Effect of Exchangeable Ions in Natural and Modified Zeolites on Ag Content, Ag Nanoparticle Formation and Their Antibacterial Activity
Abstract
:1. Introduction
2. Materials and Methods
2.1. Material Preparation
2.2. Material Characterization
2.3. Antibacterial Tests
3. Results and Discussion
3.1. Characterization of Nanocomposites
3.1.1. SEM and Morphology
3.1.2. EDX and Element Composition
3.1.3. BET and Specific Surface Area
3.1.4. TEM and Size Distribution
3.1.5. Diffuse Reflectance UV-vis Spectroscopy and Silver Forms in Nanocomposites
3.1.6. XPS and Surface Chemistry
3.2. Antibacterial Activity of Silver-Zeolite Composites
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Sample | Si | Al | K | Ca | Mg | Fe | O | Ag |
---|---|---|---|---|---|---|---|---|
Ag–Zeo | 30.6 | 5.3 | 2.3 | 1.4 | 1.2 | 1.2 | 47.6 | 10.4 1 |
Ag–NaZeo | 29.8 | 5.2 | 2.4 | 1.2 | - | 0.9 | 45.9 | 14.6 |
Ag–HZeo | 36.5 | 2.4 | 0.8 | 1.3 | - | 1.3 | 55.5 | 2.2 |
Sample | Specific Surface Area (SBET, m2/g) | Micropore Surface Area (Smicro, m2/g) | External Surface Area (Sext, m2/g) | Total Pore Volume (Vtotal, cm3/g) | Total Micropore Volume (Vmicro, cm3/g) | Average Pore Diameter (Dav, nm) |
---|---|---|---|---|---|---|
Natural Zeolite | 19 | 7 | 12 | 0.08 | 0.003 | 16 |
Na-modified Zeolite | 18 | 2 | 16 | 0.10 | 0.001 | 21 |
H-modified Zeolite | 184 | 139 | 45 | 0.17 | 0.06 | 3.7 |
Ag–Zeo | 15 | 0 | 15 | 0.08 | 0.00 | 21.0 |
Ag–NaZeo | 15 | 0 | 15 | 0.08 | 0.00 | 22.5 |
Ag–HZeo | 90 | 59 | 31 | 0.14 | 0.03 | 6.1 |
Sample | Binding Energy (eV) Photoelectron Line | Binding Energy (eV) Auger Line | Kinetic Energy (eV) | Auger Parameters | Assignment | |
---|---|---|---|---|---|---|
Ag3d5/2 | Ag3d3/2 | AgM4NN | (α’) | |||
Ag–Zeo | 369.4 | 375.4 | 1131.0 | 355.6 | 725.0 | Ag(0) |
1133.0 | 353.6 | 723.0 | Ag(I) | |||
Ag–NaZeo | 369.4 | 375.4 | 1131.0 | 355.6 | 725.0 | Ag(0) |
1133.0 | 353.6 | 723.0 | Ag(I) | |||
Ag–HZeo | 369.0 | 375.0 | 1131.0 | 355.6 | 725.0 | Ag(0) |
1133.0 | 353.6 | 723.0 | Ag(I) |
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Mintcheva, N.; Panayotova, M.; Gicheva, G.; Gemishev, O.; Tyuliev, G. Effect of Exchangeable Ions in Natural and Modified Zeolites on Ag Content, Ag Nanoparticle Formation and Their Antibacterial Activity. Materials 2021, 14, 4153. https://doi.org/10.3390/ma14154153
Mintcheva N, Panayotova M, Gicheva G, Gemishev O, Tyuliev G. Effect of Exchangeable Ions in Natural and Modified Zeolites on Ag Content, Ag Nanoparticle Formation and Their Antibacterial Activity. Materials. 2021; 14(15):4153. https://doi.org/10.3390/ma14154153
Chicago/Turabian StyleMintcheva, Neli, Marinela Panayotova, Gospodinka Gicheva, Orlin Gemishev, and Georgy Tyuliev. 2021. "Effect of Exchangeable Ions in Natural and Modified Zeolites on Ag Content, Ag Nanoparticle Formation and Their Antibacterial Activity" Materials 14, no. 15: 4153. https://doi.org/10.3390/ma14154153