Characterization and Reliability of Caprylic Acid-Stearyl Alcohol Binary Mixture as Phase Change Material for a Cold Energy Storage System
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation of the Binary Mixture Caprylic Acid-Stearyl Alcohol
2.3. Thermophysical Properties Determination
2.4. Thermal Cycling and Compatibility of Caprylic Acid-Stearyl Alcohol
3. Results and Discussion
3.1. Thermal Properties, Thermal and Chemical Stability of the Caprylic Acid-Stearyl Alcohol Binary Mixture
3.2. Accelerated Thermal Cycling of Caprylic Acid-Stearyl Alcohol Binary Mixture
3.3. Corrosion Test of Caprylic Acid-Stearyl Alcohol Binary Mixture
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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PCM Binary Mixture | Eutectic Composition | Melting Point Temperature (℃) | Latent Heat of Fusion (J/g) | Ref. |
---|---|---|---|---|
Capric acid-cetyl alcohol | 70:30 | 22.89 | 144.92 | [19] |
Lauric acid-myristyl alcohol | 40:60 | 22.46 | 151.5 | [20] |
Lauryl-cetyl alcohol | 80:20 | 20.01 | 191.63 | [25] |
Caprylic acid-1-dodecanol | 70:30 | 6.52 | 171.06 | [21] |
Capric acid-dodecanol | 60:40 | 8.9 | 156.6 | [27] |
Caprylic-palmitic acid | 90:10 | 11.33 | 116.47 | [26] |
Capric-lauric acid | 65:35 | 18 | 140.8 | [22] |
Caprylic-nonanoic acid | 81.4:18.6 | 7.6 | 123 | [24] |
Caprylic acid-stearyl alcohol | 90:10 | 11.4 | 154.1 | Present study |
Materials | IUPAC Name | Melting | Solidification | Molar Mass | |||
---|---|---|---|---|---|---|---|
TPeak (°C) | ΔHm (J/g) | TPeak (°C) | ΔHf (J/g) | g/mol | |||
Caprylic acid | Octanoic acid | 18.4 | 142.6 | 4.1 | 154.6 | 144.21 | |
Stearyl alcohol | 1-Octadecanol | 61.4 | 240.7 | 52.4 | 48.1 | 257.9 | 270.49 |
No. of Cycles | Tm °C | Tf °C | ΔHm J/g | ΔHf J/g | RPD of Tm % | RPD of Tf % | RPD of ΔHm % | RPD of ΔHm % |
---|---|---|---|---|---|---|---|---|
0 | 11.4 | 11.8 | 154.4 | 150.5 | ||||
100 | 9.8 | 9.9 | 149.7 | 150.3 | −14.0 | −16.1 | −3.04 | −0.13 |
200 | 10.8 | 11.4 | 125.2 | 124.3 | −5.2 | −3.3 | −18.9 | −17.4 |
mg/cm · Year | mm/Year | Recommendation |
---|---|---|
>1000 | 2 | Completely destroyed within days |
100–999 | 0.1–1.99 | Not recommended for service greater than a month |
50–99 | 0.1–0.19 | Not recommended for service greater than one year |
10–49 | 0.02–0.09 | Caution recommended, based on the specific application |
0.3–9.9 | - | Recommended for long term service |
<0.2 | - | Recommended for long term service; no corrosion, other than as a result of surface cleaning was evidenced |
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Ayaz, H.; Chinnasamy, V.; Cho, H. Characterization and Reliability of Caprylic Acid-Stearyl Alcohol Binary Mixture as Phase Change Material for a Cold Energy Storage System. Materials 2021, 14, 7418. https://doi.org/10.3390/ma14237418
Ayaz H, Chinnasamy V, Cho H. Characterization and Reliability of Caprylic Acid-Stearyl Alcohol Binary Mixture as Phase Change Material for a Cold Energy Storage System. Materials. 2021; 14(23):7418. https://doi.org/10.3390/ma14237418
Chicago/Turabian StyleAyaz, Hamza, Veerakumar Chinnasamy, and Honghyun Cho. 2021. "Characterization and Reliability of Caprylic Acid-Stearyl Alcohol Binary Mixture as Phase Change Material for a Cold Energy Storage System" Materials 14, no. 23: 7418. https://doi.org/10.3390/ma14237418