Nitrate-Nitrogen Adsorption Characteristics and Mechanisms of Various Garden Waste Biochars
Abstract
:1. Introduction
2. Materials and Methods
2.1. Biochar Preparation and Characterization
2.2. Adsorption Experiment
2.2.1. Influence of pH
2.2.2. Influence of Contact Time
2.2.3. Influence of Initial Concentration of NO3−–N
2.2.4. Influence of Biochar Dosage
2.3. Calculation and Statistical Methods
3. Results and Discussion
3.1. Biochar Characteristics
3.1.1. Yield, pH and Ash
3.1.2. XRD, FTIR and XPS Analysis
3.1.3. SEM and BET Analysis
3.2. Influence of pH
3.3. Influence of Contact Time
3.4. Influence of Initial Concentration of NO3−–N
3.5. Influence of Biochar Dosage
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Samples | Yield (%) | pH | Ash (%) |
---|---|---|---|
GC300 | 34.89 ± 0.11 j | 7.26 ± 0.06 abc | 11.15 ± 0.17 n |
GC500 | 31.95 ± 0.87 ef | 7.84 ± 0.05 f | 22.29 ± 0.02 o |
GC700 | 25.81 ± 1.42 j | 10.03 ± 0.10 k | 27.93 ± 0.03 p |
RC300 | 25.56 ± 0.54 l | 8.04 ± 0.07 g | 4.40 ± 0.16 d |
RC500 | 19.99 ± 0.94 j | 8.37 ± 0.17 h | 6.15 ± 0.12 h |
RC700 | 16.51 ± 0.66 i | 8.52 ± 0.11 hi | 6.25 ± 0.10 h |
PP300 | 35.67 ± 1.53 f | 7.25 ± 0.06 abc | 4.24 ± 0.12 cd |
PP500 | 28.87 ± 0.75 k | 8.03 ± 0.04 g | 5.90 ± 0.21 g |
PP700 | 26.48 ± 0.46 i | 9.32 ± 0.04 j | 6.78 ± 0.07 j |
AV300 | 47.09 ± 0.23 cd | 7.48 ± 0.07 de | 4.29 ± 0.17 d |
AV500 | 35.57 ± 0.70 h | 7.92 ± 0.14 fg | 6.14 ± 0.03 h |
AV700 | 27.01 ± 0.46 j | 8.64 ± 0.07 i | 6.66 ± 0.06 j |
MA300 | 34.69 ± 0.69 i | 7.20 ± 0.06 ab | 4.34 ± 0.03 d |
MA500 | 32.13 ± 2.68 f | 8.06 ± 0.09 g | 5.65 ± 0.06 f |
MA700 | 21.26 ± 1.10 c | 9.93 ± 0.10 k | 7.26 ± 0.03 k |
PO300 | 32.65 ± 0.04 gh | 7.22 ± 0.07 ab | 3.06 ± 0.05 a |
PO500 | 25.97 ± 0.44 f | 7.50 ± 0.08 e | 3.19 ± 0.04 ab |
PO700 | 25.21 ± 0.37 b | 8.38 ± 0.06 h | 3.25 ± 0.07 b |
PT300 | 26.40 ± 0.39 f | 7.11 ± 0.09 a | 4.10 ± 0.10 c |
PT500 | 19.14 ± 1.39 fg | 7.42 ± 0.09 cde | 5.37 ± 0.02 e |
PT700 | 14.43 ± 0.52 d | 10.03 ± 0.13 k | 7.89 ± 0.09 m |
SL300 | 39.47 ± 0.80 ef | 7.30 ± 0.05 bcd | 4.26 ± 0.04 cd |
SL500 | 28.39 ± 0.54 a | 7.47 ± 0.26 de | 6.45 ± 0.12 i |
SL700 | 23.86 ± 2.14 e | 9.97 ± 0.10 k | 7.45 ± 0.06 l |
Samples | Cellulose (%) | Hemicellulose (%) | Lignin (%) |
---|---|---|---|
GC | 19.30 ± 0.52 a | 24.61 ± 0.70 d | 2.18 ± 0.31 a |
RC | 35.44 ± 0.65 b | 15.66 ± 0.81 ab | 13.81 ± 0.14 b |
PP | 43.79 ± 1.40 d | 23.55 ± 2.48 d | 16.62 ± 0.27 c |
AV | 38.70 ± 0.86 c | 20.15 ± 1.30 c | 22.11 ± 0.71 d |
MA | 40.05 ± 3.19 c | 19.83 ± 3.17 c | 15.72 ± 0.63 c |
PO | 44.73 ± 0.39 d | 14.98 ± 1.46 a | 27.88 ± 1.18 e |
PT | 34.69 ± 0.52 b | 14.59 ± 0.17 a | 22.89 ± 0.33 d |
SL | 34.65 ± 1.31 b | 18.47 ± 0.54 bc | 16.29 ± 0.63 c |
Samples | Specific Surface Area/(m2·g−1) | Total Pore Volume/(cm3·g−1) | Average Pore Diameter/(nm) |
---|---|---|---|
GC300 | 185.232 ± 13.544 g | 0.122 ± 0.013 d | 2.590 ± 0.568 a |
RC300 | 36.772 ± 0.759 e | 0.032 ± 0.005 c | 3.018 ± 0.113 a |
PP300 | 2.616 ± 0.067 ab | 0.007 ± 0.002 a | 12.721 ± 0.917 efg |
AV300 | 1.527 ± 0.090 a | 0.005 ± 0.001 a | 14.678 ± 0.725 g |
MA300 | 2.300 ± 0.126 ab | 0.006 ± 0.002 a | 12.827 ± 0.627 efg |
PO300 | 1.310 ± 0.075 a | 0.005 ± 0.001 a | 13.047 ± 0.942 efg |
PT300 | 1.182 ± 0.148 a | 0.004 ± 0.001 a | 12.652 ± 0.496 defg |
SL300 | 21.549 ± 2.100 d | 0.018 ± 0.004 b | 3.300 ± 0.216 a |
GC500 | 2.285 ± 0.206 ab | 0.005 ± 0.001 a | 12.474 ± 1.000 def |
RC500 | 1.073 ± 0.029 a | 0.006 ± 0.001 a | 22.216 ± 0.484 i |
PP500 | 9.418 ± 1.164 c | 0.020 ± 0.005 b | 8.144 ± 0.239 b |
AV500 | 8.624 ± 1.514 bc | 0.020 ± 0.011 b | 9.636 ± 2.776 bc |
MA500 | 1.774 ± 0.075 a | 0.006 ± 0.002 a | 17.398 ± 1.504 h |
PO500 | 2.460 ± 0.165 | 0.008 ± 0.001 a | 12.686 ± 0.059 defg |
PT500 | 3.179 ± 0.270 ab | 0.009 ± 0.002 a | 10.698 ± 0.928 cd |
SL500 | 2.955 ± 0.115 ab | 0.007 ± 0.002 a | 9.648 ± 0.169 bc |
GC700 | 1.869 ± 0.066 a | 0.008 ± 0.001 a | 13.370 ± 1.610 fg |
RC700 | 0.465 ± 0.032 a | 0.005 ± 0.001 a | 46.413 ± 1.715 k |
PP700 | 51.207 ± 1.710 f | 0.039 ± 0.002 c | 3.217 ± 0.152 a |
AV700 | 10.924 ± 0.197 c | 0.031 ± 0.002 c | 11.082 ± 0.978 cde |
MA700 | 1.703 ± 0.120 a | 0.013 ± 0.002 ab | 25.454 ± 0.651 j |
PO700 | 270.801 ± 9.214 h | 0.155 ± 0.013 e | 2.254 ± 0.291 a |
PT700 | 0.831 ± 0.137 a | 0.006 ± 0.001 a | 24.071 ± 1.108 j |
SL700 | 1.297 ± 0.186 a | 0.008 ± 0.001 a | 22.079 ± 2.216 i |
Samples | Pseudo-First-Order Kinetic Model | Pseudo-Second-Order Kinetic Model | ||||
---|---|---|---|---|---|---|
qe (mg·g−1) | k1 (min−1) | R2 | qe (mg·g−1) | k2 (mg·g−1·min−1) | R2 | |
GC300 | 0.692 | 0.253 | 0.994 | 0.784 | 0.315 | 0.998 |
RC300 | 0.415 | 0.285 | 0.986 | 0.445 | 0.725 | 0.996 |
PP300 | 0.180 | 0.286 | 0.985 | 0.191 | 1.881 | 0.992 |
AV300 | 0.349 | 0.180 | 0.961 | 0.386 | 0.568 | 0.970 |
MA300 | 0.186 | 0.445 | 0.913 | 0.191 | 4.804 | 0.962 |
PO300 | 0.186 | 0.374 | 0.978 | 0.196 | 2.804 | 0.991 |
PT300 | 0.401 | 0.175 | 0.983 | 0.434 | 0.623 | 0.971 |
SL300 | 0.503 | 0.238 | 0.991 | 0.534 | 0.705 | 0.986 |
GC500 | 0.179 | 0.321 | 0.999 | 0.208 | 1.751 | 0.980 |
RC500 | 0.344 | 0.120 | 0.996 | 0.407 | 0.292 | 0.994 |
PP500 | 0.516 | 0.228 | 0.976 | 0.581 | 0.418 | 0.988 |
AV500 | 0.588 | 0.196 | 0.986 | 0.641 | 0.376 | 0.994 |
MA500 | 0.305 | 0.186 | 0.999 | 0.340 | 0.699 | 0.987 |
PO500 | 0.306 | 0.174 | 0.992 | 0.333 | 1.002 | 0.927 |
PT500 | 0.208 | 0.256 | 0.983 | 0.222 | 1.590 | 0.988 |
SL500 | 0.213 | 0.297 | 0.988 | 0.225 | 1.955 | 0.994 |
GC700 | 0.179 | 0.320 | 0.999 | 0.193 | 1.832 | 0.996 |
RC700 | 0.165 | 0.276 | 0.966 | 0.178 | 1.715 | 0.977 |
PP700 | 0.621 | 0.296 | 0.982 | 0.668 | 0.486 | 0.992 |
AV700 | 0.588 | 0.149 | 0.979 | 0.651 | 0.317 | 0.989 |
MA700 | 0.560 | 0.058 | 0.988 | 0.719 | 0.079 | 0.992 |
PO700 | 0.778 | 0.127 | 0.970 | 0.880 | 0.180 | 0.976 |
PT700 | 0.209 | 0.182 | 0.945 | 0.224 | 1.436 | 0.963 |
SL700 | 0.204 | 0.302 | 0.985 | 0.218 | 1.810 | 0.998 |
Samples | Langmuir | Freundlich | Temkin | Dubinin–Radushkevich | |||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
qmax (mg·g−1) | kL (L·mg−1) | R2 | kF (mg·g−1) | 1/n (mg·g−1·min−1) | R2 | a | b | R2 | qmax (mg·g−1) | Β (mol2·kJ−2) | R2 | E (kJ·mol−1) | |
GC300 | 0.723 | 1.139 | 0.988 | 0.451 | 0.091 | 0.966 | 0.477 | 0.050 | 0.849 | 0.717 | 0.287 | 0.980 | 1.320 |
RC300 | 0.395 | 0.439 | 0.906 | 0.153 | 0.230 | 0.966 | 0.163 | 0.052 | 0.930 | 0.353 | 0.153 | 0.726 | 1.809 |
PP300 | 0.197 | 0.118 | 0.961 | 0.031 | 0.459 | 0.950 | 0.033 | 0.029 | 0.888 | 0.157 | 2.303 | 0.803 | 0.466 |
AV300 | 0.127 | 2.770 | 0.243 | 0.087 | 0.201 | 0.461 | 0.061 | 0.058 | 0.857 | 0.263 | 0.412 | 0.422 | 1.101 |
MA300 | 0.184 | 0.937 | 0.954 | 0.092 | 0.198 | 0.972 | 0.063 | 0.051 | 0.901 | 0.246 | 0.408 | 0.503 | 1.107 |
PO300 | 0.211 | 0.210 | 0.967 | 0.052 | 0.349 | 0.935 | 0.008 | 0.069 | 0.923 | 0.256 | 1.738 | 0.634 | 0.536 |
PT300 | 0.447 | 0.208 | 0.947 | 0.085 | 0.429 | 0.765 | 0.116 | 0.060 | 0.920 | 0.361 | 0.691 | 0.876 | 0.851 |
SL300 | 0.466 | 0.065 | 0.341 | 0.042 | 0.043 | 0.538 | 0.022 | 0.078 | 0.359 | 0.432 | 44.930 | 0.690 | 0.105 |
GC500 | 0.187 | 0.188 | 0.894 | 0.063 | 0.223 | 0.734 | 0.059 | 0.025 | 0.810 | 0.178 | 2.527 | 0.961 | 0.445 |
RC500 | 0.256 | 0.063 | 0.655 | 0.015 | 0.828 | 0.892 | 0.035 | 0.074 | 0.840 | 0.256 | 4.590 | 0.681 | 0.330 |
PP500 | 0.302 | 2.442 | 0.883 | 0.181 | 0.297 | 0.903 | 0.203 | 0.065 | 0.886 | 0.424 | 0.087 | 0.686 | 2.395 |
AV500 | 0.504 | 0.464 | 0.737 | 0.183 | 0.313 | 0.887 | 0.195 | 0.078 | 0.795 | 0.510 | 0.551 | 0.614 | 0.953 |
MA500 | 0.463 | 0.051 | 0.926 | 0.031 | 0.615 | 0.851 | 0.013 | 0.070 | 0.955 | 0.313 | 3.021 | 0.890 | 0.407 |
PO500 | 0.443 | 0.056 | 0.999 | 0.033 | 0.611 | 0.996 | 0.037 | 0.053 | 0.865 | 0.266 | 2.635 | 0.876 | 0.436 |
PT500 | 0.254 | 0.120 | 0.957 | 0.042 | 0.432 | 0.843 | 0.053 | 0.031 | 0.864 | 0.189 | 1.962 | 0.887 | 0.505 |
SL500 | 0.311 | 0.095 | 0.768 | 0.039 | 0.490 | 0.569 | 0.074 | 0.029 | 0.825 | 0.208 | 1.870 | 0.977 | 0.517 |
GC700 | 0.228 | 0.111 | 0.864 | 0.042 | 0.382 | 0.682 | 0.050 | 0.030 | 0.861 | 0.188 | 2.682 | 0.941 | 0.432 |
RC700 | 0.463 | 0.024 | 0.727 | 0.018 | 0.671 | 0.600 | 0.027 | 0.030 | 0.830 | 0.151 | 2.280 | 0.653 | 0.468 |
PP700 | 0.340 | 10.138 | 0.499 | 0.280 | 0.101 | 0.617 | 0.312 | 0.063 | 0.795 | 0.550 | 0.051 | 0.567 | 3.131 |
AV700 | 0.487 | 0.612 | 0.795 | 0.200 | 0.294 | 0.948 | 0.216 | 0.077 | 0.873 | 0.532 | 0.447 | 0.702 | 1.058 |
MA700 | 0.293 | 0.098 | 0.688 | 0.032 | 0.659 | 0.630 | 0.022 | 0.070 | 0.890 | 0.323 | 3.104 | 0.892 | 0.401 |
PO700 | 1.339 | 0.051 | 0.937 | 0.097 | 0.560 | 0.751 | 0.107 | 0.134 | 0.719 | 0.661 | 2.666 | 0.689 | 0.433 |
PT700 | 0.267 | 0.106 | 0.925 | 0.037 | 0.480 | 0.851 | 0.064 | 0.088 | 0.934 | 0.270 | 2.664 | 0.644 | 0.433 |
SL700 | 0.228 | 0.186 | 0.955 | 0.067 | 0.288 | 0.831 | 0.063 | 0.030 | 0.865 | 0.198 | 2.005 | 0.962 | 0.499 |
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Yao, J.; Wang, Z.; Liu, M.; Bai, B.; Zhang, C. Nitrate-Nitrogen Adsorption Characteristics and Mechanisms of Various Garden Waste Biochars. Materials 2023, 16, 5726. https://doi.org/10.3390/ma16165726
Yao J, Wang Z, Liu M, Bai B, Zhang C. Nitrate-Nitrogen Adsorption Characteristics and Mechanisms of Various Garden Waste Biochars. Materials. 2023; 16(16):5726. https://doi.org/10.3390/ma16165726
Chicago/Turabian StyleYao, Jingjing, Zhiyi Wang, Mengfan Liu, Bing Bai, and Chengliang Zhang. 2023. "Nitrate-Nitrogen Adsorption Characteristics and Mechanisms of Various Garden Waste Biochars" Materials 16, no. 16: 5726. https://doi.org/10.3390/ma16165726