Scaling Up the Process of Titanium Dioxide Nanotube Synthesis and Its Effect on Photoelectrochemical Properties
Abstract
:1. Introduction
2. Materials and Methods
2.1. Synthesis of TiO2 Nanotubes
2.2. Characterization Techniques
2.2.1. Morphology and Crystal Structure
2.2.2. Photoelectrochemical Measurements
3. Results and Discussion
3.1. Morphology
3.2. UV–Vis and Raman Spectroscopy
3.3. Photoelectrochemical Properties
3.4. The Solar to Hydrogen Conversion Efficiency
3.5. Flat Band Potential and Carrier Density
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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No. | Sample | F (nm) | D (nm) | H (µm) | Sr (cm2) |
---|---|---|---|---|---|
1 | NT4 | 22 | 140 | 2.9 | 80.8 |
2 | NT16 | 25 | 170 | 2.2 | 50.3 |
3 | NT25 | 26 | 180 | 2.1 | 50.2 |
4 | NT36 | 28 | 200 | 1.9 | 36.8 |
5 | NT64 | 26 | 150 | 1.8 | 67.1 |
Electrode | Area | J (µA·cm−2) | η (%) |
---|---|---|---|
NT4 | 1 | 83 | 0.051 |
2 | 81 | 0.050 | |
NT16 | 1 | 80 | 0.049 |
2 | 82 | 0.050 | |
3 | 99 | 0.055 | |
NT25 | 1 | 66 | 0.044 |
2 | 79 | 0.052 | |
3 | 82 | 0.055 | |
NT36 | 1 | 62 | 0.040 |
2 | 63 | 0.040 | |
3 | 75 | 0.048 | |
NT64 | 1 | 62 | 0.039 |
2 | 66 | 0.041 | |
3 | 22 | 0.012 | |
4 | 83 | 0.052 |
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Szkoda, M.; Trzciński, K.; Zarach, Z.; Roda, D.; Łapiński, M.; Nowak, A.P. Scaling Up the Process of Titanium Dioxide Nanotube Synthesis and Its Effect on Photoelectrochemical Properties. Materials 2021, 14, 5686. https://doi.org/10.3390/ma14195686
Szkoda M, Trzciński K, Zarach Z, Roda D, Łapiński M, Nowak AP. Scaling Up the Process of Titanium Dioxide Nanotube Synthesis and Its Effect on Photoelectrochemical Properties. Materials. 2021; 14(19):5686. https://doi.org/10.3390/ma14195686
Chicago/Turabian StyleSzkoda, Mariusz, Konrad Trzciński, Zuzanna Zarach, Daria Roda, Marcin Łapiński, and Andrzej P. Nowak. 2021. "Scaling Up the Process of Titanium Dioxide Nanotube Synthesis and Its Effect on Photoelectrochemical Properties" Materials 14, no. 19: 5686. https://doi.org/10.3390/ma14195686