1. Introduction
Renewable energy sources such as wind and solar are expected to play a significant role in the global energy transition [
1]. However, they are also known as intermittent energy sources due to the fact that their operation depends on atmospheric conditions. Wind power stations produce energy when the wind blows, and solar plants do it only during the day. Thus, to meet the grid demand, it is necessary to store the surplus and utilize it during an undersupply period.
Li-ion batteries are widely used in portable electronics, electric vehicles, as well as energy storage systems that operate in one-day cycles. Their main advantages are an operating voltage of 3.2–4.0 V and an energy density of up to 250 Wh/kg (based on the weight of the entire cell) [
2]. The cathodes in lithium cells have a high gravimetric capacity of 120–200 mAh/g and a lifetime of more than 1000 charge–discharge cycles [
3]. Scientists struggle to find an inexpensive and widely available alternative to lithium. One of them can be sodium, which is also an alkaline metal. Sodium batteries usually have less capacity and have a lower operating voltage. Despite this, the energy density is still reasonably high, which makes them good candidates for sustainable and cost-efficient large-scale energy storage [
4].
Alluaudite-type materials are proposed to become novel cathodes in sodium-ion batteries. Their theoretical gravimetric capacity reaches 170 mAh/g. Nevertheless, it is hard to obtain material with practical capacity close to the theoretical value. One of the reasons is the low electrical conductivity of the compounds.
The first reports on the possibility of applying alluaudites in reversible cells came from Richardson’s 2003 work. He researched, among others,
and
in lithium cells. The first one reached a gravimetric capacity of 30 mAh/g and the second one 125 mAh/g, while the theoretical value is 170 mAh/g. He also received
in amorphous form by rapid cooling of a molten mixture of reagents. The FTIR spectrum was characteristic of alluaudite [
5].
In 2010, Trad investigated
obtained by solid-state reaction and the sol–gel method. The gravimetric capacity of the former was only 15 mAh/g. The material obtained by the sol–gel method was made up of smaller crystalline grains and had a porous structure, which led to an increase in capacity to 50 mAh/g. Difficulty in achieving the theoretical value (170 mAh/g) was mainly attributed to poor electronic conductivity [
6].
Eight years later, Dwibedi made an attempt to improve the parameters of
. Crystalline material with 100 nm grains coated with carbon reached a capacity of 60 mAh/g (at a C/20 current), but with a higher load, it dropped to 20 mAh/g (at a C current). The electrical conductivity was
S/cm,
eV [
7].
Essehli described
with the capacity of 109 mAh/g while drawing low currents of 5 mA/g. After 100 cycles, 87% of the initial capacity remained still useful. At higher loads, the amount of charge that could be reversibly cycled dropped significantly (by over 30%). This was attributed to the low electrical conductivity [
8].
Liu and Palmore investigated the effect of grinding
material and coating it with carbon on sodium cell performance. It turned out that the best results were obtained when the material was ground to particles less than 200 nm and coated with carbon as well. The high capacity of 141 mAh/g (theoretical 160 mAh/g) was attributed to increased electrical conductivity, reduced resistance between the grains, and the better-organized surface of the coated material [
9].
Walczak indicated that the
obtained by the solid-state reaction method did not contain secondary crystalline phases, in contrast to
. Besides, she concluded that the cathode redox reactions were limited by the low Na
ion diffusion coefficient—ca.
cm
/s [
10].
A growing interest in alluaudites has caused an increasing number of publications in this topic. Many other groups put valuable efforts into research on alluaudite-type cathode materials for NIBs. A description of other works can be found, e.g., in [
11].
To overcome the problem of the low electrical conductivity of various potential cathode materials, J.E. Garbarczyk, T.K. Pietrzak, and co-workers investigated the phenomenon of thermal nanocrystallization of amorphous analogues of cathode materials for lithium batteries (e.g., [
12,
13]). A correlation was observed between the increase in the electrical conductivity of the materials and changes in their microstructure. It was indicated that heating at an appropriate temperature resulted in the formation of small crystal grains of nanometric size embedded in the glassy matrix. It was concluded that such a microstructure creates favorable conditions for polaron hopping conductivity.
A similar approach was recently applied to alluaudite-type materials with a nominal composition of Na
Fe
(PO
)
, Na
VFe
(PO
)
, and Na
VFeMn(PO
)
[
14]. It was shown that these compounds can be synthesized in a glassy form via the melt-quenching technique. Thermal nanocrystallization of these glasses usually resulted in an increase in the electrical conductivity of the material; however, the increase was often not satisfactory. Moreover, the low reproducibility of samples with a pure alluaudite phase was obscure. Therefore, in 2021, we focused on optimizing the synthesis conditions to strive for better phase purity and reproducibility, as well as the higher conductivity of alluaudite-type nanostructured glass ceramics. Three previously studied compositions were extensively investigated [
15]. In particular, numerous factors influencing the final phase purity were carefully investigated, and a set of optimized synthesis condition parameters was elaborated. Some differences occurred between materials of various compositions. Furthermore, numerous in situ electrical studies were carried out with a wide variety of the maximum temperature of the thermal nanocrystallization. As a result, nanomaterials with significantly improved electrical conductivity and high phase purity were synthesized.
For the purposes of this work, three alluaudite-like glasses with the compositions mentioned above were synthesized using optimized conditions, as described in [
15]. Subsequently, they were subjected to a thermal nanocrystallization optimized procedure. Their impedance was studied at ultra-high frequencies. Eventually, prototype laboratory sodium cells were assembled, and their electrochemical properties were investigated.
2. Materials and Methods
The synthesis procedure was described in detail in [
15]. In short, the following reagents were used: Na
CO
(99.8%, Polish Chemicals), FePO
H
O (pure, Roth) or FeC
O
H
O (99%, Aldrich), V
O
(99.6%, Roth), Mn(CH
COO)
H
O (99%, Aldrich), and NH
H
PO
(99%, Polish Chemicals).
(labeled as FFF) was synthesized using iron (II) oxalate as the Fe precursor. All reagents were mixed and homogenized in a mortar. The batches in porcelain crucibles were then placed in a chamber oven and presynthesized at 240 °C for 4 h. After that, the crucibles were put into an Argenta AFI-02 inductive furnace, preheated to 700 °C, heated to 1300 °C, and melted for 15 min. To ensure a non-oxidizing atmosphere, a double-crucible technique was used—the main crucibles were put into a larger one, filled with activated charcoal, and covered with a lid. At the end, the melt was poured onto a copper plate and immediately pressed with another one.
The procedure for the (VFF) sample was similar. However, the batches were not presynthesized before melting and quenching was conducted between steel plates, and not copper ones.
(VFM), in turn, required iron (III) phosphate as the Fe precursor. The rest of the procedure was identical as that for the FFV sample.
The amorphousness of the as-synthesized samples and the structure of the nanocrystalline glass ceramics were investigated with X-ray diffractometry, using a Malvern Panalytical Empyrean diffractometer. The measurements were carried out in the 5–110° range at room temperature and using a copper lamp.
Electrical properties were studied by impedance spectroscopy (IS). The setup was based on a broadband impedance analyzer that performed measurements in the frequency range from 10 Hz to 7 GHz [
16,
17]. Pt electrodes were sputtered onto opposite faces of the solid samples in order to provide good electrical contacts. The impedance measurements were carried out on heating and cooling ramps in the temperature range from 25 °C to the optimal temperature determined for each composition (FFF—581 °C, VFF—628 °C, VFM—607 °C).
Active material for cathode preparation was synthesized as follows. Pristine glasses were heat treated in a tube furnace (Czylok) for 1 h at the temperature determined from the impedance measurements. Constant argon flow during the whole process was provided. The heating and cooling rates were set to 2 °C/min. The nanocrystalline glass ceramics were then ground in a mortar.
Each cathode layer had 3 constituents, which were mixed in the following proportions: active material—75%, conductive carbon black (Super P)—15%, polyvinylidene difluoride (PVDF) binder—10%. In the first step, only the active material and carbon black dried in a vacuum drier were mixed and then ball milled for 10 h at 100 rpm. Subsequently, a proper amount of binder was added, and a 1-methyl-2-pyrrolidinone solvent was used to prepare a slurry, which was put on a magnetic stirrer. After obtaining a smooth consistency, it was stirred further for at least 1 h. The cathode slurry was poured on aluminum foil and carefully but steadily spread by means of a doctor blade. The layer was preliminarily dried at ambient temperature in air for about 1 h. Then, it was placed in a vacuum drier at 55 °C overnight.
Electrochemical cells were assembled in Swagelok-type holders. A cathode disk was put into the cell in air. The rest of the process was performed in a glove box filled with argon. Glass microfiber separators were soaked with the electrolyte (1 M solution in ethyl carbonate (EC) and propylene carbonate (PC) mixed at a 1:1 mass ratio), and metallic sodium (serving as an anode) was freshly rolled and cut. All components were put together and screwed sensitively in order not to damage the cathode layer, but to provide tightness and contact. When finished, the cells were additionally sealed with parafilm.
At the end, the cells were tested using the Arbin BT-2043 Battery Test System. The cycling procedure consisted of charge/discharge galvanostatic cycles with cut-off voltages of 1.5 V and 4.5 V. The cells were tested at various current rates, as follows: C/50 (1 cycle), C/20 (4 cycles), C/10 (20 cycles), C/5 (20 cycles), C/2 (20 cycles), C (20 cycles), C/10 (10 cycles). Current rates were calculated for the capacity considering only 2 active sodium ions per formula, i.e., 108 mAh/g.
4. Conclusions
This work was a natural continuation of our recent study [
15], where highly conductive nanocrystalline alluaudite-like materials were synthesized and their thermal, structural, and electrical properties were extensively studied. Here, we focused on the electrochemical performance of the active materials with optimized electrical conductivity.
Unfortunately, despite the high electrical conductivity and extended surfaces of the nanocrystalline grains, the electrochemical performance of the studied materials was modest. The highest reversible capacity did not exceed 35 mAh/g. Interestingly, the charge/discharge curves for nanocrystalline samples did not show standard plateaus. They were rather arc-like or had a stretched step-like shape. This is characteristic for nanostructured cathode materials, as shown, e.g., in the paper [
20]. The most steps could be distinguished in the VFM material. This suggests the activity of a few redox couples, which may be due to the presence of three different transition metals.
It seems that at this point, the high electrical conductivity of the nanocrystalline materials did not result in an improvement of the electrochemical performance of the laboratory cells. Even though the electronic conductivity was significantly improved, the ionic conductivity probably remained at a modest level, what may be the reason for modest electrochemical performance. Nevertheless, in our opinion, further optimization in the preparation of cathode layers and assembling prototype cells could lead to better performance. In particular, the optimization of the nanocrystallite-to-residual-glassy-matrix ratio could be a factor influencing the performance, as well as some other parameters (e.g., milling time and speed, layer thickness, etc.). The quite good recent electrochemical results of nanocrystalline olivine-like nanomaterials [
21] gives strong motivation for further studies in this area.